Patents by Inventor Kazutoshi Miyazawa

Kazutoshi Miyazawa has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5948318
    Abstract: Liquid crystal compositions which have a low threshold voltage, excellent miscibility at low temperatures, and a wide range of a nematic phase while satisfying various characteristics required of liquid crystal compositions for active matrix mode liquid crystal display devices. The compositions contain, as a first component, at least one compound expressed by any one of formulas ##STR1## and as a second component, at least one compound expressed by any one of formulas ##STR2## wherein each of the formulas, X represents CF.sub.3 or OCF.sub.3, each Y represents, independently of each other, a hydrogen or fluorine atom, m is 1 or 2, and n is an integer or 1 to 10.
    Type: Grant
    Filed: August 15, 1996
    Date of Patent: September 7, 1999
    Assignee: Chisso Corporation
    Inventors: Kazutoshi Miyazawa, Shuichi Matsui, Tomoyuki Kondo, Takashi Kato, Yasuko Sekiguchi, Etsuo Nakagawa
  • Patent number: 5922243
    Abstract: A liquid crystal composition which comprises at least one phenylbenzoate derivative represented by formula (1) ##STR1## wherein R.sub.1 is a hydrogen atom or an alkyl group of 1-10 carbons and others; X is a hydrogen atom or a halogen atom; A and B each independently represent a 1,4-phenylene group or a trans-1,4-cyclohexylene group and others; Z.sub.1 and Z.sub.2 each independently represent --CH.sub.2 CH.sub.2 --, --CO--O--, a covalent bond and others; m and n each independently represent 0 or 1.
    Type: Grant
    Filed: August 11, 1997
    Date of Patent: July 13, 1999
    Assignee: Chisso Corporation
    Inventors: Shuichi Matsui, Tomoyuki Kondo, Kazutoshi Miyazawa, Noriyuki Ohnishi, Yasuyuki Goto, Etsuo Nakagawa, Shinichi Sawada
  • Patent number: 5879585
    Abstract: A liquid crystalline compound having a remarkably high .DELTA.n and good miscibility with other liquid crystalline compounds, and expressed by the general formula (1) ##STR1## wherein R.sub.1 represents, for example, a halogen atom, cyano group, or an alkyl or alkenyl group of 1 to 15 carbon atoms in which alkyl or alkenyl group hydrogen atom may be replaced, for example, by fluorine atom, and one or not-adjacent two or more methylene groups may be replaced by oxygen atom, --CH.dbd.CH-- or --C.tbd.C--; R.sub.2 represents an alkyl group of 1 to 10 carbon atoms or hydrogen atom; rings A.sub.1, A.sub.2, A.sub.3, and A.sub.4 independently represent, for example, 1,4-cyclohexylene or 1,4-phenylene in which hydrogen atom may be replaced by a halogen atom or cyano group; Z.sub.1, Z.sub.2, and Z.sub.3 independently represent, for example, a covalent bond or --CH.sub.2 CH.sub.2 --; s and t are 0 or 1; u is an integer of 1 to 5; and each of the elements in the general formula may be its isotope.
    Type: Grant
    Filed: October 10, 1997
    Date of Patent: March 9, 1999
    Assignee: Chisso Corporation
    Inventors: Kazutoshi Miyazawa, Shuichi Matsui, Hiroyuki Takeuchi, Yasuhiro Kubo, Fusayuki Takeshita, Etsuo Nakagawa
  • Patent number: 5858272
    Abstract: There is provided an electrically and chemically stable liquid crystalline compound which exhibits a significantly large value of De and a high voltage holding ratio. The compound is a phenyldioxane derivative represented by formula (1): ##STR1## wherein R represents a C1-C20 alkyl group; each of n1 and n2 represents 0 or 1; each of Q.sub.1 through Q.sub.6 represents a hydrogen atom, a fluorine atom, or a chlorine atom, provided that Q.sub.3 is a fluorine atom or a chlorine atom when n2 is 0, and that at least one of Q.sub.1 and Q.sub.3 is a fluorine atom or a chlorine atom when n2 is 1; each of Za and Zb represents a single bond, --COO--, or --CF.sub.2 O--; Zc represents a single bond or --CH.sub.2 CH.sub.2 --; Y represents a hydrogen atom, a halogen atom, or a C1-C5 halogenated alkyl group in which one or more non-adjacent methylene groups may be replaced by oxygen atoms or sulfur atoms; and each of the elements that constitute the compound may comprise isotopes of the element.
    Type: Grant
    Filed: July 15, 1997
    Date of Patent: January 12, 1999
    Assignee: Chisso Corporation
    Inventors: Yasuhiro Haseba, Shuichi Matsui, Kazutoshi Miyazawa, Hiroyuki Takeuchi, Yasusuke Hisatsune, Fusayuki Takeshita, Etsuo Nakagawa
  • Patent number: 5858270
    Abstract: In order to provide novel compounds which are useful as liquid crystal materials for low voltages in several liquid crystal displays, have a large dielectric anisotropy, and are low in viscosity; and to improve characteristics of liquid crystal compositions, difluorooxymethane derivatives expressed by the following general formula (I) and liquid crystal compositions containing the compound are proposed ##STR1## wherein each of l, m, and n is 0 or 1, rings A.sub.1 to A.sub.3 independently represent six-membered rings such as trans-1,4-cyclohexylene and 1,4-phenylene, Z.sub.1 to Z.sub.3 independently represent a bonding group such as covalent bond and --CH.sub.2 CH.sub.2 --, L.sub.1 to L.sub.4 independently represent hydrogen atom or halogen atom, and X represents a group such as halogen atom and OCF3.They are useful as liquid crystal materials for low voltages in several modes such as active matrix mode and STN mode.
    Type: Grant
    Filed: January 30, 1997
    Date of Patent: January 12, 1999
    Assignee: Chisso Corporation
    Inventors: Shuichi Matsui, Kazutoshi Miyazawa, Noriyuki Ohnishi, Yasuhiro Haseba, Yasuyuki Goto, Etsuo Nakagawa, Shinichi Sawada
  • Patent number: 5858275
    Abstract: Chlorobenzene derivatives which have the following four-ring structure and are preferably usable for display devices of active matrix mode, and liquid crystal compositions comprising the derivative are provided: ##STR1## wherein ring A, ring B, and ring C independently represent trans-1,4-cyclohexylene group or 1,4-phenylene group, one or more hydrogen atoms on the six-membered ring of which may be replaced by halogen atoms, Z.sub.1, Z.sub.2, and Z.sub.3 represent --CH.sub.2 CH.sub.2 -- or single bond, respectively, provided that at least one of them represents --CH.sub.2 CH.sub.2 --, L.sub.1 and L.sub.2 represent H or halogen atom, and R represents an alkyl group or alkoxy group having 1 to 10 carbon atoms, provided that when Z.sub.1 and Z.sub.3 represent single bond and Z.sub.2 represents --CH.sub.2 CH.sub.2 --, ring A represents 1,4-phenylene group, and when Z.sub.1 and Z.sub.2 represent single bond, and Z.sub.3 represents --CH.sub.2 CH.sub.
    Type: Grant
    Filed: March 10, 1997
    Date of Patent: January 12, 1999
    Assignee: Chisso Corporation
    Inventors: Shuichi Matsui, Tomoyuki Kondo, Kazutoshi Miyazawa, Yasuyuki Goto, Etsuo Nakagawa, Shinichi Sawada
  • Patent number: 5855814
    Abstract: A liquid crystal composition which comprises as a first component at least one or more compounds represented by formula (1') ##STR1## wherein n represents an integer of 1-10; X represents H or F; or m represents 1 or 2 and as a second component at least one or more compounds represented by formulas (2-1) to (2-5) in which n represents an integer of 1-10.
    Type: Grant
    Filed: August 11, 1997
    Date of Patent: January 5, 1999
    Assignee: Chisso Corporation
    Inventors: Shuichi Matsui, Tomoyuki Kondo, Kazutoshi Miyazawa, Noriyuki Ohnishi, Yasuyuki Goto, Etsuo Nakagawa, Shinichi Sawada
  • Patent number: 5833879
    Abstract: A novel liquid crystalline compound having a sufficiently large .DELTA.n, a superior, low temperature compatibility with other liquid crystals and a chemical stability; a liquid crystal composition containing the above compound; and a display element using the above liquid crystal composition are provided,which liquid crystalline compound is expressed by the formula (1): ##STR1## wherein R.sub.1 is an alkyl group or alkoxy group of 1 to 10C, cyano group or a halogen atom; R.sub.2 is an alkyl group of 1 to 5C wherein one methylene group (--CH.sub.2 --) may be replaced by oxygen atom; X.sub.1 and X.sub.2 each independently are hydrogen atom or a halogen atom; A and B each independently are single bond, 1,4-phenylene ring or 1,4-cyclohexylene ring which may be substituted by halogen atom may be; and p is 1 to 5.
    Type: Grant
    Filed: February 12, 1996
    Date of Patent: November 10, 1998
    Assignee: Chisso Corporation
    Inventors: Kazutoshi Miyazawa, Shuichi Matsui, Yasuko Sekiguchi, Etsuo Nakagawa
  • Patent number: 5820784
    Abstract: A liquid crystal composition is disclosed which contains, as the first component, at least one compound expressed by the formula (I-a) or (I-b) and contains, as the second component, at least one compound expressed by any one of the formulas (II-a) to (II-g), each of the formulas being recited in the specification. According to the present invention, a liquid crystal composition which is particularly excellent in compatibility in low temperatures, and has a suitably large .DELTA.n and a small V.sub.th can be provided while satisfying several characteristics required for liquid crystal compositions for AM-LCD.
    Type: Grant
    Filed: February 22, 1996
    Date of Patent: October 13, 1998
    Assignee: Chisso Corporation
    Inventors: Tomoyuki Kondo, Shuichi Matsui, Yasuyuki Koizumi, Koichi Shibata, Yasuhiro Haseba, Norihisa Hachiya, Etsuo Nakagawa, Kazutoshi Miyazawa
  • Patent number: 5792386
    Abstract: Liquid crystal compositions are provided which have a particularly excellent miscibility at low temperatures, properly large .DELTA.n, and small Vth and viscosity while satisfying several characteristics required of liquid crystal composition for AM-LCD.Disclosed are liquid crystal compositions containing, as a first component, at least one compound expressed by general formula either (I-1) or (I-2), and containing, as a second component, at least one compound expressed by any one of general formulas (II-1) to (II-7) ##STR1## wherein n is an integer of 1 to 10, Z.sup.1 represents --CH.sub.2 CH.sub.2 -- or single bond, X represents F or OCF.sub.3, Y represents H or F, and m is 0 or 1.The liquid crystal compositions of the present invention are useful as liquid crystal material for low voltage in several modes such as active matrix mode and STN mode.
    Type: Grant
    Filed: April 29, 1997
    Date of Patent: August 11, 1998
    Assignee: Chisso Corporation
    Inventors: Shuichi Matsui, Kazutoshi Miyazawa, Noriyuki Ohnishi, Yasuhiro Haseba, Yasuyuki Goto, Etsuo Nakagawa, Shinichi Sawada
  • Patent number: 5779936
    Abstract: A liquid crystalline compound expressed by the general formula (1) ##STR1## (wherein R.sub.1 is an alkyl group having 1 to 12 carbon atoms and one CH.sub.2 group in the alkyl group may be replaced by oxygen atom or --CH.dbd.CH--; X represents hydrogen atom or fluorine atom; Y represents hydrogen atom or alkoxy group having 1 to 5 carbon atoms; l and m independently represent 0 or 1, respectively; and n and p independently represent an integer of 0 to 10, respectively, and when p is 0, n is 1 or more, and when Y is an alkoxy group, X is a fluorine atom and p is 0.)Liquid crystal compositions which are suitable for use in liquid crystal display devices, have a high clearing point, and have a function of decreasing viscosity, and novel liquid crystalline compounds useful as a component of the liquid crystal compositions are provided.
    Type: Grant
    Filed: July 24, 1996
    Date of Patent: July 14, 1998
    Assignee: Chisso Corporation
    Inventors: Kazutoshi Miyazawa, Shuichi Matsui, Atsuko Fujita, Tomoyuki Kondo, Yasuyuki Goto, Etsuo Nakagawa, Shinichi Sawada
  • Patent number: 5776367
    Abstract: A novel liquid crystalline compound having a low viscosity and a high elastic constant ratio and at the same time, a superior compatibility with other known liquid crystalline compounds, and a liquid crystal composition and a liquid crystal display element containing the novel compound, are provided.The compound is an alkenylcyclohexane derivative expressed by the formula (1): ##STR1## wherein R.sup.1 and R.sup.2 represent a linear or branched alkyl group of 1 to 15 carbon atoms or alkenyl group of 2 to 15 carbon atoms; at least one of R.sup.1 and R.sup.2 represents an alkenyl group; in these groups, one or more non-adjacent CH.sub.2 groups may be replaced by oxygen atom, sulfur atom or --C.tbd.C-- group; ring A.sup.1, ring A.sup.2 and ring A.sup.3 each independently represent 1,4-cyclohexylene group wherein one or more CH.sub.2 groups on the ring may be replaced by oxygen atom or sulfur atom, or 1,4-phenylene group wherein one or more CH groups on the ring may be replaced by nitrogen atom; Z.sup.1 and Z.sup.
    Type: Grant
    Filed: June 19, 1996
    Date of Patent: July 7, 1998
    Assignee: Chisso Corporation
    Inventors: Shuichi Matsui, Yasuyuki Koizumi, Takashi Kato, Kazutoshi Miyazawa, Norihisa Hachiya, Etsuo Nakagawa
  • Patent number: 5755994
    Abstract: A novel liquid crystalline compound having a large dielectric anisotropy value, a small change in the threshold voltage depending upon temperatures, and an improved solubility in other liquid crystal materials at low temperatures, and a liquid crystal composition containing the compound are provided,which liquid crystalline compound is expressed by the formula (1) ##STR1## wherein R is H or an alkyl group of 1 to 10C; l is an integer of 1 to 9; m, n and o are each independently 0 or 1; A.sub.1, A.sub.2 and A.sub.3 are each independently trans-1,4-cyclohexylene group, 1,4-phenylene group, one or more H atoms on the ring of which group may be replaced by F, or the like group; Z.sub.1, Z.sub.2 and Z.sub.3 are each independently --COO--, etc., but at least one of them is --COO--; X is CF.sub.3, etc.; and Y.sub.1, and Y.sub.2 are each independently H or F.
    Type: Grant
    Filed: February 22, 1996
    Date of Patent: May 26, 1998
    Assignee: Chisso Corporation
    Inventors: Tomoyuki Kondo, Shuichi Matsui, Yasuyuki Koizumi, Koichi Shibata, Yasuhiro Haseba, Norihisa Hachiya, Etsuo Nakagawa, Kazutoshi Miyazawa
  • Patent number: 5733477
    Abstract: A liquid crystal composition satisfying various characteristics required for a liquid crystal composition and at the same time having a low temperature threshold voltage, a superior low temperature compatibility and a broad range of nematic phase is provided. A liquid crystal composition characterized by containing as a first component, at least one compound expressed by the following formula (1): ##STR1## wherein R.sup.1 represents an alkyl group of 1 to 10 carbon atoms or an alkenyl group of 2 to 10 carbon atoms; A.sup.1 represents trans-1,4-cyclohexylene of 1,4-phenylene wherein one or more hydrogens present on its ring may be replaced by F; X represents OCF.sub.3 or CF.sub.3 ; Y represents H or F; and m represents an integer of 0 to 2, and as a second component, at least compound expressed by the following formulas (2-1) to (2-6): ##STR2## wherein R.sup.2 represents an alkyl group of 1 to 10 carbon atoms.
    Type: Grant
    Filed: December 5, 1996
    Date of Patent: March 31, 1998
    Assignee: Chisso Corporation
    Inventors: Tomoyuki Kondo, Yasuhiro Haseba, Yasuyuki Koizumi, Kazutoshi Miyazawa, Norihisa Hachiya, Etsuo Nakagawa
  • Patent number: 5728319
    Abstract: Liquid crystal compositions are provided which have particularly a low threshold voltage, excellent miscibility at low temperatures, and a wide nematic phase range while satisfying several characteristics required of liquid crystal compositions for AM-LCD. The liquid crystal compositions contain, as a first component, at least one compound expressed by either formula (I-1) or (I-2), and as a second component, at least one compound expressed by any one of formulas (II-1) to (II-7) ##STR1## wherein n is an integer of 1 to 10, Z.sub.1 represents --CH.sub.2 CH.sub.2 -- or a single bond, X represents F, OCF.sub.3 or CF.sub.3, and Y represents H or F.
    Type: Grant
    Filed: March 27, 1997
    Date of Patent: March 17, 1998
    Assignee: Chisso Corporation
    Inventors: Shuichi Matsui, Kazutoshi Miyazawa, Noriyuki Ohnishi, Yasuhiro Haseba, Yasuyuki Goto, Etsuo Nakagawa, Shinichi Sawada
  • Patent number: 5723621
    Abstract: A novel process for producing a biaryl compound represented by formula (III), which is useful as a medicine, an agricultural chemical and an electrooptical liquid-crystal display material:Ar--Ar' (III)(wherein Ar and Ar' each independently represents a substituted or unsubstituted aromatic group) which comprises the steps of (i) reacting a trialkoxysilyl-substituted aromatic compound represented by formula (I):Ar--Si(OR).sub.3 (I)(wherein Ar has the same meaning as defined above and R represents an alkyl group having from 1 to 5 carbon atoms) with a fluoride ion source in the presence of a solvent, and then (ii) adding thereto an aromatic compound represented by formula (II):X--Ar' (II)(wherein X represents an eliminating group and Ar' has the same meaning as defined above) and a catalyst comprising a transition metal of tenth group to conduct a further reaction.
    Type: Grant
    Filed: May 14, 1996
    Date of Patent: March 3, 1998
    Assignee: Chisso Corporation
    Inventors: Koichi Shibata, Shuichi Matsui, Kazutoshi Miyazawa
  • Patent number: 5720899
    Abstract: A novel liquid crystalline compound having a high elastic constant ratio (K.sub.33 /K.sub.11) and an improved solubility thereof in other liquid crystal materials, at low temperatures, and a liquid crystal composition containing the same are provided. The liquid crystalline compound is expressed by the formula (1): ##STR1## wherein Q represents CF.sub.3, CF.sub.2 H or CFH.sub.2 ; A.sub.1, A.sub.2 and A.sub.3 each independently represent trans-1,4-cyclohexylene group, 1,4-phenylene group, wherein one or more hydrogen atoms on its six-membered ring may be replaced by F, Cl or CN, pyridine-2,5-diyl group or 1,3-pyrimidine-2,5-diyl; ring B represents 1,4-phenylene group or trans-1,4-cyclohexylene group; Z.sub.1, Z.sub.2 and Z.sub.3 each independently represent covalent bond, --C.dbd.C--, --C.tbd.C--, --OCO--, --COO--, --CH.sub.2 O--, --OCH.sub.2 --, --(CH.sub.2).sub.2 -- or --(CH.sub.2).sub.4 --; l and m each independently represent an integer of 0 to 5; o and p each independently represent 0 or 1; L.sub.1 and L.
    Type: Grant
    Filed: December 30, 1996
    Date of Patent: February 24, 1998
    Assignee: Chisso Corporation
    Inventors: Tomoyuki Kondo, Kazutoshi Miyazawa, Atsuko Fujita, Noriyuki Ohnishi, Yasuyuki Goto, Etsuo Nakagawa, Shinichi Sawada
  • Patent number: 5714088
    Abstract: Liquid crystalline compounds are disclosed which are expressed by the following general formula (1) ##STR1## wherein R.sub.1 represents a branched alkyl group having 3 to 10 carbon atoms, ring A represents 1,4-phenylene group or 1,4-cyclohexylene group, Z.sub.1 and Z.sub.2 independently represent a single bond or 1,2-ethylene group, respectively, X.sub.1, X.sub.2, X.sub.3, and X.sub.4 independently represent fluorine atom or hydrogen atom, respectively, and Y.sub.1 represents oxygen atom or a single bond. The compounds are excellent in compatibility with other liquid crystalline compounds, and have a large positive value of dielectric anisotropy, extremely low viscosity, extremely high specific resistance (high voltage holding ratio), and excellent UV stability.
    Type: Grant
    Filed: March 22, 1996
    Date of Patent: February 3, 1998
    Assignee: Chisso Corporation
    Inventors: Kazutoshi Miyazawa, Shuichi Matsui, Yasuko Sekiguchi, Etsuo Nakagawa
  • Patent number: 5709820
    Abstract: Liquid crystalline alkenyl cyclohexane compounds of formula (I) having a nematic phase over a broad temperature range, a higher elastic constant ratio K.sub.33 /K.sub.11 and a lower viscosity, liquid crystal compositions comprising the above compounds and liquid crystal display elements using the liquid crystal compositions. ##STR1## wherein R.sub.1 is an alkyl group of 1-15 carbons, an alkenyl group of 2-15 carbons or an alkyl or alkenyl group in which at least one of non-adjacent methylene groups (--CH.sub.2 --) is replaced by --O--, --S--, --C.tbd.C-- or --COO--; R.sub.2 is a hydrogen atom or an alkyl group of 1-10 carbons; m is 0-5; when m is 2 or more, any one methylene group in --(CH.sub.2).sub.m -- may be replaced by --O--; and the rings A.sub.1, A.sub.2 and A.sub.3 are independently a 1,4-cyclohexylene, a cyclohexene-1,4-diyl or a 6-membered ring group, one or two --CH.sub.2 -- groups in said rings optionally replaced by --O-- or --S--.
    Type: Grant
    Filed: May 31, 1996
    Date of Patent: January 20, 1998
    Assignee: Chisso Corporation
    Inventors: Takashi Kato, Shuichi Matsui, Kazutoshi Miyazawa, Yasuko Sekiguchi, Etsuo Nakagawa
  • Patent number: 5702641
    Abstract: A liquid crystalline compound exhibiting a large .DELTA..epsilon. value, an electrical and chemical stability and a superior compatibility with existing liquid crystalline compounds, a liquid crystal composition containing the same, and a liquid crystal display element constructed by using the composition are provided,which liquid crystalline compound is expressed by the formula (I),F--(CH.sub.2)n-E--(CH.sub.2 CH.sub.2).sub.k --G--(CH.sub.2 CH.sub.2).sub.l --L--(CH.sub.2 CH.sub.2).sub.
    Type: Grant
    Filed: December 21, 1995
    Date of Patent: December 30, 1997
    Assignee: Chisso Corporation
    Inventors: Yasuhiro Haseba, Kazutoshi Miyazawa, Shuichi Matsui, Tomoyuki Kondo, Yasuyuki Goto, Etsuo Nakagawa, Shinichi Sawada