Abstract: An internal combustion engine 1 is provided, in an exhaust passage thereof with an electrochemical reactor including: an ion conductive solid electrolyte layer; an anode layer arranged on a surface of the solid electrolyte layer; and a cathode layer arranged on a surface of the solid electrolyte layer and able to hold NOX. The engine includes a current control device for controlling the current supplied to the electrochemical reactor so as to flow from the anode layer through the solid electrolyte layer to the cathode layer. The current control device is configured so as to supply current to the electrochemical reactor at least temporarily while that internal combustion engine is stopped.

Abstract: An exhaust treatment catalyst (5) is arranged in the engine exhaust passage, and hydrogen generated in the reformer (6) is supplied through the hydrogen supply pipe (13) to the inside of the engine exhaust passage upstream of the exhaust treatment catalyst (5). Heat exchange fins (15) for heat exchange with exhaust gas flowing through the inside of the engine exhaust passage are formed on the outer circumferential surface of the hydrogen supply pipe (13) inserted inside the engine exhaust passage.

Abstract: The NOx catalyst is irradiated with an electromagnetic wave, a resonance frequency and a ratio of a reception power to an oscillation power at the time of the irradiation are detected, and an upper limit value of a change amount of the resonance frequency or an upper limit value of a change amount of the ratio at which the NOx catalyst is diagnosed to be abnormal is determined from a change amount of the resonance frequency and a change amount of the ratio until water is adsorbed on all acid sites included in the NOx catalyst, and a change amount of the resonance frequency and a change amount of the ratio until ammonia is adsorbed on all acid sites included in the NOx catalyst, when it is supposed that the NOx catalyst is in a state of being on the borderline between normal and abnormal.

Abstract: An abnormality diagnosis apparatus includes an irradiation device to detect a resonance frequency by irradiating an electromagnetic wave to the NOx catalyst, and a controller to diagnose based on the resonance frequency whether the NOx catalyst is abnormal, wherein the NOx catalyst is arranged in such a position that an electric field strength inside the NOx catalyst at the time when the irradiation device irradiates the electromagnetic wave of the resonance frequency becomes larger in an upstream portion of the NOx catalyst, which is at the upstream side of a center of the NOx catalyst in the direction of flow of exhaust gas, than in a downstream portion of the NOx catalyst, which is at the downstream side of the center of the NOx catalyst.

Abstract: An abnormality diagnosis apparatus for an exhaust gas control apparatus. The abnormality diagnosis apparatus includes: an adsorption amount detector which detects an actual adsorption amount that is an amount of ammonia actually adsorbed in a catalyst; and an electronic control unit configured to: i) estimate an estimated adsorption amount that is an ammonia adsorption amount in the catalyst on an assumption that an ammonia supply apparatus is normal; and ii) execute an abnormality diagnosis in which the ammonia supply apparatus is diagnosed as being abnormal, in a case where the estimated adsorption amount is equal to or smaller than a predetermined adsorption amount and where a difference between the estimated adsorption amount and the actual adsorption amount is larger than a threshold.

Abstract: An exhaust gas purification system comprises a first fuel supply unit to supply fuel to exhaust gas flowing in an exhaust passage by a supply valve arranged in the exhaust passage, and a second fuel supply unit to supply fuel to exhaust gas by adjusting a fuel injection condition, wherein in a temperature raising stage of the NOx SCR catalyst associated with the exhaust gas temperature raising processing, first control is performed in which fuel is supplied by the first fuel supply unit, and in a temperature holding stage of the NOx SCR catalyst associated with the exhaust gas temperature raising processing, at least second control is performed in which the ratio of an amount of fuel supply by the second fuel supply unit with respect to an amount of fuel supply by the first fuel supply unit becomes higher in comparison with that when performing the first control.

Abstract: An electrochemical reactor 70 is provided with a proton conductive solid electrolyte layer 75; an anode layer 76 arranged on the surface of the solid electrolyte layer and able to hold water molecules; a cathode layer 77 arranged on the surface of the solid electrolyte layer; and a current control device 73 controlling a current flowing through the anode layer and the cathode layer. The current control device reduces the current flowing through the anode layer and the cathode layer, when the water molecules held in the anode layer become smaller in amount.

Abstract: An exhaust gas catalyst includes: catalyst particles that clean exhaust gas; and magnetic particles that are placed around the catalyst particles and that generate heat upon absorption of microwaves. Each of the magnetic particles includes: a core portion composed of a ferromagnetic material capable of generating heat upon absorption of microwaves; and a shell portion coating a surface of the core portion, the shell portion having a property of permitting passage of microwaves, the shell portion being superior to ?-alumina or ?-alumina in a property of blocking gases.

Abstract: An exhaust gas purification system comprise a first fuel supply unit to supply fuel to exhaust gas flowing in an exhaust passage by a supply valve arranged in the exhaust passage, and a second fuel supply unit to supply fuel to exhaust gas by adjusting a fuel injection condition wherein in a temperature raising stage of the NOx SCR catalyst associated with the exhaust gas temperature raising processing, first control is performed in which fuel is supplied by the first fuel supply unit, and in a temperature holding stage of the NOx SCR catalyst associated with the exhaust gas temperature raising processing, at least second control is performed in which the ratio of an amount of fuel supply by the second fuel supply unit with respect to an amount of fuel supply by the first fuel supply unit becomes higher in comparison with that when performing the first control.

Abstract: An exhaust gas purification apparatus for an internal combustion engine comprises: a selective catalytic reduction (SCR) catalyst selectively reducing NOx in an exhaust gas of the internal combustion engine using ammonia as a reducing agent; a supply device adding an additive agent, such as ammonia, to the exhaust gas at an upstream side of the SCR catalyst; and a controller, when a temperature of SCR catalyst is higher than a predetermined temperature, increases a NOx concentration of the exhaust gas flowing into the SCR catalyst and increases an amount of addition of the additive agent in such a manner that a ratio of an amount of ammonia with respect to an amount of NOx contained in the exhaust gas flowing into the SCR catalyst, becomes large, as compared to when the temperature is equal to or less than the predetermined temperature.

Abstract: In order to supply a reducing agent to two NOx catalysts arranged in series in an appropriate manner, normal control in which an additive agent of an amount according to an amount of NOx flowing into an upstream side NOx catalyst is added from an upstream side of the upstream side NOx catalyst, and decrease control in which when an amount of ammonia adsorbed to a downstream side NOx catalyst exceeds a predetermined upper limit amount in cases where the two NOx catalysts have been activated, an amount of additive agent to be added from a first addition valve is made smaller than the amount of additive agent to be added at the time of the normal control, are carried out.

Abstract: When it is determined that there is a possibility of start-up of an internal combustion engine while regeneration control is in execution during stop of the internal combustion engine, processing of the regeneration control is stopped. Accordingly, as compared with the case where the regeneration control is continuously executed when the internal combustion engine is started up, temperature increase in a filter can be suppressed: Therefore, even when an increased amount of oxygen is supplied to the filter, an oxidation reaction is suppressed, so that overheating of the filter can be suppressed.

Abstract: A vehicle includes a filter disposed in an exhaust passage through which exhaust gas discharged from an internal combustion engine passes, the filter being configured to collect PM that is particulate matter contained in the exhaust gas; a PM removal control device configured to start execution of PM removal control that heats the filter to remove the PM accumulated on the filter while the internal combustion engine is stopped; and a determination device configured to determine whether a user of the vehicle is away from the vehicle. The PM removal control device is configured to start the execution of the PM removal control only when the determination device determines that the user of the vehicle is away from the vehicle.

Abstract: When a user requests start-up of an internal combustion engine while PM removal control is in execution or immediately after execution of the PM removal control is completed, an electronic control unit informs the user of the vehicle of a first alarm, so that the user recognizes that the internal combustion engine cannot be started up immediately. This makes it possible to suppress the discomfort caused because the internal combustion engine is not started up.

Abstract: An exhaust gas purification system for an internal combustion engine is provided with a filter including a selective catalytic reduction NOx catalyst carried thereon. Further, a post-catalyst is provided for an exhaust gas passage disposed on a downstream side from the filter. The post-catalyst has an oxidizing function, and the post-catalyst has such a function that the production of N2 based on the oxidation of ammonia is facilitated in a predetermined first temperature area. A filter regeneration process execution unit is programmed to control the temperature of the post-catalyst to be in the first temperature area while adjusting the temperature of the filter to be in a predetermined second temperature area lower than a filter regeneration temperature during a certain period of time.

Abstract: An object of the present invention is to appropriately remove, from an exhaust gas, HC, CO, and ammonia flowing out from a filter (SCRF) on which an SCR catalyst is carried. In the present invention, a post-catalyst 8 is provided for an exhaust gas passage of an internal combustion engine on a downstream side from SCRF along with a flow of the exhaust gas. The post-catalyst 8 is constructed to include an adsorption reduction part 81c which adsorbs ammonia and which reduces NOx by using ammonia as a reducing agent, a first oxidation part 81b which oxidizes ammonia, and a second oxidation part 82 which oxidizes HO and CO.

Abstract: An object of the present invention is to provide a technique with which an amount of reducing agent adsorbed to a selective reduction type NOx catalyst provided in an exhaust passage of an internal combustion engine can be controlled to a target adsorption amount. In an exhaust gas purification system for an internal combustion engine according to the present invention, when a reducing agent adsorption amount adsorbed on a selective reduction type NOx catalyst is held at a target adsorption amount, a reducing agent supply amount supplied from a supply apparatus per unit time is controlled to an amount obtained by adding a predetermined amount to a reduction consumption amount, which is an amount of reducing agent consumed per unit time by the selective reduction type NOx catalyst for NOx reduction.

Abstract: An object is to suppress the occurrence of a failure in supply of urea water as much as possible in filling control of urea water in a pump share-type urea water supply system with two supply valves. In the pump share-type urea water supply system with a first supply valve and a second supply valve, a urea water tank is connected with the respective supply valves by a urea water supply path. The urea water supply path includes a first supply path for the first supply valve and a second supply path for the second supply valve. The second supply path has a larger capacity than the capacity of the first supply path by a predetermined volume.

Abstract: An exhaust gas purification apparatus for an internal combustion engine comprises: a selective catalytic reduction (SCR) catalyst selectively reducing NOx in an exhaust gas of the internal combustion engine using ammonia as a reducing agent; a supply device adding an additive agent, such as ammonia, to the exhaust gas at an upstream side of the SCR catalyst; and a controller, when a temperature of SCR catalyst is higher than a predetermined temperature, increases a NOx concentration of the exhaust gas flowing into the SCR catalyst and increases an amount of addition of the additive agent in such a manner that a ratio of an amount of ammonia with respect to an amount of NOx contained in the exhaust gas flowing into the SCR catalyst, becomes large, as compared to when the temperature is equal to or less than the predetermined temperature.

Abstract: A pump share-type urea water supply system includes a first supply valve and a second supply valve. A urea water tank is connected with the respective supply valves by a urea water supply path that includes a first supply path for the first supply valve and a second supply path for the second supply valve. The second supply path has a larger capacity than the first supply path by a predetermined volume. A suck-back control controls opening and closing of the respective supply valves such that a first estimated valve-opening time of the first supply valve for suck-back control in the first supply valve and supply path is shorter than a second estimated valve-opening time of the second supply valve for suck-back control in the second supply valve and in-the-second supply path by at least a first control time corresponding to the predetermined volume.