Abstract: Providing a negative-electrode material for nonaqueous-electrolyte secondary battery, the negative-electrode material including lithium silicate particles coated by a carbonaceous substance, a production process for the same, a negative electrode for nonaqueous-electrolyte secondary battery, and a nonaqueous-electrolyte secondary battery. A negative-electrode material for nonaqueous-electrolyte secondary battery includes lithium silicate particles having a surface at least some of which is coated by a carbonaceous substance formed by heating a carbon-containing compound at a thermal decomposition temperature of the carbon-containing compound or more and 1,100±° C. or less, the carbon-containing compound being a solid at ordinary temperature and exhibiting a zeta-potential absolute value being 60 or more against N-methyl-2-pyrrolidone (or NMP).

Abstract: A lithium-ion secondary battery of the present invention comprises a positive electrode including a positive electrode active material composite formed by compositing a lithium silicate-based material and a carbon material, a negative electrode including a negative electrode active material containing a silicon, and an electrolyte. The lithium-ion secondary battery satisfies 0.8<B/A<1.2, where A is irreversible capacity of the positive electrode and B is irreversible capacity of the negative electrode.

Abstract: Provided are a positive electrode active material for a sodium ion secondary battery, and a positive electrode and a sodium ion secondary battery using the material. The positive electrode active material for a sodium ion secondary battery comprises a lithium sodium-based compound containing lithium (Li), sodium (Na), iron (Fe), and oxygen (O).

Abstract: In a secondary battery, a negative electrode, an electrolytic solution for negative electrode, a diaphragm, an electrolytic solution for positive electrode, and a positive electrode are disposed in order. The negative electrode includes a negative-electrode active material that has an element whose oxidation-reduction potential is more “base” by 1.5 V or more than an oxidation-reduction potential of hydrogen, and whose volume density is larger than that of lithium metal. The diaphragm includes a solid electrolyte transmitting ions of said element alone. A secondary battery with high volumetric density is provided.

Abstract: Provided is a novel lithium silicate-based material useful as a positive electrode material for lithium ion secondary battery. The lithium silicate-based compound is represented by Li1.5FeSiO4.25. The lithium silicate-based compound is a compound including: lithium (Li); iron (Fe); silicon (Si); and oxygen (O), and expressed by a composition formula, Li1+2?FeSiO4+??c (?0.25???0.25, 0?c?0.5). The lithium silicate-based compound, of which iron (Fe) is trivalent, exerts a remarkable chemical stability as compared to Li2FeSiO4.

Abstract: A production process for lithium-silicate-based compound according to the present invention is characterized in that: a lithium-silicate compound being expressed by Li2SiO3 is reacted with a transition-metal-element-containing substance including at least one member being selected from the group consisting of iron and manganese at 550° C. or less within a molten salt including at least one member being selected from the group consisting of alkali-metal nitrates as well as alkali-metal hydroxides in an atmosphere in the presence of a mixed gas including carbon dioxide and a reducing gas. In accordance with the present invention, it is possible to produce lithium-silicate-based materials, which are useful as a positive-electrode active material for lithium-ion secondary battery, and the like, at low temperatures by means of relatively easy means.

Abstract: A lithium-ion secondary battery of the present invention comprises a positive electrode including a positive electrode active material composite formed by compositing a lithium silicate-based material and a carbon material, a negative electrode including a negative electrode active material containing a silicon, and an electrolyte. The lithium-ion secondary battery satisfies 0.8<B/A<1.2, where A is irreversible capacity of the positive electrode and B is irreversible capacity of the negative electrode.

Abstract: Providing a negative-electrode active material for nonaqueous-electrolyte secondary battery, the negative-electrode active material enabling an output characteristic to upgrade, a production process for the same, a negative electrode for nonaqueous-electrolyte secondary battery, and a nonaqueous-electrolyte secondary battery. The negative-electrode active material includes an Si-metal-carbon composite composed of: a metal/carbon composite matrix including at least one metal selected from the group consisting of Cu, Fe, Ni, Ti, Nb, Zn, In and Sn, at least one member selected from the group consisting of N, O, P and S, and amorphous carbon; and nanometer-size Si particles dispersed in the metal/carbon composite matrix.

Abstract: A lithium silicate-based compound according to the present invention is expressed by a general formula, Li(2?a+b)AaMn(1?x?y)CoxMySiO(4+?)Cl? (In the formula: “A” is at least one element selected from the group consisting of Na, K, Rb and Cs; “M” is at least one member selected from the group consisting of Mg, Ca, Al, Ni, Fe, Nb, Ti, Cr, Cu, Zn, Zr, V, Mo and W; and the respective subscripts appear to be as follows: 0?“a”<0.2; 0?“b”<1; 0<“x”<1; 0?“y”?0.5; ?0.25?“?”?1.25; and 0?“?”?0.05). The lithium silicate-based compound is used as a positive-electrode active material for secondary battery whose discharge average voltage is higher, and which is able to sorb and desorb lithium ions.

Abstract: Providing a negative-electrode material for nonaqueous-electrolyte secondary battery, the negative-electrode material including lithium silicate particles coated by a carbonaceous substance, a production process for the same, a negative electrode for nonaqueous-electrolyte secondary battery, and a nonaqueous-electrolyte secondary battery. A negative-electrode material for nonaqueous-electrolyte secondary battery includes lithium silicate particles having a surface at least some of which is coated by a carbonaceous substance formed by heating a carbon-containing compound at a thermal decomposition temperature of the carbon-containing compound or more and 1,100° C. or less, the carbon-containing compound being a solid at ordinary temperature and exhibiting a zeta-potential absolute value being 60 or more against N-methyl-2-pyrrolidone (or NMP).

Abstract: A solid electrolyte has a sheet shape, and is composed of an oxide sintered body. The solid electrolyte includes a layer-shaped dense portion whose sintered density is 90% or more, and a porous portion formed on a superficial side of the solid electrolyte so as to be continuous from at least one of opposite surfaces of the dense portion, and having a porosity of 50% or more. A secondary battery includes a positive electrode, and a negative electrode, the positive electrode and negative electrode arranged at opposite facing positions interposing the solid electrolyte.

Abstract: Providing a negative-electrode active material for nonaqueous-electrolyte secondary battery, the negative-electrode active material enabling an output characteristic to upgrade, a production process for the same, a negative electrode for nonaqueous-electrolyte secondary battery, and a nonaqueous-electrolyte secondary battery. The negative-electrode active material includes an Si-metal-carbon composite composed of: a metal/carbon composite matrix including at least one metal selected from the group consisting of Cu, Fe, Ni, Ti, Nb, Zn, In and Sn, at least one member selected from the group consisting of N, O, P and S, and amorphous carbon; and nanometer-size Si particles dispersed in the metal/carbon composite matrix.

Abstract: In a secondary battery, a negative electrode, an electrolytic solution for negative electrode, a diaphragm, an electrolytic solution for positive electrode, and a positive electrode are disposed in order. The negative electrode includes a negative-electrode active material that has an element whose oxidation-reduction potential is more “base” by 1.5 V or more than an oxidation-reduction potential of hydrogen, and whose volume density is larger than that of lithium metal. The diaphragm includes a solid electrolyte transmitting ions of said element alone. A secondary battery with high volumetric density is provided.

Abstract: A lithium silicate-based compound according to the present invention is expressed by a general formula, Li(2?a+b)AaMn(1?x?y)CoxMySiO(4+?)Cl? (In the formula: “A” is at least one element selected from the group consisting of Na, K, Rb and Cs; “M” is at least one member selected from the group consisting of Mg, Ca, Al, Ni, Fe, Nb, Ti, Cr, Cu, Zn, Zr, V, Mo and W; and the respective subscripts appear to be as follows: 0?“a”<0.2; 0?“b”<1; 0<“x”<1; 0?“y”?0.5; ?0.25?“?”?1.25; and 0?“?”?0.05). The lithium silicate-based compound is used as a positive-electrode active material for secondary battery whose discharge average voltage is higher, and which is able to sorb and desorb lithium ions.

Abstract: Provided are a positive electrode active material for a sodium ion secondary battery, and a positive electrode and a sodium ion secondary battery using the material. The positive electrode active material for a sodium ion secondary battery comprises a lithium sodium-based compound containing lithium (Li), sodium (Na), iron (Fe), and oxygen (O).

Abstract: Provided is a novel lithium silicate-based material useful as a positive electrode material for lithium ion secondary battery. The lithium silicate-based compound is represented by Li1.5FeSiO4.25 The lithium silicate-based compound is a compound including: lithium (Li); iron (Fe); silicon (Si); and oxygen (O), and expressed by a composition formula, Li1+2?FeSiO4+??c(?0.25???0.25, 0?c?0.5). The lithium silicate-based compound, of which iron (Fe) is trivalent, exerts a remarkable chemical stability as compared to Li2FeSiO4.

Abstract: To provide a sulfur-system positive electrode for lithium-ion battery, sulfur-system positive electrode which is good in the cyclability and the other characteristics, and a lithium-ion secondary battery including that positive electrode. In a positive electrode for lithium-ion secondary battery, the positive electrode having: a current collector; and an electrode layer that is formed on a surface of the current collector, and which includes a binder resin, an active material and a conductive additive, the positive electrode is characterized in that the active material includes a sulfur-modified polyacrylonitrile that is produced by heating a raw-material powder including a sulfur powder and a polyacrylonitrile powder in an enclosed nonoxidizing atmosphere; and the binder resin includes a polyimide resin and/or a polyamide-imide resin.

Abstract: A negative-electrode active material for secondary battery includes a sulfur-modified polyacrylonitrile. The sulfur-modified polyacrylonitrile includes a polyacrylonitrile, and sulfur being introduced into the polyacrylonitrile.

Abstract: It is intended to provide a positive electrode active material, which contains a lithium silicate based compound and has superior conductivity, for nonaqueous electrolyte secondary battery, a process for producing the same, and a nonaqueous electrolyte secondary battery using the positive electrode active material. The lithium silicate based compound and a carbon material are mixed at 450 to 16000 rpm for 1 minute to 10 hours and then heated and pressurized at 500° C. to 700° C. at 1 to 500 MPa for 1 minute to 15 hours, thereby adhering the lithium silicate based compound and the carbon material to each other.

Abstract: Because of being equipped with a positive electrode, a negative electrode and a sodium-ion nonaqueous electrolyte, and because the positive electrode includes a sulfur-based positive-electrode active material containing carbon (C) and sulfur (S), it is possible to inhibit sulfur from eluting out into electrolytic solution, thereby resulting in a sodium secondary battery that makes it feasible to undergo charging and discharging for 100 cycles or more reversibly.