Abstract: The toner contains binder resin-containing toner particles and silica fine particle S1, wherein the weight-average particle diameter of the toner is 4.0-15.0 ?m, both inclusive, peaks originating with the silica fine particle S1 are observed in 29 Si-NMR measurement of the silica fine particle S1, and, in the spectrum obtained by 29Si CP/MAS NMR or 29Si DD/MAS NMR, the peak area of a peak corresponding to the D1 unit structure in the silica fine particle S1, the peak area of a peak corresponding to the D2 unit structure in the silica fine particle S1, and the peak area of a peak corresponding to the Q unit structure in the silica fine particle S1 satisfy a prescribed relationship.

Abstract: A method for producing an ultra-low carbon steel product having a carbon concentration of 0.005% by mass or less includes, at least, a step of adjusting a carbon concentration of molten iron to obtain molten steel, a step of casting the molten steel into a slab, and a step of hot rolling the slab to obtain a hot-rolled steel sheet, in which the method further includes a width reduction step of performing width reduction on the slab with a reduction amount which is predetermined in accordance with the slab width in a direction orthogonal to the rolling direction of the slab.

Abstract: A continuous casting method of steel includes the step of bulging wide side surfaces of a slab having there inside an unsolidified layer with a total intentional bulging amount of 3 to 10 mm by increasing stepwise toward a downstream side in a casting direction a roller gap of a plurality of pairs of slab support rollers disposed in a continuous casting machine.

Abstract: A continuous casting method of steel includes the step of bulging wide side surfaces of a slab having there inside an unsolidified layer with a total intentional bulging amount of 3 to 10 mm by increasing stepwise toward a downstream side in a casting direction a roller gap of a plurality of pairs of slab support rollers disposed in a continuous casting machine.

Abstract: An exhaust gas control apparatus (100) of an internal combustion engine (200) of a vehicle, which is provided with: the internal combustion engine which can use fuel containing methane in exhaust gas; an exhaust gas purifying apparatus (300) disposed in an exhaust passage of the internal combustion engine; an EGR passage (400) which can recirculate the exhaust gas to an intake passage of the internal combustion engine, in a HPL path which does not include the exhaust gas purifying apparatus; and an adjusting device (407) which can adjust an exhaust gas recirculation amount in the EGR passage, is provided with: a first specifying device for specifying a methane concentration in the exhaust gas; and a first controlling device for controlling the adjusting device to increase an exhaust gas recirculation amount in the HPL path if the specified methane concentration is greater than or equal to a reference value.

Abstract: An exhaust device for an internal combustion engine is mounted on a vehicle and equipped with an exhaust passage, a reforming catalyst and a NOx purification catalyst. The exhaust passage communicates with the engine. The reforming catalyst is provided on the exhaust passage at the upstream side of the NOx purification catalyst, and it generates the reducing agent by reforming CH4. The NOx purification catalyst purifies NOx by means of the reducing agent generated by the reforming catalyst.

Abstract: An exhaust emission control system of an internal combustion engine includes: a bypass passage (22) provided in an exhaust passage (14) of the engine and arranged to bypass a main passage (16) as a part of the exhaust passage, a NOx adsorbent (28) provided in the bypass passage and adapted to adsorb at least NOx as one of components contained in exhaust gas, a channel switching device (30) that switches a channel of the exhaust gas between the main passage and the bypass passage, an adsorption control device (50) that controls the channel switching device, based on operating conditions of the engine, so as to cause the exhaust gas to flow through the bypass passage, and an adsorbing capability determining device (50) that determines, when the adsorbing capability of the NOx adsorbent degrades, whether the degradation in the adsorbing capability is a surmountable degradation from which the NOx adsorbent can recover, or an insurmountable degradation from which the NOx adsorbent cannot recover.

Abstract: An exhaust gas purification device has: a bypass passage (20) disposed in an exhaust passage (15) of an internal combustion engine (10); an adsorbent (21) which is disposed in the bypass passage (20), and adsorbs unburned components in exhaust gas at a low temperature and desorbs the adsorbed unburned components at a high temperature; and an exhaust gas purification catalyst (22) which is disposed in the exhaust passage (15) at a downstream side of a portion where the bypass passage (20) merges, and purifies unburned components in exhaust gas; and a desorption amount adjustment (19) unit that adjusts the desorption amount of unburned components adsorbed by the adsorbent (21) based on an integrated fuel cut air amount (fgs), which is an integrated value of air amount taken into a combustion chamber of the internal combustion engine (10) during execution of fuel cut.

Abstract: A control apparatus for an internal combustion engine is provided, which is capable of suppressing deterioration of exhaust emission due to an unburned fuel contained in oil which enters a combustion chamber during valve stop control while preventing inflow of fresh air to a catalyst, at a time of valve return following return from fuel cut. Variable valve operating apparatuses having valve stop mechanisms capable of changing operation states of an intake valve and an exhaust valve between valve operation states and valve closed and stopped states are included. Valve stop control that changes the operation states of the intake valve and the exhaust valve to the valve closed and stopped states is performed, at a time of execution of the fuel cut. When a return request from the fuel cut with the valve stop control is detected, a fuel is supplied to a combustion chamber before the operation state of the exhaust valve is returned to the valve operation state.

Abstract: A control device is applied to an internal combustion engine capable of using CNG and gasoline by switching therebetween, and the CNG and the gasoline are associated, as fuel for use, with one and the other of two driving areas respectively, the driving areas being different from each other. The control device exceptionally switches the fuel for use from gasoline to CNG and implements an air-fuel ratio imbalance inspection (S6, S7), when the air-fuel ratio imbalance inspection is required for a CNG mode using CNG (S1), the engine is driving in a driving area (AR2) correlated to gasoline as fuel for use (S2), and gasoline mode using gasoline as fuel for use is ongoing (S3).

Abstract: Provided is a control apparatus, which can successfully suppress that deterioration of combustion is caused in response to inflow of a large amount of blow-by gas to cylinders at the time of a valve return from a valve stop state in an internal combustion engine including a positive crankcase ventilation system and a variable valve operating mechanism that is capable of stopping at least one valve of an intake valve and exhaust valve in a closed state. A valve stop control is performed which stops the intake valve and exhaust valve in a closed state when a fuel cut of the internal combustion engine is executed. A deviation amount ?A/F between a predetermined target air fuel ratio and an actual air fuel ratio detected by an A/F sensor at the time of a valve return is obtained. A correction is performed to decrease a fuel injection amount by a fuel amount equivalent to the deviation amount ?A/F at the time of the subsequent valve returns.

Abstract: An object of the present invention is to provide an exhaust gas purifying apparatus for an internal combustion engine which can properly purge at least NOx of unpurified components contained in exhaust gas while considering characteristics of NOx desorbed from an adsorbent. A bypass passage 18 bypassing a main exhaust passage 12 of the internal combustion engine 10 is provided. A HC/NOx adsorbent 22 having a function of adsorbing HC and NOx is provided in the bypass passage 18. A second underfloor catalyst 30 is provided downstream of the adsorbent 22. A purge passage 26 branching off from the bypass passage 18 while connecting to an intake passage is provided. An exhaust switching valve 20 and a purge control valve 28 are provided as a flow path switching means that is capable of switching a flow target into which the exhaust gas flows between the main exhaust passage 12 and the bypass passage 18. If the purging operations are executed, the intake purging operation is first executed.

Abstract: A moisture adsorbent (32) for adsorbing moisture in exhaust gas and an NOx adsorbent (34) for adsorbing NOx are disposed in a bypass passage (30) for bypassing an exhaust passage (16) of an internal combustion engine (10). When an adsorption operation to the NOx adsorbent (34) is executed, inflow of the exhaust gas to the bypass passage (30) is allowed until the moisture amount that flows into the water adsorbent (32) reaches an allowable moisture inflow amount. The allowable moisture inflow amount is determined based on a residual moisture amount before the starting of the adsorption operation in the moisture adsorbent (32). The residual moisture amount in the water adsorbent (32) can be determined based on the temperature of the moisture adsorbent (32) at the immediately preceding execution of the purge operation.

Abstract: An exhaust gas control apparatus (100) of an internal combustion engine (200) of a vehicle, which is provided with: the internal combustion engine which can use fuel containing methane in exhaust gas; an exhaust gas purifying apparatus (300) disposed in an exhaust passage of the internal combustion engine; an EGR passage (400) which can recirculate the exhaust gas to an intake passage of the internal combustion engine, in a HPL path which does not include the exhaust gas purifying apparatus; and an adjusting device (407) which can adjust an exhaust gas recirculation amount in the EGR passage, is provided with: a first specifying device for specifying a methane concentration in the exhaust gas; and a first controlling device for controlling the adjusting device to increase an exhaust gas recirculation amount in the HPL path if the specified methane concentration is greater than or equal to a reference value.

Abstract: An exhaust device for an internal combustion engine is mounted on a vehicle and equipped with an exhaust passage, a reforming catalyst and a NOx purification catalyst. The exhaust passage communicates with the engine. The reforming catalyst is provided on the exhaust passage at the upstream side of the NOx purification catalyst, and it generates the reducing agent by reforming CH4. The NOx purification catalyst purifies NOx by means of the reducing agent generated by the reforming catalyst.

Abstract: An exhaust gas purifying apparatus for an internal combustion engine is provided to desorb predetermined components contained in exhaust gas from an adsorption device for adsorbing the components and to purify the desorbed components, even during the stop of the internal combustion engine. A main exhaust passage and a bypass passage bypassing the main exhaust passage are provided. An exhaust switching valve is capable of switching a flow target into the exhaust gas flows between the main exhaust passage and the bypass passage. An adsorbent for adsorbing the predetermined components is provided in the bypass passage. An underfloor catalyst including a catalyst with a heater is provided at a downstream side of the bypass passage in the main exhaust passage. A pump and a heater are provided in an air supply passage which branches from the bypass passage at an upstream portion of the adsorbent.

Abstract: A control apparatus for an internal combustion engine is provided, which is capable of suppressing deterioration of exhaust emission due to an unburned fuel contained in oil which enters a combustion chamber during valve stop control while preventing inflow of fresh air to a catalyst, at a time of valve return following return from fuel cut. Variable valve operating apparatuses having valve stop mechanisms capable of changing operation states of an intake valve and an exhaust valve between valve operation states and valve closed and stopped states are included. Valve stop control that changes the operation states of the intake valve and the exhaust valve to the valve closed and stopped states is performed, at a time of execution of the fuel cut. When a return request from the fuel cut with the valve stop control is detected, a fuel is supplied to a combustion chamber before the operation state of the exhaust valve is returned to the valve operation state.

Abstract: An air-fuel ratio imbalance determining apparatus that is configured to sequentially stop a fuel injection for each of cylinders in accordance with a firing (ignition) order by changing the intake valves and exhaust valves of the cylinder whose fuel injection is stopped from a valve operating state to a valve resting state. After a predetermined time elapses (time-point tp), an upstream-side air-fuel ratio value obtained based on an output value of an upstream air-fuel ratio sensor disposed in the exhaust passage which becomes a value corresponding to an air-fuel ratio of the final gas. The determining apparatus obtains that value as data relating to an air-fuel ratio of the cylinder which discharged the final gas, and determines whether or not an air-fuel ratio imbalance is occurring based on the data relating to the air-fuel ratio of each of the cylinders.

Abstract: The present invention has its object to provide a control apparatus for an internal combustion engine including a variable valve operating mechanism which is capable of accurately and effectively identifying an abnormality-occurring cylinder during operation while preventing the deterioration of a catalyst. A fuel injection valve which is capable of injecting fuel for each cylinder is provided. Variable valve operating mechanisms which are capable of halting the operation of the intake and exhaust valves in the closed state for each cylinder are provided. An abnormality evaluation index value is acquired during the operation of the internal combustion engine and, based on the abnormality evaluation index value, an abnormality which has occurred in at least one cylinder in the internal combustion engine is detected.