Patents by Inventor Kazuyuki Hayashi
Kazuyuki Hayashi has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 6130017Abstract: Black non-magnetic composite particles for black toner according to the present invention, comprise:black hematite particles or black iron oxide hydroxide particles as core particles;fine particles which are adhered or exist on at least a part of the surface of each magnetite particle, and comprise oxides, oxide hydroxides or oxides and oxide hydroxides composed of at least one element selected from the group consisting of Si, Zr, Ti, Al and Ce; anda methyl hydrogen polysiloxane coating layer formed on said fine particles or said fine particles and the exposed surface of the magnetite particle,the average particle size of said black non-magnetic composite particles being 0.08 to 1.0 .mu.m.Such black non-magnetic composite particles are suitable for a black toner which can exhibit not only an excellent flowability but also a high volume resistivity.Type: GrantFiled: April 16, 1999Date of Patent: October 10, 2000Assignee: Toda Kogyo CorporationInventors: Kazuyuki Hayashi, Seiji Ishitani, Yasuyuki Tanaka, Hiroko Morii
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Patent number: 6124022Abstract: Acicular hematite particles of the present invention comprise a geometrical standard deviation of major axis diameter of not more than 1.50, a geometrical standard deviation of minor axis diameter of not more than 1.35, a BET specific surface area of 35.9 to 150 m.sup.2 /g and an average major axis diameter of 0.004 to 0.295 .mu.m. Such acicular hematite particles are suitable as non-magnetic particles for a non-magnetic undercoat layer of a magnetic recording medium having a low light transmittance, an excellent smooth surface, a high mechanical strength and an excellent durability.Type: GrantFiled: November 25, 1998Date of Patent: September 26, 2000Assignee: Toda Kogyo CorporationInventors: Kazuyuki Hayashi, Yasuyuki Tanaka, Keisuke Iwasaki, Hiroko Morii
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Patent number: 6120898Abstract: The present invention relates to acicular hematite particles containing aluminum of 0.05 to 50% by weight, calculated as Al, having an average major axial diameter of not more than 0.3 .mu.m and a pH value of the particles of not less than 8, and containing soluble sodium salts of not more than 300 ppm soluble sodium, calculated as Na, and soluble sulfates of not more than 150 ppm soluble sulfate, calculated as SO.sub.4, which have an excellent dispersibility in a binder resin, and a magnetic recording medium which uses the hematite particles as non-magnetic particles for a non-magnetic undercoat layer, which has small light transmittance, smooth surface, high strength and high durability, and which is capable of suppressing the deterioration in the magnetic properties caused by a corrosion of the magnetic particles containing as a main ingredient in the magnetic recording layer.Type: GrantFiled: January 8, 1998Date of Patent: September 19, 2000Assignee: Toda Kogyo CorporationInventors: Kazuyuki Hayashi, Keisuke Iwasaki, Hiroko Morii, Yasuyuki Tanaka
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Patent number: 6117540Abstract: In accordance with the present invention, there are provided non-magnetic black particles composed primarily of Fe and having a hematite structure, which shows an excellent blackness, heat resistance, and dispersibility in a vehicle, and which particles contain manganese in an amount of 5 to 40% by weight based on the weight of the non-magnetic black particles, a soluble sodium salt in an amount of not more than 500 ppm (calculated as Na), and a soluble sulfate in an amount of not more than 200 ppm (calculated as SO.sub.4), and have an average particle size of 0.1 to 10.0 .mu.m and a pH of not less than 5.Type: GrantFiled: January 5, 2000Date of Patent: September 12, 2000Assignee: Toda Kogyo CorporationInventors: Yasuyuki Tanaka, Hiroko Morii, Kazuyuki Hayashi, Hiroshi Sumita
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Patent number: 6087004Abstract: In accordance with the present invention, there are provided non-magnetic black particles composed primarily of Fe and having a hematite structure, which shows an excellent blackness, heat resistance, and dispersibility in a vehicle, and which particles contain manganese in an amount of 5 to 40% by weight based on the weight of the non-magnetic black particles, a soluble sodium salt in an amount of not more than 500 ppm (calculated as Na), and a soluble sulfate in an amount of not more than 200 ppm (calculated as SO.sub.4), and have an average particle size of 0.1 to 10.0 .mu.m and a pH of not less than 5.5.Type: GrantFiled: August 18, 1997Date of Patent: July 11, 2000Assignee: Toda Kogyo CorporationInventors: Yasuyuki Tanaka, Hiroko Morii, Kazuyuki Hayashi, Hiroshi Sumita
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Patent number: 6063490Abstract: A magnetic recording medium of the present invention comprises: a base film; a non-magnetic undercoat layer formed on said base film and comprising a binder resin and non-magnetic acicular particles containing iron as a main component, comprising iron and titanium of 0.05 to 50% by weight, calculated as Ti, based on the total weight of the particles, which is present within the particle; and a magnetic recording layer formed on said non-magnetic undercoat layer and comprising magnetic particles and a binder resin. Such a magnetic recording medium has a low light transmittance, an excellent smooth surface, a high mechanical strength and an excellent durability.Type: GrantFiled: August 12, 1998Date of Patent: May 16, 2000Assignee: Toda Kogyo CorporationInventors: Kazuyuki Hayashi, Keisuke Iwasaki, Toshiharu Harada, Hiroko Morii
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Patent number: 6054201Abstract: The present invention relates to a magnetic recording medium comprising: a non-magnetic substrate; a non-magnetic undercoat layer formed on said non-magnetic substrate, said undercoat layer comprising non-magnetic acicular hematite particles containing 0.05 to 50% by weight of aluminum uniformly within the particles, calculated as Al, based on the total weight of the non-magnetic particles and a binder resin,; and a magnetic recording layer formed on said non-magnetic undercoat layer, said magnetic recording layer comprising magnetic particles containing iron as a main ingredient and a binder resin. The magnetic recording medium has small light transmittance, smooth surface, high strength and high durability.Type: GrantFiled: February 26, 1998Date of Patent: April 25, 2000Assignee: Toda Kogyo CorporationInventors: Kazuyuki Hayashi, Keisuke Iwasaki, Hiroko Morii, Yasuyuki Tanaka
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Patent number: 6042937Abstract: The present invention relates to titanium oxide particles having an average particle size of not more than 0.3 .mu.m, and a BET specific surface area of 15 to 200 m.sup.2 /g, containing a soluble sodium salt of not more than 230 ppm, calculated as Na, and a soluble sulfate of not more than 150 ppm, calculated as SO.sub.4, and having a pH value of not less than 8. The titanium oxide particles of the present invention are suitable as non-magnetic particles for a non-magnetic undercoat layer of a magnetic recording medium which uses magnetic particles containing iron as a main ingredient, and even more particularly, are suitable as non-magnetic particles for a non-magnetic undercoat layer of a magnetic recording medium which uses magnetic particles containing iron as a main ingredient, show an excellent dispersibility in a binder resin, contain only a small amount of soluble sodium salt and soluble sulfate, and have a pH value of not less than 8.Type: GrantFiled: December 15, 1997Date of Patent: March 28, 2000Assignee: Toda Kogyo CorporationInventors: Kazuyuki Hayashi, Keisuke Iwasaki, Yasuyuki Tanaka, Hiroko Morii
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Patent number: 6030688Abstract: Rectangular parallelopipedic lepidocrocite particles of the present invention have a minor axial diameter of 0.045 to 0.5 .mu.m, a major axial diameter of 0.05 to 1.0 .mu.m, and a thickness of 0.001 to 0.3 .mu.m, which are individual. Such rectangular parallelopipedic lepidocrocite particles according to the present invention are firstly used as a coloring pigment for paints, resin moldings, printing ink, road asphalt, cosmetics, etc., and secondly used as a non-magnetic material for non-magnetic undercoat layers which are formed on non-magnetic substrates which constitute a substrate for magnetic recording media, and which have an excellent surface smoothness and a high strength.Type: GrantFiled: August 8, 1997Date of Patent: February 29, 2000Assignee: Toda Kogyo CororationInventors: Kazuyuki Hayashi, Hiroko Morii, Yoshiro Okuda, Keisuke Iwasaki
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Patent number: 6027559Abstract: Yellow iron oxide hydroxide particles comprising:iron oxide hydroxide particle as a core, andcomposite oxide hydroxide of Fe and Al deposited on surface of said iron oxide hydroxide particle as a core wherein the amount of Al in said composite oxide hydroxide is 0.1 to 10% by weight, calculated as Al, based on the weight of said iron oxide hydroxide as a core, the amount of Fe in said composite oxide hydroxide is 0.1 to 50% by weight, calculated as Fe, based on the weight of said iron oxide hydroxide particle as a core, and the ratio of Al to Fe in said composite oxide hydroxide is 0.05:1 to 2:1, calculated as Al and Fe atoms,said yellow iron oxide hydroxide particles having an average major axis diameter of 0.1 to 1.0 .mu.m, an average minor axis diameter of 0.02 to 0.10 .mu.m, an aspect ratio (major axis diameter/minor axis diameter) of 2 to 20, a BET specific surface area of 10 to 180 m.sup.2 /g and a heat-resistance temperature of not less than 255.degree. C.Type: GrantFiled: June 22, 1998Date of Patent: February 22, 2000Assignee: Toda Kogyo CorporationInventors: Hiroko Morii, Mineko Ohsugi, Kazuyuki Hayashi, Hiroshi Sumita
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Patent number: 6019834Abstract: A pigment of the present invention comprises:pigment particle as core particle;a lower coat formed on at least a part of surface of the pigment particle, comprising squaric acid, polyol having an anthraquinone skeleton represented by the general formula (I): ##STR1## wherein m is an integer of 0 to 4, n is an integer of 0 to 4 and m+n is an integer of 2 to 4,or a mixture of the squaric acid and the polyol having an anthraquinone skeleton represented by the general formula (I); andan upper coat formed on at least a part of surface of the obtained particle, comprising at least one alkylene glycol represented by the general formula (II):C.sub.q H.sub.2q (OH).sub.2 (II)wherein q is an integer of 2 to 10.Such pigment has excellent dispersion facility, dispersion homogeneity and dispersion stability, and is suitably used for not only organic solvent-type paints but also water-based paints.Type: GrantFiled: March 5, 1998Date of Patent: February 1, 2000Assignee: Toda Kogyo CorporationInventors: Kazuyuki Hayashi, Mineko Ohsugi, Hiroko Morii, Mamoru Kamigaki
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Patent number: 5994611Abstract: The disclosure describes plastic formed products comprising:one selected from the group consisting of a thermoplastic resin and a thermosetting resin; and0.1 to 10 wt % of at least one selected from the group consisting of ferric oxide hydroxide particles, hematite particles, magnetite particles and maghemite particles;wherein (1) the average major axial diameter or the plate diameter of said ferric oxide hydroxide particles is 0.02 or 2.0 .mu.m and the average aspect ratio or the plate ratio thereof is 2 to 20, (2) the average particle size of said hematite particles, magnetite particles and maghemite particles is 0.01 to 1.0, the BET specific surface area thereof is 1 to 120 m.sup.2 /g and the water content on the surfaces thereof is not less than 0.02 wt %/m.sup.2 /g.Type: GrantFiled: February 9, 1998Date of Patent: November 30, 1999Assignee: Toda Kogyo CorporationInventors: Masaharu Nishihara, Masaaki Nishikawa, Suminori Tanaka, Nanao Horiishi, Satoru Saito, Naruo Yokoyama, Kazuyuki Hayashi, Masayuki Watanabe
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Patent number: 5922464Abstract: A rubber or resin composition comprises:0.1 to 10.0 parts by weight of iron oxide particles composed of iron oxide core which contains 0.21 to 2.14 wt % of silicon, calculated as SiO.sub.2, and 0.01 to 10.0 wt %, calculated as SiO.sub.2, of a precipitate composed of silicon, which adheres to the surfaces of said iron oxide core, a sphere ratio, maximum diameter/ minimum diameter, of said iron oxide particles being of 0.7 to 1.0, an average particle diameter of said iron oxide particles being 0.05 to 1.0 .mu.m, a geometric standard deviation .sigma.g of said iron oxide particles which shows the particle size distribution being not more than 1.40, a bulk density of said iron oxide particles being 0.80 to 1.5 g/cm.sup.3, and a surface activity of said iron oxide particles which is indicated by the number of cyclohexanone molecules adsorbed to the surfaces of the iron oxide particles, number of molecules/nm.sup.2, being not more than 1.70; and90 to 99.9 parts by weight of rubber or thermoplastic resin.Type: GrantFiled: August 8, 1997Date of Patent: July 13, 1999Assignee: Toda Kogyo CorporationInventors: Kazuyuki Hayashi, Minoru Ohsugi, Hiroko Morii, Koso Aoki
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Patent number: 5900313Abstract: The disclosure describes plastic formed products comprising:one selected from the group consisting of a thermoplastic resin and a thermosetting resin; and0.1 to 10 wt % of at least one selected from the group consisting of ferric oxide hydroxide particles, hematite particles, magnetite particles and maghemite particles;wherein (1) the average major axial diameter or the plate diameter of said ferric oxide hydroxide particles is 0.02 or 2.0 .mu.m and the average aspect ratio or the plate ratio thereof is 2 to 20, (2) the average particle size of said hematite particles, magnetite particles and maghemite particles is 0.01 to 1.0, the BET specific surface area thereof is 1 to 120 m.sup.2 /g and the water content on the surfaces thereof is not less than 0.02 wt %/m.sup.2 /g.Type: GrantFiled: September 18, 1995Date of Patent: May 4, 1999Assignee: Toda Kogyo CorporationInventors: Masaharu Nishihara, Masaaki Nishikawa, Suminori Tanaka, Nanao Horiishi, Satoru Saito, Naruo Yokoyama, Kazuyuki Hayashi, Masayuki Watanabe
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Patent number: 5882795Abstract: The disclosure describes a non-magnetic undercoating layer for a magnetic recording medium, coated on the surface of a non-magnetic substrate comprising:non-magnetic particles selected from the group consisting of particles (1) and (2):(1) coated acicular or spindle-shaped .alpha.-Fe.sub.2 O.sub.3 particles which are produced by adhering not less than 0.01 to 20 wt % (calculated as Al, SiO.sub.2 or Al and SiO.sub.2, and based on acicular or spindle-shaped .alpha.-Fe.sub.2 O.sub.3 particles as a core material) of an oxide or a hydroxide containing Al, Si or both Al and Si to the surfaces of acicular or spindle-shaped .alpha.-Fe.sub.2 O.sub.3 particles as a core material, and have a molecular weight-dependent parameter .alpha. represented by the following formula of not less than 0.5:As=K.sub.1 .multidot.M.sup..alpha.wherein M represents the number-average molecular weight of a binder resin, As represents the saturation adsorption of said binder resin, and K.sub.Type: GrantFiled: February 22, 1995Date of Patent: March 16, 1999Assignee: Toda Kogyo CorporationInventors: Kazuyuki Hayashi, Keisuke Iwasaki, Yasuyuki Tanaka, Minoru Ohsugi, Hiroko Morii, Mineko Sakoda, Norio Sugita, Masaaki Maekawa
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Patent number: 5830557Abstract: The disclosure describes a non-magnetic undercoating layer for a magnetic recording medium, coated on the surface of a non-magnetic substrate comprising:non-magnetic particles selected from the group consisting of particles (1) and (2):(1) coated acicular or spindle-shaped .alpha.-Fe.sub.2 O.sub.3 particles which are produced by adhering not less than 0.01 to 20 wt % (calculated as Al, SiO.sub.2 or Al and SiO.sub.2, and based on acicular or spindle-shaped .alpha.-Fe.sub.2 O.sub.3 particles as a core material) of an oxide or a hydroxide containing Al, Si or both Al and Si to the surfaces of acicular or spindle-shaped .alpha.-Fe.sub.2 O.sub.3 particles as a core material, and have a molecular weight-dependent parameter .alpha. represented by the following formula of not less than 0.5:As=K.sub.1 .multidot.M.sup..alpha.wherein M represents the number-average molecular weight of a binder resin, As represents the saturation adsorption of said binder resin, and K.sub.Type: GrantFiled: February 22, 1995Date of Patent: November 3, 1998Assignee: Toda Kogyo CorporationInventors: Kazuyuki Hayashi, Keisuke Iwasaki, Yasuyuki Tanaka, Minoru Ohsugi, Hiroko Morii, Mineko Sakoda, Norio Sugita, Masaaki Maekawa
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Patent number: 5750250Abstract: Hematite particles for a non-magnetic undercoat layer for a magnetic recording medium, comprise: high-density acicular hematite particles having an average major axial diameter of not more than 0.3 .mu.m, a major axial diameter distribution in geometrical standard of not more than 1.50 and a BET specific surface area of not less than 35 m.sup.2 /g, showing a pH of not less than 8, and containing not more than 300 ppm of soluble sodium salt, calculated as Na, and not more than 150 ppm of soluble sulfate, calculated as SO.sub.4.Type: GrantFiled: October 18, 1996Date of Patent: May 12, 1998Assignee: Toda Kogyo CorporationInventors: Kazuyuki Hayashi, Keisuke Iwasaki, Yasuyuki Tanaka, Hiroko Morii
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Patent number: 5693690Abstract: A rubber or resin composition comprises:0.1 to 10.0 parts by weight of iron oxide particles composed of iron oxide core which contains 0.21 to 2.14 wt % of silicon, calculated as SiO.sub.2, and 0.01 to 10.0 wt %, calculated as SiO.sub.2, of a precipitate composed of silicon, which adheres to the surfaces of said iron oxide core,a sphere ratio, maximum diameter/minimum diameter, of said iron oxide particles being of 0.7 to 1.0, an average particle diameter of said iron oxide particles being 0.05 to 1.0 .mu.m, a geometric standard deviation .sigma.g of said iron oxide particles which shows the particle size distribution being not more than 1.40, a bulk density of said iron oxide particles being 0.80 to 1.5 g/cm.sup.3, and a surface activity of said iron oxide particles which is indicated by the number of cyclohexanone molecules adsorbed to the surfaces of the iron oxide particles, number of molecules/nm.sup.2, being not more than 1.70; and90 to 99.9 parts by weight of rubber or thermoplastic resin.Type: GrantFiled: April 4, 1996Date of Patent: December 2, 1997Assignee: Toda Kogyo CorporationInventors: Kazuyuki Hayashi, Minoru Ohsugi, Hiroko Morii, Koso Aoki
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Patent number: 5686012Abstract: The disclosure describes modified particles comprising inorganic particles as core particles, and at least one polysiloxane modified with at least one selected from the group consisting of polyethers, polyesters and aralkyls, which is coated on the surfaces of said core particles.Type: GrantFiled: September 1, 1995Date of Patent: November 11, 1997Assignee: Toda Kogyo CorporationInventors: Kazuyuki Hayashi, Hiroko Morii, Mineko Sakoda, Minoru Ohsugi, Mamoru Kamigaki
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Patent number: 5604015Abstract: The disclosure describes a non-magnetic undercoating layer for a magnetic recording medium, coated on the surface of a non-magnetic substrate comprising:non-magnetic particles selected from the group consisting of particles (1) and (2):(1) coated acicular or spindle-shaped .alpha.-Fe.sub.2 O.sub.3 particles which are produced by adhering not less than 0.01 to 20 wt % (calculated as Al, SiO.sub.2 or Al and SiO.sub.2, and based on acicular or spindle-shaped .alpha.-Fe.sub.2 O.sub.3 particles as a core material) of an oxide or a hydroxide containing Al, Si or both Al and Si to the surfaces of acicular or spindle-shaped .alpha.-Fe.sub.2 O.sub.3 particles as a core material, and have a molecular weight-dependent parameter .alpha. represented by the following formula of not less than 0.5:As=K.sub.1 .multidot.M.sup..alpha.wherein M represents the number-average molecular weight of a binder resin, As represents the saturation adsorption of said binder resin, and K.sub.Type: GrantFiled: May 10, 1994Date of Patent: February 18, 1997Assignee: Toda Kogyo CorporationInventors: Kazuyuki Hayashi, Keisuke Iwasaki, Yasuyuki Tanaka, Minoru Ohsugi, Hiroko Morii, Mineko Sakoda, Norio Sugita, Masaaki Maekawa