Patents by Inventor Kazuhiro Wataya
Kazuhiro Wataya has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 11912583Abstract: A slurry of a dispersion medium and rare earth oxide particles. The particles having a volume basis median particle size D50 of up to 50 nm. The rare earth oxide particles having a dispersity index S of up to 1, the dispersity index S being determined according to the formula (1): (D90?D10)/D50??(1) wherein D10, D50 and D90 are cumulative 10%, 50% and 90% diameters in volume basis particle size distribution, respectively.Type: GrantFiled: November 8, 2021Date of Patent: February 27, 2024Assignee: SHIN-ETSU CHEMICAL CO., LTD.Inventor: Kazuhiro Wataya
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Patent number: 11840456Abstract: An aqueous solution containing ions of one or more rare earth elements selected from the group consisting of Y, Nd, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu, hydrogen peroxide, urea, and polyvinylpyrrolidone is heated at a temperature of 80° C. or higher and equal to or lower than a boiling point of the aqueous solution to produce particles of a rare earth compound under a reaction between a hydrolysis product of urea and the ions of the rare earth elements. Furthermore, the particles of the rare earth compound are solid-liquid separated from the aqueous solution, and the obtained solid content is baked at a temperature of 600° C. or higher in an atmosphere containing oxygen to produce rare earth oxide particles.Type: GrantFiled: October 15, 2021Date of Patent: December 12, 2023Assignee: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Hironori Suzuki, Kazuhiro Wataya
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Publication number: 20220119271Abstract: An aqueous solution containing ions of one or more rare earth elements selected from the group consisting of Y, Nd, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu, hydrogen peroxide, urea, and polyvinylpyrrolidone is heated at a temperature of 80° C. or higher and equal to or lower than a boiling point of the aqueous solution to produce particles of a rare earth compound under a reaction between a hydrolysis product of urea and the ions of the rare earth elements. Furthermore, the particles of the rare earth compound are solid-liquid separated from the aqueous solution, and the obtained solid content is baked at a temperature of 600° C. or higher in an atmosphere containing oxygen to produce rare earth oxide particles.Type: ApplicationFiled: October 15, 2021Publication date: April 21, 2022Applicant: Shin-Etsu Chemical Co., Ltd.Inventors: Hironori Suzuki, Kazuhiro Wataya
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Patent number: 11292726Abstract: Rare earth compound particles are prepared by a step of heating an aqueous solution containing rare earth metal ions and urea to form a rare earth compound by a reaction of a hydrolysis product of urea, and the rare earth metal ions. In the heating step, heating the aqueous solution into which an acetylene glycol-ethylene oxide adduct is added.Type: GrantFiled: August 27, 2019Date of Patent: April 5, 2022Assignee: SHIN-ETSU CHEMICAL CO., LTD.Inventor: Kazuhiro Wataya
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Publication number: 20220055913Abstract: Rare earth compound particles are prepared by a step of heating an aqueous solution containing rare earth metal ions and urea to form a rare earth compound by a reaction of a hydrolysis product of urea, and the rare earth metal ions. In the heating step, heating the aqueous solution into which an acetylene glycol-ethylene oxide adduct is added.Type: ApplicationFiled: November 8, 2021Publication date: February 24, 2022Applicant: Shin-Etsu Chemical Co., Ltd.Inventor: Kazuhiro Wataya
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Publication number: 20220055912Abstract: Rare earth compound particles are prepared by a step of heating an aqueous solution containing rare earth metal ions and urea to form a rare earth compound by a reaction of a hydrolysis product of urea, and the rare earth metal ions. In the heating step, heating the aqueous solution into which an acetylene glycol-ethylene oxide adduct is added.Type: ApplicationFiled: November 8, 2021Publication date: February 24, 2022Applicant: Shin-Etsu Chemical Co., Ltd.Inventor: Kazuhiro Wataya
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Publication number: 20200190334Abstract: Spraying particles including a rare earth silicate wherein the spraying particles are granulated particles and have a composition represented by the average compositional formula: (A2SiyOz)1-a-b(CeSipOq)a(EuSimOn)b or the average compositional formula: A2SiyOz is manufactured from (A) rare earth oxide particles and/or rare earth silicate particles, and silicon oxide particle, (B) a water-soluble rare earth compound and silicon oxide particles, or rare earth silicate particles by granulating and firing.Type: ApplicationFiled: December 13, 2019Publication date: June 18, 2020Applicant: Shin-Etsu Chemical Co., Ltd.Inventor: Kazuhiro Wataya
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Publication number: 20200071180Abstract: Rare earth compound particles are prepared by a step of heating an aqueous solution containing rare earth metal ions and urea to form a rare earth compound by a reaction of a hydrolysis product of urea, and the rare earth metal ions. In the heating step, heating the aqueous solution into which an acetylene glycol-ethylene oxide adduct is added.Type: ApplicationFiled: August 27, 2019Publication date: March 5, 2020Applicant: Shin-Etsu Chemical Co., Ltd.Inventor: Kazuhiro Wataya
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Patent number: 10450505Abstract: Provided is a wavelength conversion member in which the following are dispersed in a thermoplastic resin: a LuYAG fluorescent material that is represented by (Y1-?-?Lu?Ce?)3Al5O12 (in which ? is a positive number between 0.3-0.8 inclusive and ? is a positive number between 0.01-0.05 inclusive), that emits yellow-green light as a result of excitation by blue light, and that has a diffraction peak within a range in which the diffraction angle 2? in X-ray diffraction by the K?1 line of Cu is 52.9° to 53.2° inclusive; and a KSF fluorescent material that is represented by K2(Si1-xMnx)F6 (in which x is a positive number between 0.001 and 0.3 inclusive) and that emits red light as a result of excitation by blue light. The content of the KSF fluorescent material in the wavelength conversion member is 1 to 5 times the content of the LuYAG fluorescent material by mass ratio.Type: GrantFiled: November 27, 2015Date of Patent: October 22, 2019Assignee: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Toshihiro Tsumori, Hajime Nakano, Toshihiko Tsukatani, Kazuhiro Wataya, Takehisa Minowa
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Patent number: 10288260Abstract: A turn signal for a vehicle has a blue LED as a light source, and an outer cover irradiated by the blue light. The outer cover includes a molded body of a polymeric material including phosphors dispersed therein that absorb blue light and emit light. By means of the present invention, it is possible to provide a turn signal for vehicles which has improved visibility and which imparts excellent visibility and sufficient luminous intensity over a wide angle. Further, because the entire outer cover surface-emits light, uniformity of luminous intensity is ensured without subjecting the outer cover to light scattering treatment, enabling as a result preventing glare caused by light scattering treatment, making this turn signal safe without being unpleasant for pedestrians and drivers of nearby vehicles. Furthermore, because no complex optical design is necessary, this turn signal saves space and can be arranged in a vehicle.Type: GrantFiled: February 28, 2014Date of Patent: May 14, 2019Assignee: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Toshihiko Tsukatani, Toshihiro Tsumori, Kazuhiro Wataya, Masami Kaneyoshi, Takehisa Minowa
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Patent number: 10266763Abstract: Provided is a method of producing a Mn-activated complex fluoride phosphor, the method including: mixing a red phosphor as a Mn-activated complex fluoride represented by the following formula (1): K2MF6:Mn??(1) wherein M is one or two or more of tetravalent elements selected from the group consisting of Si, Ti, Zr, Hf, Ge and Sn and necessarily includes Si, with K2MnF6 in solid state and optionally with a hydrogenfluoride represented by the following formula (2): AF.nHF??(2) wherein A is one or two or more of alkali metals and/or ammonium selected from the group consisting of Li, Na, K, Rb and NH4 and necessarily includes K, and n is a number of 0.7 to 4, in solid state; and heating the resulting mixture at a temperature of 100 to 500° C. According to the present invention, it is possible to obtain a Mn-activated complex fluoride phosphor which can be used with smaller amount as compared to those according to the related art.Type: GrantFiled: October 13, 2016Date of Patent: April 23, 2019Assignee: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Masami Kaneyoshi, Hirofumi Kawazoe, Isamu Fujioka, Kazuhiro Wataya, Hajime Nakano
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Patent number: 10202547Abstract: Disclosed is an adjustment component that: includes a complex fluoride fluorophore represented by A2(M1-xMnx)F6 (in the formula: M is one or two or more of type of tetravalent element selected from Si, Ti, Zr, Hf, Ge, and Sn; A is one or two or more of type of alkali metal selected from Li, Na, K, Rb, and Cs and including at least Na and/or K; and x is from 0.001 to 0.3); and adjusts the chromaticity and/or color rendering index of illumination light by absorbing light having a wavelength of from 420 nm to 490 nm inclusive, and emitting light including a red wavelength component.Type: GrantFiled: December 26, 2013Date of Patent: February 12, 2019Assignee: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Toshihiro Tsumori, Takehisa Minowa, Masami Kaneyoshi, Kazuhiro Wataya
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Patent number: 9988572Abstract: This lighting apparatus is provided with a blue LED chip having a maximum peak at a wavelength of 420-480 nm and a fluorescent material-containing resin layer disposed on the front of the blue LED chip in the light emission direction. The fluorescent material-containing resin layer is obtained by mixing and dispersing a LuAg fluorescent material, which is represented by the formula Lu3Al5O12:Ce3+ and in which the Ce activation rate is 2 mol. % or lower relative to Lu, and a double fluoride fluorescent material represented by the formula A2(B1?xMnx)F6 (in the formula, A is at least one type of element selected from among the group consisting of Li, Na, K and Cs, B is at least one type of element selected from among the group consisting of Si, Ti, Nb, Ge and Sn, and x is an integer that falls within the range 0.001?x?0.1) in a resin.Type: GrantFiled: November 28, 2014Date of Patent: June 5, 2018Assignee: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Kazuhiro Wataya, Toshihiro Tsumori, Toshihiko Tsukatani, Takehisa Minowa
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Patent number: 9978913Abstract: An outdoor luminaire comprising a blue LED chip having a maximum peak at a wavelength of 420-480 nm and a phosphor layer disposed forward of the LED chip in its emission direction is provided. The phosphor layer comprises a phosphor of the formula: Lu3Al5O12:Ce3+ which is activated with up to 1 mol % of Ce relative to Lu, the phosphor being dispersed in a resin. In scotopic and mesopic vision conditions, the luminaire produces illumination affording brighter lighting, higher visual perception and brightness over a broader area.Type: GrantFiled: June 20, 2014Date of Patent: May 22, 2018Assignee: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Toshihiro Tsumori, Toshihiko Tsukatani, Kazuhiro Wataya, Takehisa Minowa
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Publication number: 20170342320Abstract: Provided is a wavelength conversion member in which the following are dispersed in a thermoplastic resin: a LuYAG fluorescent material that is represented by (Y1-?-?Lu?Ce?)3Al5O12 (in which ? is a positive number between 0.3-0.8 inclusive and ? is a positive number between 0.01-0.05 inclusive), that emits yellow-green light as a result of excitation by blue light, and that has a diffraction peak within a range in which the diffraction angle 2? in X-ray diffraction by the K?1 line of Cu is 52.9° to 53.2° inclusive; and a KSF fluorescent material that is represented by K2(Si1-xMnx)F6 (in which x is a positive number between 0.001 and 0.3 inclusive) and that emits red light as a result of excitation by blue light. The content of the KSF fluorescent material in the wavelength conversion member is 1 to 5 times the content of the LuYAG fluorescent material by mass ratio.Type: ApplicationFiled: November 27, 2015Publication date: November 30, 2017Applicant: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Toshihiro TSUMORI, Hajime NAKANO, Toshihiko TSUKATANI, Kazuhiro WATAYA, Takehisa MINOWA
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Publication number: 20170336040Abstract: This LED light source for a vehicle-mounted headlight is provided with: a blue LED that emits blue light having a dominant wavelength of 430-470 nm; and a fluorescent material that is arranged forward in the light emission direction of the blue light and that performs wavelength conversion of the blue light. The main fluorescent material constituting the fluorescent material is a celium-activated lutetium/aluminum/garnet fluorescent material represented by Lu3Al5O12:Ce. The LED light source for a vehicle-mounted headlight emits pseudo-white light that has a color temperature of 6,000 K or less and that is unlikely to decrease in visibility even during bad weather. The LED light source for a vehicle-mounted headlight has characteristics such as a wide lighting range and excellent visibility in the peripheral area of the visual field (the peripheral visual field) and can thus contribute to accident prevention and road traffic safety.Type: ApplicationFiled: December 2, 2015Publication date: November 23, 2017Applicant: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Toshihiro TSUMORI, Toshihiko TSUKATANI, Kazuhiro WATAYA, Takehisa MINOWA
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Patent number: 9657221Abstract: Disclosed is a wavelength conversion member which is a resin-molded article having dispersed therein a complex fluoride fluorophore that absorbs light with a blue wavelength component and emits light including a red wavelength component and that is represented by A2(M1?xMnx)F6 (in the formula: M is at least one type of tetravalent element selected from Si, Ti, Zr, Hf, Ge, and Sn; A is at least one type of alkali metal selected from Li, Na, K, Rb, and Cs and including at least Na and/or K; and x is from 0.001 to 0.3), wherein the hue of the wavelength conversion member when light is not emitted is as follows in CIELAB (CIE 1976): L*=from 40 to 60 inclusive; a*=from 0 to +1 inclusive; and b*=from +2 to +15 inclusive.Type: GrantFiled: December 26, 2013Date of Patent: May 23, 2017Assignee: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Toshihiro Tsumori, Takehisa Minowa, Masami Kaneyoshi, Kazuhiro Wataya
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Publication number: 20170107425Abstract: Provided is a method of producing a Mn-activated complex fluoride phosphor, the method including: mixing a red phosphor as a Mn-activated complex fluoride represented by the following formula (1): K2MF6:Mn??(1) wherein M is one or two or more of tetravalent elements selected from the group consisting of Si, Ti, Zr, Hf, Ge and Sn and necessarily includes Si, with K2MnF6 in solid state and optionally with a hydrogenfluoride represented by the following formula (2): AF.nHF??(2) wherein A is one or two or more of alkali metals and/or ammonium selected from the group consisting of Li, Na, K, Rb and NH4 and necessarily includes K, and n is a number of 0.7 to 4, in solid state; and heating the resulting mixture at a temperature of 100 to 500° C. According to the present invention, it is possible to obtain a Mn-activated complex fluoride phosphor which can be used with smaller amount as compared to those according to the related art.Type: ApplicationFiled: October 13, 2016Publication date: April 20, 2017Applicant: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Masami Kaneyoshi, Hirofumi Kawazoe, Isamu Fujioka, Kazuhiro Wataya, Hajime Nakano
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Patent number: 9617469Abstract: Phosphor particles are provided in the form of spherical polycrystalline secondary particles consisting of a multiplicity of primary particles, including a garnet phase having the compositional formula: (A1-xBx)3C5O12 wherein A is Y, Gd, and/or Lu, B is Ce, Nd, and/or Tb, C is Al and/or Ga, and 0.002?x?0.2, the secondary particles having an average particle size of 5-50 ?m.Type: GrantFiled: December 23, 2011Date of Patent: April 11, 2017Assignee: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Toshihiko Tsukatani, Kazuhiro Wataya, Yasushi Takai, Takehisa Minowa
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Patent number: 9611425Abstract: A method for treating a Mn-activated complex fluoride phosphor is provided wherein a preliminarily-prepared red phosphor of a Mn-activated complex fluoride represented by the following formula (1): A2MF6:Mn??(1) wherein M represents at least one tetravalent element selected from Si, Ti, Zr, Hf, Ge and Sn, A represents at least one alkali metal selected from Li, Na, K, Rb and Cs provided that at least Na and/or K is contained, is heated in a substantially oxygen atom-free gas but containing a fluorine atom at a temperature of at least 50° C.Type: GrantFiled: October 22, 2015Date of Patent: April 4, 2017Assignee: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Masami Kaneyoshi, Kazuhiro Wataya