Patents by Inventor Kazuo Shiraishi

Kazuo Shiraishi has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 9656248
    Abstract: Provided is a catalyst having high activity and yield of a target product for producing an unsaturated aldehyde and/or an unsaturated carboxylic acid and further having high mechanical strength. The catalyst is a catalyst prepared by a method in which a catalyst formulation satisfies specified atomic ratios; and in the preparation thereof, a molybdenum component raw material is an ammonium molybdate, a solvent for dissolving the ammonium molybdate is water, a bismuth component raw material is bismuth nitrate, and a solvent for dissolving bismuth nitrate is a nitric acid aqueous solution, and the weight of water for dissolving the ammonium molybdate, the weight of the nitric acid aqueous solution for dissolving the bismuth nitrate, and the acid concentration of the nitric acid aqueous solution are satisfied with specified ranges, respectively.
    Type: Grant
    Filed: May 8, 2014
    Date of Patent: May 23, 2017
    Assignee: Nippon Kayaku Kabushiki Kaisha
    Inventors: Yuuta Nakazawa, Yoshiko Shoya, Masaki Nakahara, Eiji Nishimura, Kazuo Shiraishi, Tatsuhiko Kurakami, Ryota Hiraoka
  • Patent number: 9440904
    Abstract: Provided is a method capable of producing acrolein and/or acrylic acid, or methacrolein and/or methacrylic acid, stably in a high yield over a long period of time advantageously even in a high-load reaction, and the method is a method in which when preparing two or more kinds of catalysts having different formulations and stacking two or more layers in the axial direction of the tube, the catalysts are filled in such a manner that not only the component amount of bismuth relative to molybdenum decreases from the gas inlet side toward the gas outlet side, but also the component amount of iron relative to molybdenum increases from the gas inlet side toward the gas outlet side.
    Type: Grant
    Filed: July 17, 2014
    Date of Patent: September 13, 2016
    Assignee: Nippon Kayaku Kabushiki Kaisha
    Inventors: Yuuta Nakazawa, Tatsuhiko Kurakami, Kazuo Shiraishi
  • Publication number: 20160145181
    Abstract: Provided is a method capable of producing acrolein and/or acrylic acid, or methacrolein and/or methacrylic acid, stably in a high yield over a long period of time advantageously even in a high-load reaction, and the method is a method in which when preparing two or more kinds of catalysts having different formulations and stacking two or more layers in the axial direction of the tube, the catalysts are filled in such a manner that not only the component amount of bismuth relative to molybdenum decreases from the gas inlet side toward the gas outlet side, but also the component amount of iron relative to molybdenum increases from the gas inlet side toward the gas outlet side.
    Type: Application
    Filed: July 17, 2014
    Publication date: May 26, 2016
    Inventors: Yuuta Nakazawa, Tatsuhiko Kurakami, Kazuo Shiraishi
  • Publication number: 20160059218
    Abstract: Provided is a catalyst having high activity and yield of a target product for producing an unsaturated aldehyde and/or an unsaturated carboxylic acid and further having high mechanical strength. The catalyst is a catalyst prepared by a method in which a catalyst formulation satisfies specified atomic ratios; and in the preparation thereof, a molybdenum component raw material is an ammonium molybdate, a solvent for dissolving the ammonium molybdate is water, a bismuth component raw material is bismuth nitrate, and a solvent for dissolving bismuth nitrate is a nitric acid aqueous solution, and the weight of water for dissolving the ammonium molybdate, the weight of the nitric acid aqueous solution for dissolving the bismuth nitrate, and the acid concentration of the nitric acid aqueous solution are satisfied with specified ranges, respectively.
    Type: Application
    Filed: May 8, 2014
    Publication date: March 3, 2016
    Inventors: Yuuta Nakazawa, Yoshiko Shoya, Masaki Nakahara, Eiji Nishimura, Kazuo Shiraishi, Tatsuhiko Kurakami, Ryota Hiraoka
  • Patent number: 8969618
    Abstract: A catalyst and a catalyst packing schedule are designed so that a relation between the raw material conversion rate at which the yield of the objective product becomes maximum and the raw material conversion rate at which a high and low correlation between maximum temperature of the catalyst layer present closest to a reaction gas inlet side Zin and maximum temperature of the catalyst layer present closest to a reaction gas outlet side Zout is reversed satisfies a specific condition of 0.5?Cmax?Ccrs?5, in which Cmax: a raw material conversion rate at which yield of the objective products becomes maximum; and Ccrs: a raw material conversion rate at which, when maximum temperature of the catalyst layer Zin is regarded as Tin, maximum temperature of the catalyst layer Zout is regarded as Tout, and the raw material conversion rate is changed, a high and low correlation between Tin and Tout is reversed.
    Type: Grant
    Filed: January 16, 2012
    Date of Patent: March 3, 2015
    Assignee: NipponKayaku Kabushiki Kaisha
    Inventors: Tatsuhiko Kurakami, Susumu Matsumoto, Atsushi Sudo, Kazuo Shiraishi, Masashi Hashiba
  • Publication number: 20130310604
    Abstract: There is provided a process for producing aerolein, acrylic acid, methacrolein, methacrylic acid in a safe and steady manner and in high yields, which avoids a phenomenon of occurrence of an abnormal reaction attributable to the fact that the temperature at a raw material gas outlet side becomes considerably higher than the temperature at a raw material gas inlet side, with regard to the temperature of a catalyst packed in a reaction tube at vapor-phase catalytic oxidation of propylene, isobutylene, or the like.
    Type: Application
    Filed: January 16, 2012
    Publication date: November 21, 2013
    Applicant: NIPPONKAYAKU KABUSHIKIKAISHA
    Inventors: Tatsuhiko Kurakami, Susumu Matsumoto, Atsushi Sudo, Kazuo Shiraishi, Masashi Hashiba
  • Patent number: 8586785
    Abstract: An object of the present invention is to provide a process for stably producing a catalyst for methacrylic acid production exhibiting high activity and high performance. The process for producing a catalyst for methacrylic acid production of the invention is characterized in that the water content of the catalyst ingredient powder for use in molding, temperature and humidity of a molding step, humidity and temperature of a baking step are individually controlled in the case where molding is performed by a coating method using an Mo—V—P—Cu-based hetero polyacid as an active ingredient and water or an alcohol and/or an aqueous solution of an alcohol as a binder.
    Type: Grant
    Filed: November 17, 2011
    Date of Patent: November 19, 2013
    Assignee: NipponKayaku KabushikiKaisha
    Inventors: Atsushi Sudo, Kazuo Shiraishi, Hideki Sugi, Hiroyoshi Nowatari, Fumio Sakai, Tomoaki Kobayashi, Tatsuhiko Kurakami
  • Publication number: 20120065427
    Abstract: An object of the present invention is to provide a process for stably producing a catalyst for methacrylic acid production exhibiting high activity and high performance. The process for producing a catalyst for methacrylic acid production of the invention is characterized in that the water content of the catalyst ingredient powder for use in molding, temperature and humidity of a molding step, humidity and temperature of a baking step are individually controlled in the case where molding is performed by a coating method using an Mo—V—P—Cu-based hetero polyacid as an active ingredient and water or an alcohol and/or an aqueous solution of an alcohol as a binder.
    Type: Application
    Filed: November 17, 2011
    Publication date: March 15, 2012
    Applicant: NIPPONKAYAKU KABUSHIKIKAISHA
    Inventors: Atsushi Sudo, Kazuo Shiraishi, Hideki Sugi, Hiroyoshi Nowatari, Fumio Sakai, Tomoaki Kobayashi, Tatsuhiko Kurakami
  • Patent number: 6852203
    Abstract: A three-dimensional periodical structure whose period is about 1 ?m or smaller is provided. At least two kinds of films which have two-dimensionally substantially periodical projections are successively formed in layers substantially periodical to construct structure which is substantially three-dimensionally periodical. For instance, the films are made of materials different in refractive index. The three-dimensional periodical structure whose period is about 1 ?m or smaller can be obtained by a simple fabricating method. By this structure, the propagation of a wave with a specific wavelength in many solid angular directions including several axial directions parallel to the plane and the thickness direction of the layers can be cut off.
    Type: Grant
    Filed: March 24, 1998
    Date of Patent: February 8, 2005
    Assignee: Autocloning Technology, LTD
    Inventors: Shojiro Kawakami, Hiroyuki Sakaki, Kazuo Shiraishi
  • Patent number: 6349162
    Abstract: Disclosed is a field distribution converting optical fiber which can be massproduced and enables mutual conversion elliptical field distribution to circular field distribution or vice versa, and a laser diode module in which the field distribution converting optical fiber is used. The optical axis is assumed to be Z, either of the refractive index profiles of a core in the X and Y directions of the orthogonal three axes X, Y and Z is made into a square-law distribution profile, a slope of the refractive index profile in the corresponding X direction is made different from a slope of the refractive index profile in the Y direction. The optical axis propagating in the XZ and XY planes is caused to cyclically change in the Z direction, wherein these cycles are made different from each other to cause the cross-sectional profile of the field distribution of the optical fiber to be cyclically changed.
    Type: Grant
    Filed: October 26, 1999
    Date of Patent: February 19, 2002
    Assignee: The Furukawa Electric Co., Ltd.
    Inventors: Kazuo Shiraishi, Isamu Oishi
  • Patent number: 6130972
    Abstract: A lensed optical fiber and a semiconductor laser module, characterized in that first and second optical fibers, each including a core and a cladding, are connected to one end of a single-mode fiber, including a core and a cladding, in the order named. The core of the first optical fiber has a first square-low index distribution and a length substantially equal to 1/4 of the meandering period of light propagating through the core or an odd multiple thereof. The core of the second optical fiber has a second square-low index distribution and a meandering period different from that of the first optical fiber.
    Type: Grant
    Filed: January 28, 1999
    Date of Patent: October 10, 2000
    Assignee: The Furukawa Electric Co., Ltd.
    Inventors: Kazuo Shiraishi, Isamu Ohishi
  • Patent number: 6028220
    Abstract: The present invention concerns a method for producing acrolein and acrylic acid by carrying out vapor phase catalytic oxidation of propylene with molecular oxygen or a gas containing molecular oxygen using a oxidation catalysts comprising Mo, Bi and Fe as an essentially element and a fixed bed multitubular reactor, which comprisesa) using a plurality of supported catalysts having different activities, which was obtained, for example, by different calcination method in the production process of the supported catalysts,b) setting a catalyst layer in a reaction tube, which is formed by dividing it into plural portions in the tube axial direction, andc) arranging the aforementioned plural supported catalysts in such order that the activity becomes high toward the outlet from the inlet of the material gas in the reaction tube axial direction.
    Type: Grant
    Filed: July 28, 1998
    Date of Patent: February 22, 2000
    Assignee: Nippon Kayaku Kabushiki Kaisha
    Inventors: Koichi Wada, Yoshimasa Seo, Akira Iwamoto, Atsushi Sudo, Fumio Sakai, Kazuo Shiraishi, Hiroyoshi Nowatari
  • Patent number: 6024563
    Abstract: A device which allows easy observation of discrepancies between the upper and lower jaw comprises an upper bow (100) and a lower bow (200) which separately hold in place an upper jaw model (UM) and a lower jaw model (LM) prepared based on impressions and position these upper and lower jaw models (UM) and (LM) opposite to each other, checker pins (310) in the upper bow (200) which are positioned at a location corresponding to the opening/closing axis of the upper jaw model (UM) and lower jaw model (LM) and along the opening/closing axis, and checker plates (300) in the upper bow (100) positioned in such a manner that their outer surfaces (306) are perpendicular to the opening/closing axis and adjacent to the tips of the checker pins (310).
    Type: Grant
    Filed: July 10, 1997
    Date of Patent: February 15, 2000
    Assignee: Sankin Kogyo Kabushiki Kaisha
    Inventors: Kazuo Shiraishi, Akihiko Tashiro, Tadashi Kimura
  • Patent number: 5959143
    Abstract: A catalyst having a high activity and mechanical strength and a process for preparing it are provided. The catalyst comprises molybdenum, vanadium, copper and antimony as essential components. The peak in X-ray diffractometry of the catalytically active component with Cu--K.alpha. line is largest at 22.2.+-.0.30.degree. (2.theta.).
    Type: Grant
    Filed: October 30, 1996
    Date of Patent: September 28, 1999
    Assignee: Nippon Kayaku Kabushiki Kaisha
    Inventors: Hideki Sugi, Fumio Sakai, Koichi Wada, Kazuo Shiraishi, Toshitake Kojima, Atsushi Umejima, Yoshimasa Seo
  • Patent number: 5929275
    Abstract: A catalyst for the production of unsaturated aldehyde and unsaturated acid, obtained by loading a catalytically active component on a carrier and calcining the loaded catalyst, characterized by an average particle diameter of the catalyst of 4 to 16 mm, an average particle diameter of the carrier of 3 to 12 mm, a calcining temperature of 520 to 600.degree. C. and an amount of the catalytically active component loaded on the carrier of 5 to 80% by weight ?weight of the catalytically active component)/(weight of the catalytically active component+weight of the carrier+weight of a strength improver)!, and a process for producing unsaturated aldehyde and unsaturated acid with the catalyst.
    Type: Grant
    Filed: May 9, 1997
    Date of Patent: July 27, 1999
    Assignee: Nippon Kayaku Co., Ltd.
    Inventors: Koichi Wada, Akira Iwamoto, Yoshimasa Seo, Atsusi Sudo, Fumio Sakai, Kazuo Shiraishi, Hideaki Miki
  • Patent number: 5848203
    Abstract: An optical isolator for preventing reflection-returned light from entering back into the emitter of an optical system such as an optical fiber communication or an optical disc input/output device, using semiconductor laser. The polarization-independent optical isolator includes a light-emitting side optical fiber having a diameter of a core expanded to give a mode field diameter at an end face of 20 to 50 .mu.m, a light-incident side optical fiber having a diameter of a core expanded to give a mode field diameter at an end face of 20 to 50 .mu.
    Type: Grant
    Filed: February 4, 1997
    Date of Patent: December 8, 1998
    Assignees: Sumitomo Osaka Cement Co., Ltd., Shojiro Kawakami, Kazuo Shiraishi
    Inventors: Shojiro Kawakami, Kazuo Shiraishi, Masashi Shimo
  • Patent number: 5774607
    Abstract: A lensed-fiber including a single-mode fiber having a core and a cladding, a coreless fiber having a coreless isotropic refractive index and a convex surface at a first end thereof, and a square-law index fiber having a square-law index profile. The square-law index fiber is positioned between the single-mode fiber and the coreless fiber so as to connect an end of the single-mode fiber to a second end of the coreless fiber. The lensed-fiber may be arranged in a optical module facing an optical semiconductor element which emits a light beam to be propagated through the single-mode fiber.
    Type: Grant
    Filed: September 27, 1996
    Date of Patent: June 30, 1998
    Assignee: The Furukawa Electric Co., Ltd.
    Inventors: Kazuo Shiraishi, Kazuhito Matsumura, Isamu Ohishi
  • Patent number: 5716895
    Abstract: A simple and excellent process for the regeneration of heteropolyacid catalysts can be provided. A heteropolyacid catalyst, e.g. a phosphomolybdic acid catalyst, whose activity has been lowered can be regenerated by dissolving and/or suspending it in an aqueous medium and then treating with an inorganic ion-exchange material, e.g. crystalline antimonic acid.
    Type: Grant
    Filed: June 2, 1997
    Date of Patent: February 10, 1998
    Assignee: Nippon Kayaku Kabushiki Kaisha
    Inventors: Hideki Sugi, Kazuo Shiraishi, Atsushi Sudo
  • Patent number: 5446816
    Abstract: An optical fiber having a lens formed at an end thereof comprises a fiber body including a core and a cladding, and an incident light guide portion having a uniform refractive index and integrally formed at an end portion of the fiber body, wherein the incident light guide portion has a convex surface, and the core has a distal end located within the incident light guide portion at a position close to a focal point of the incident light guide portion.
    Type: Grant
    Filed: August 1, 1994
    Date of Patent: August 29, 1995
    Assignee: The Furukawa Electric Co., Ltd.
    Inventors: Kazuo Shiraishi, Kazuhito Matsumura, Isamu Oishi, Katsuo Ebine
  • Patent number: 5267078
    Abstract: An optical isolator comprising an optical isolator unit having a structure depending on a plane of polarization of incident light, a first optical system for splitting the incident light into two polarized components for incidence on the optical isolator unit, and a second optical system for combining the two polarized components emerging from the optical isolator unit. The optical isolator can thus manifest an excellent effect of isolation without considering the plane of polarization of the incident light.
    Type: Grant
    Filed: August 18, 1992
    Date of Patent: November 30, 1993
    Assignees: Kazuo Shiraishi, Sumitomo Metal Mining Co., Ltd.
    Inventors: Kazuo Shiraishi, Kazuhiro Nakajima, Yasuo Numajiri