Abstract: The present invention provides an electrolyte capable of improving charge/discharge cycle performance of a nonaqueous secondary battery containing a lithium-free transition metal sulfide as a cathode active material. The electrolyte is for a nonaqueous secondary battery containing a lithium-free transition metal sulfide as a cathode active material and includes an organic solvent containing a chain carbonate compound, lithium bis(trifluoromethanesulfonyl)imide (LiTFSI), and an additive.

Abstract: An electrolyte solution that satisfies at least one of the following (A) and (B) can improve the charge/discharge cycle performances of nonaqueous secondary batteries containing a lithium-free transition metal sulfide as a cathode active material and can also improve initial coulombic efficiency when a specific additive is used: (A) the nonaqueous secondary battery electrolyte solution contains an organic solvent containing a cyclic carbonate compound, and the content of the cyclic carbonate compound is 80 to 100 vol %, and the content of a chain carbonate compound is 0 to 20 vol %, based on the total amount of the organic solvent taken as 100 vol %; and (B) the nonaqueous secondary battery electrolyte solution contains an organic solvent containing a cyclic carbonate compound and an additive.

Abstract: Disclosed is an electrolyte solution used for a lithium secondary battery having high capacity, less undergoing aging deterioration of capacity, and also excellent in life characteristic. The electrolyte solution used for a lithium secondary battery contains a compound having a trivalent or higher boron formed by incorporation of a boroxine compound represented by (RO)3(BO)3 in which R(s) each represent independently an organic group of 1 to 6 carbon atoms and LiPF6, and a non-aqueous solvent.

Abstract: Provided is a technique of achieving a longer-life lithium ion secondary battery. The lithium ion secondary battery includes a cathode including a cathode active material containing Mn, an anode including an anode active material containing graphite and non-aqueous electrolytic solution including electrolyte, and LiBF4 and LiPF6 are allowed to coexist in the non-aqueous electrolytic solution. Especially preferably LiPF6 is contained more than LiBF4 in the electrolytic solution. Preferably the electrolytic solution further includes iodide salt. As a result, an oxide of phosphor and boron is deposited on the cathode, thus preventing elution of Mn included in the cathode. The amount of these electrolytes is preferably in the decreasing order of phosphor, boron and then iodine.

Abstract: Disclosed is an electrolyte solution used for a lithium secondary battery having high capacity, less undergoing aging deterioration of capacity, and also excellent in life characteristic. The electrolyte solution used for a lithium secondary battery contains a compound having a trivalent or higher boron formed by incorporation of a boroxine compound represented by (RO)3(BO)3 in which R(s) each represent independently an organic group of 1 to 6 carbon atoms and LiPF6, and a non-aqueous solvent.

Abstract: A cathode material for a lithium secondary battery capable of stably suppressing manganese dissolution even under high temperature and voltage conditions is provided. Further, by using the cathode material for a lithium secondary battery, a lithium secondary battery excellent in a charge/discharge cycle profile at a high temperature and a secondary battery module equipped with the battery are provided. The cathode material for a lithium secondary battery comprises a lithium manganese composite oxide and a coating layer formed on the surface of the lithium manganese composite oxide. The coating layer includes an oxide compound or a fluoride compound each containing M (wherein, M is at least one element selected from the group of Mg, Al and Cu), and a phosphorous compound. An atomic density of M at the side of the lithium manganese composite oxide in the coating layer is higher than an atomic density of M at the side of a surface layer of the coating layer facing to the electrolyte.

Abstract: A lithium ion secondary battery in which a high capacity, as well as a high level of safety, is achieved, by using an oxide material containing Li and Fe for a negative electrode active material. In the lithium ion secondary battery, the negative electrode active material is a mixed phase of LiFeO2 and LiFe5O8 and a material in which the value calculated as the ratio of the height of a diffraction peak belonging to LiFeO2 (200) plane and the height of a diffraction peak belonging to LiFe5O8 (311) plane, which are obtained by X-ray diffraction method, is 0.18 to 20.4.

Abstract: An object of the invention is to reduce the charging overvoltage by using a positive electrode member which does not contain a carbon material that causes the generation of lithium carbonate (Li2CO3), and which comprises a metal porous material, thereby suppressing the formation of lithium carbonate (Li2CO3). The metal air secondary battery of the invention is characterized by having a negative electrode member which has metal ions occluded therein and emits metal ions, a positive electrode member which ionizes oxygen, and a separator which is impregnated with an electrolyte and disposed between the negative electrode member and the positive electrode member, wherein the carbon weight in the total weight of a carrier, a catalyst, and a binder constituting the positive electrode member is 50% or less.

Abstract: Disclosed is a negative electrode active material for lithium-ion secondary batteries which contributes to high capacity, high energy density, and safety and a lithium-ion secondary battery provided with the negative electrode active material. The negative electrode active material is an oxide containing Li and Fe and having crystalline and amorphous phases of LiFeO2 such that there is a specific ratio ranging from 13.2 to 100 between peak value of X-ray diffraction due to the plane of the crystalline phase and peak value of X-ray diffraction due to the amorphous phase. The negative electrode active material is produced by preparing a mixture of LiOH.H2O and FeOOH and heating it together with distilled water in an autoclave at 180 to 220° C. for 10 to 20 hours, thereby giving an oxide having the crystalline and amorphous phases of LiFeO2 or an oxide having the crystalline and amorphous phases of LiFeO2 and LiFe5O8.

Abstract: A nonaqueous electrolyte and a lithium-ion secondary battery using the same, wherein a mixture of a cyclic carbonate, a chain carbonate, a first phosphoric acid ester wherein bonding between carbons is a single bond, and a second phosphoric acid ester wherein bonding between carbons contains a double bond is used as the nonaqueous electrolyte. It is desirable that the first phosphoric acid ester is a trimethyl phosphate. In addition, it is desirable that the second phosphoric acid ester is a dimethylisopropenyl phosphate.

Abstract: A non-aqueous electrolyte and a lithium secondary battery using the same are provided, which satisfy both flame retardancy and charge-discharge cycle characteristics, and attain a longer lifetime of the battery. A mixture of a chain carbonate, vinylene carbonate, a fluorinated cyclic carbonate and a phosphate ester is used as the non-aqueous electrolyte. It is desirable that the phosphate ester includes trimethyl phosphate and a fluorinated phosphate ester. Further, it is desirable that ethylene carbonate is further contained.

Abstract: Provided is a technique of achieving a longer-life lithium ion secondary battery. The lithium ion secondary battery includes a cathode including a cathode active material containing Mn, an anode including an anode active material containing graphite and non-aqueous electrolytic solution including electrolyte, and LiBF4 and LiPF6 are allowed to coexist in the non-aqueous electrolytic solution. Especially preferably LiPF6 is contained more than LiBF4 in the electrolytic solution. Preferably the electrolytic solution further includes iodide salt. As a result, an oxide of phosphor and boron is deposited on the cathode, thus preventing elution of Mn included in the cathode. The amount of these electrolytes is preferably in the decreasing order of phosphor, boron and then iodine.

Abstract: The present invention aims to improve the fire resistance of an electrolytic solution used for a lithium-ion battery and improve the life characteristics of the lithium-ion battery. In the lithium ion battery of the present invention, specific amounts of ethylene carbonate and dimethyl carbonate are used for a non-aqueous electrolytic solution, and trimethyl phosphate is added thereto. Specifically, the non-aqueous electrolytic solution contains 60 vol % or more of ethylene carbonate (EC) and dimethyl carbonate (DMC). The volume ratio of DMC to the sum of EC and DMC is 0.3 to 0.6, and the non-aqueous electrolytic solution contains 3 to 5 wt % of trimethyl phosphate (TMP) with respect to the total weight of the non-aqueous electrolytic solution. Such a non-aqueous electrolytic solution has an effect of improving the self-fire extinguishing property, and thus improves the safety of the lithium-ion battery.

Abstract: To provide a lithium secondary battery excellent in the life characteristic and the power density. A lithium secondary battery, comprising: a positive electrode capable of intercalating and deintercalating lithium; and an negative electrode capable of intercalating and deintercalating lithium, wherein the positive electrode contains a manganese-containing positive electrode active material of a spinel structure and an oxide that coats the surface of this positive electrode active material, wherein the oxide contains a metallic element, wherein the metallic element forms a solid solution with the positive electrode active material, and wherein the atomic concentration of the metallic element is approximately 0 at depths of from 50 to 100 nm from an external surface of the negative electrode.

Abstract: An object of the invention is to reduce the charging overvoltage by using a positive electrode member which does not contain a carbon material that causes the generation of lithium carbonate (Li2CO3), and which comprises a metal porous material, thereby suppressing the formation of lithium carbonate (Li2CO3). The metal air secondary battery of the invention is characterized by having a negative electrode member which has metal ions occluded therein and emits metal ions, a positive electrode member which ionizes oxygen, and a separator which is impregnated with an electrolyte and disposed between the negative electrode member and the positive electrode member, wherein the carbon weight in the total weight of a carrier, a catalyst, and a binder constituting the positive electrode member is at least 50% or less.

Abstract: To provide a lithium secondary battery excellent in the life characteristic and the power density. A lithium secondary battery, comprising: a positive electrode capable of intercalating and deintercalating lithium; and an negative electrode capable of intercalating and deintercalating lithium, wherein the positive electrode contains a manganese-containing positive electrode active material of a spinel structure and an oxide that coats the surface of this positive electrode active material, wherein the oxide contains a metallic element, wherein the metallic element forms a solid solution with the positive electrode active material, and wherein the atomic concentration of the metallic element is approximately 0 at depths of from 50 to 100 nm from an external surface of the negative electrode.

Abstract: To provide a lithium secondary battery which suppresses a decrease in the charge and discharge efficiency during a battery storage test and which is excellent in maintaining the battery capacity after the storage test.

Abstract: A positive electrode material for a lithium-ion secondary battery that can stably inhibit heat generation, a lithium-ion secondary battery comprising the positive electrode material for a lithium-ion secondary battery as a positive electrode material that is excellent in safety during charging, and a secondary battery module using the lithium-ion secondary battery are provided. The positive electrode material for a lithium-ion secondary battery of the present invention is characterized in that: a coating layer comprising a phosphate compound and an oxide or fluoride containing A (where A denotes at least one element selected from the group consisting of Mg, Al, Ti, and Cu) is formed on a layered lithium-manganese composite oxide represented by the following formula: LiMnxM1-xO2 (where 0.1?x?0.

Abstract: A nonaqueous electrolyte and a lithium-ion secondary battery using the same, wherein a mixture of a cyclic carbonate, a chain carbonate, a first phosphoric acid ester wherein bonding between carbons is a single bond, and a second phosphoric acid ester wherein bonding between carbons contains a double bond is used as the nonaqueous electrolyte. It is desirable that the first phosphoric acid ester is a trimethyl phosphate. In addition, it is desirable that the second phosphoric acid ester is a dimethylisopropenyl phosphate.

Abstract: The present invention provides a battery that experiences a small degree of temporal change from the initial battery properties over the long term storage period of the battery. Specifically, the present invention provides a lithium secondary battery, in which a positive electrode capable of storing and releasing lithium and a negative electrode capable of storing and releasing lithium are formed via an electrolyte, wherein: the electrolyte comprises a cyclic solvent and a chain-type solvent and contains a compound having a boron-oxygen bond (B—O) and a carbon-carbon double bond (C?C).