Abstract: A radical polymerization method may use a compound having a polycyclic aromatic skeleton and an endoperoxide compound having a polycyclic aromatic skeleton. An endoperoxide compound may have a polycyclic aromatic skeleton of formula (1), and a compound may have a polycyclic aromatic skeleton, which is a raw material of the endoperoxide compound: wherein R is a C1-10 alkyl group, an alkoxymethyl group having a C1-5 alkoxy group, a C6-10 aryl group, an alkylcarbonyl group having a C1-10 alkyl group, an arylcarbonyl group having a C6-20 aryl group, an alkyloxycarbonyl group having a C1-10 alkyl group, an aryloxycarbonyl group having a C6-10 aryl group, an alkyloxycarbonylmethyl group having a C1-12 alkyl group or an aryloxycarbonylmethyl group having a C6-12 aryl group.

Abstract: A conventional polymerization inhibitor is for example an agent to scavenge radicals generated during storage of a radical polymerizable compound and used to stably handle the radical polymerizable compound, but is unnecessary when the radical polymerizable compound is to be subjected to radical polymerization reaction, and is preferably removed at the time of the radical polymerization reaction. The object of the present invention is to obviate inconvenience of removing the polymerization inhibitor at the time of radical polymerization. The radical polymerization control agent contained in a radical polymerizable composition of the present invention functions as a radical polymerization inhibitor for example stored in a dark place, but loses its radical polymerization inhibiting effect when polymerization is initiated while being irradiated with light at a certain specific wavelength at the time of polymerization.

Abstract: A photoradical polymerization initiator that is environmentally friendly and composed solely of carbon, hydrogen and oxygen atoms, generating no acid that may cause corrosion during a radical polymerization reaction, and having a high radical polymerization initiation capacity to light having a wavelength of 350 nm to 420 nm. A photoradical polymerizable composition including a radical polymerizable compound and a photoradical polymerization initiator, where the photoradical polymerization initiator is a 1,4-dihydroxy-2-naphthoic acid compound represented by formula (1): where R is a hydrogen atom, a C1-10 alkyl group or a C6-14 aryl group, and X is a hydrogen atom, a C1-10 alkyl group, a C6-14 aryl group, a hydroxy group, a C1-10 alkoxy group or a C6-14 aryloxy group.

Abstract: The purpose of the present invention is to provide a photopolymerizable composition which can act as a photopolymerization sensitizer that is active against light having a wavelength falling within a wavelength range of from 300 to 500 nm, and which has such a property that coloring of a cured product produced by polymerizing a photopolymerizable composition containing the photopolymerization sensitizer is less. A photopolymerization sensitizer composition characterized by comprising a photopolymerization sensitizer containing an alkoxyanthracene compound represented by the formula (1) and a singlet oxygen quencher; and a photopolymerizable composition containing the photopolymerization sensitizer composition: in the formula (1), n represents an integer of 1 or 2; R represents a C1-12 alkyl group; and X represents a hydrogen atom or a C1-8 alkyl group.

Abstract: A radical polymerization method may use a compound having a polycyclic aromatic skeleton and an endoperoxide compound having a polycyclic aromatic skeleton. An endoperoxide compound may have a polycyclic aromatic skeleton of formula (1), and a compound may have a polycyclic aromatic skeleton, which is a raw material of the endoperoxide compound: wherein R is a C1-10 alkyl group, an alkoxymethyl group having a C1-5 alkoxy group, a C6-10 aryl group, an alkylcarbonyl group having a C1-10 alkyl group, an arylcarbonyl group having a C6-20 aryl group, an alkyloxycarbonyl group having a C1-10 alkyl group, an aryloxycarbonyl group having a C6-10 aryl group, an alkyloxycarbonylmethyl group having a C1-12 alkyl group or an aryloxycarbonylmethyl group having a C6-12 aryl group.

Abstract: A conventional polymerization inhibitor is for example an agent to scavenge radicals generated during storage of a radical polymerizable compound and used to stably handle the radical polymerizable compound, but is unnecessary when the radical polymerizable compound is to be subjected to radical polymerization reaction, and is preferably removed at the time of the radical polymerization reaction. The object of the present invention is to obviate inconvenience of removing the polymerization inhibitor at the time of radical polymerization. The radical polymerization control agent contained in a radical polymerizable composition of the present invention functions as a radical polymerization inhibitor for example stored in a dark place, but loses its radical polymerization inhibiting effect when polymerization is initiated while being irradiated with light at a certain specific wavelength at the time of polymerization.

Abstract: [OBJECT] The purpose of the present invention is to provide a photopolymerizable composition which can act as a photopolymerization sensitizer that is active against light having a wavelength falling within a wavelength range of from 300 to 500 nm, and which has such a property that coloring of a cured product produced by polymerizing a photopolymerizable composition containing the photopolymerization sensitizer is less. [SOLUTION TO PROBLEM] A photopolymerization sensitizer composition characterized by comprising a photopolymerization sensitizer containing an alkoxyanthracene compound represented by the formula (1) and a singlet oxygen quencher; and a photopolymerizable composition containing the photopolymerization sensitizer composition: in the formula (1), n represents an integer of 1 or 2; R represents a C1-12 alkyl group; and X represents a hydrogen atom or a C1-8 alkyl group.