Abstract: An olefin production device for producing an olefin from a raw material gas containing methane and oxygen includes a reactor containing: a first catalyst; and a second catalyst disposed downstream of the first catalyst in a flow direction of the raw material gas. The first catalyst is a catalyst in which a zirconium salt or carbonate of an alkali metal, an oxide of an alkaline earth metal, an oxide of one kind of lanthanoid element, a composite oxide containing a lanthanoid element, or a combination thereof is supported on a support. The second catalyst is a catalyst containing a tungsten oxide, phosphate, or carbonate of an alkali metal.

Abstract: A partial oxidative coupling catalyst has a structure in which a component represented by M2ZrO3 is supported on a support, where M represents an alkali metal.

Abstract: The present invention relates to the electrodeposition and photochemical deposition of one or more material layer that protects metal surfaces from unwanted redox reactions. The deposited layer materials are composed of silicon oxide prepared in the presence of tetraalkylammonium shape directing agent. The deposited layer can be cathodically electrodeposited onto a metallic material. The deposition results in a uniform and acid-tolerant thin layer (15 nm-100 nm), which functions as a membrane to prevent dissolved gaseous reactants and various ions from penetrating. The silicon oxide protection layer also prevents corrosion underneath the layer. In the present invention, a process for producing these membranes is disclosed, with an example exhibiting the selective hydrogen evolution reaction (HER) excluding the reaction of coexisting redox ions and oxygen (corrosion inhibition).

Abstract: Oxygen evolution electrocatalysts, electrodes using oxygen evolution electrocatalysts, and methods of making oxygen evolution electrocatalysts are provided. The oxygen evolution electrocatalyst includes an oxide electrocatalyst and a permselective amorphous layer deposited on the oxide electrocatalyst. In this regard, the permselective amorphous layer may prevent diffusion of redox ions but permit diffusion of hydroxide ions and evolved O2 through the permselective amorphous layer.

Abstract: Provided herein are scalable photoreactors that can include a membrane-free water-splitting electrolyzer and systems that can include a plurality of membrane-free water-splitting electrolyzers. Also provided herein are methods of using the scalable photoreactors provided herein.

Abstract: The present invention uses a cobalt catalyst for carbon dioxide reforming of lower alkanes to synthesis gas having a cobalt catalyst on an oxide support where the supported cobalt catalyst has been modified with a boron precursor. The boron-treated cobalt catalyst systems as described herein show significant increases in the conversion of CH4 and CO2 during the dry reforming of methane (DRM) reaction as compared to traditional catalysts. Described herein are supported catalysts and methods of using the catalysts for the dry reforming of methane to synthesis gas, with the supported catalysts in the present invention include a boron-treated cobalt catalyst disposed on an oxide support. Also described herein are processes for preparing the supported catalysts.

Abstract: Provided herein are scalable photoreactors that can include a membrane-free water-splitting electrolyzer and systems that can include a plurality of membrane-free water-splitting electrolyzers. Also provided herein are methods of using the scalable photoreactors provided herein.

Abstract: Disclosed is a supported nanoparticle catalyst, methods of making the supported nanoparticle 5 catalysts and uses thereof. The supported nanoparticle catalyst includes catalytic metals M1, M2, M3, and a support material. M1 and M2 are different and are each selected from nickel (Ni), cobalt (Co), manganese (Mn), iron (Fe), copper (Cu) or zinc (Zn), wherein M1 and M2 are dispersed in the support material. M3 is a noble metal deposited on the surface of the nanoparticle catalyst and/or dispersed in the support material. The nanoparticle catalyst is 10 capable of producing hydrogen (H2) and carbon monoxide (CO) from methane (CH4) and carbon dioxide (CO2).

Abstract: The present invention is directed, at least in part, to a process for improving the efficiency of a photocatalyst (a semiconductor photocatalyst) by tethering (depositing) a metal (e.g., metal ions of a late transition metal, such as nickel) to the semiconductor (photocatalyst) surface through the use of an organic ligand. More specifically, 1,2-ethanedithiol (EDT) functions as an excellent molecular linker (organic ligand) to attach a transition metal complex (e.g., nickel (Ni2+ ions)) to the semiconductor surface, which can be in the form of a cadmium sulfide surface. The photocatalyst has particular utility in generating hydrogen from H2S.

Abstract: The present invention is directed, at least in part, to a process for improving the efficiency of a photocatalyst (a semiconductor photocatalyst) by tethering (depositing) a metal (e.g., metal ions of a late transition metal, such as nickel) to the semiconductor (photocatalyst) surface through the use of an organic ligand. More specifically, 1,2-ethanedithiol (EDT) functions as an excellent molecular linker (organic ligand) to attach a transition metal complex (e.g., nickel (Ni2+ ions)) to the semiconductor surface, which can be in the form of a cadmium sulfide surface. The photocatalyst has particular utility in generating hydrogen from H2S.

Abstract: The invention provides an organic compound(s) hydrogenation device that allows hydrogen derived from water to be stored essentially without generating hydrogen gas. The organic compound hydrogenation device of the invention comprises an oxidation chamber that holds a water-containing electrolyte, a reduction chamber that holds an organic compound(s) with an unsaturated bond, an electrolyte membrane with ion permeability that separates the electrolyte held in the oxidation chamber from the organic compound(s) held in the reduction chamber, an oxidizing electrode that generates protons from the water held in the oxidation chamber, and a reducing electrode that hydrogenates the organic compound(s) held in the reduction chamber.