Patents by Inventor Keizo Shimada

Keizo Shimada has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 4342715
    Abstract: A wholly aromatic polyamide shaped article is prepared by a process wherein a solution of a wholly aromatic polyamide is extruded through an orifice and introduced into a first coagulating bath comprising an aqueous coagulating liquid and, then, the coagulated extrudate is introduced into a second coagulating bath comprising an aqueous solution of an inorganic salt.
    Type: Grant
    Filed: October 29, 1980
    Date of Patent: August 3, 1982
    Assignee: Teijin Limited
    Inventors: Keizo Shimada, Akihiro Aoki, Hiroshi Mera, Tsutomu Nakamura
  • Patent number: 4337155
    Abstract: A wholly aromatic polyamide fiber material having an excellent resistance to chemicals, comprises wholly aromatic polyamide fibers each covered with a coating of a fluorine-containing polymeric resin which coating has been derived from an aqueous emulsion of the fluorine-containing polymer resin.
    Type: Grant
    Filed: January 14, 1981
    Date of Patent: June 29, 1982
    Assignee: Teijin Limited
    Inventors: Hideharu Sasaki, Yorikazu Tamura, Keizo Shimada
  • Patent number: 4324706
    Abstract: A friction material having an excellent heat-resistance, comprises 5 to 70% by weight of pulp-like particles consisting essentially of a heat-resistant aromatic polymeric material; 1 to 70% by weight of a fibrous material comprising at least one member selected from inorganic fibrous materials and heat-resistant organic fibrous materials; 1 to 35% by weight of a friction-regulating agent and; 5 to 40% by weight of a thermosetting polymeric resin.
    Type: Grant
    Filed: January 14, 1981
    Date of Patent: April 13, 1982
    Assignees: Teijin Limited, Adebono Brake Industry Co., Ltd.
    Inventors: Yutaka Tabe, Hiromitsu Takamoto, Keizo Shimada, Yasusaburo Sugita
  • Patent number: 4309476
    Abstract: An aromatic polyamide fiber having an excellent dyeing property has a core-in-sheath type structure, in which the core portion is insoluble and the sheath portion is soluble in N-methyl-2-pyrrolidone at 35.degree. C.
    Type: Grant
    Filed: April 14, 1980
    Date of Patent: January 5, 1982
    Assignee: Teijin Limited
    Inventors: Tsutomu Nakamura, Yasuo Nakagawa, Osamu Kai, Keizo Shimada
  • Patent number: 4291142
    Abstract: Aromatic polyamide film, having an excellent thermal resistance and a high dielectric breakdown strength, which comprises an aromatic polyamide containing repeating units of the formula----NH--Ar.sub.1 --CO----or----NH--Ar.sub.1 --NHCO--Ar.sub.2 --CO----and cross-linked with a cross-linking compound having at least one radical selected fromR.sup.1 --C(R.sup.2).dbd.C--CH.sub.2 (R.sup.3)--,R.sup.1 --C(R.sup.2).dbd.CR .sup.3 --,R.sup.1 --C(R.sup.2).dbd.C(R.sup.3)--COO--andR.sup.1 --C(R.sup.2).dbd.C(R.sup.3)--CONH--,or another cross-linking cyanuric or isocyanuric acid compound, by means of heat, ultraviolet rays or electron beam.
    Type: Grant
    Filed: July 6, 1979
    Date of Patent: September 22, 1981
    Assignee: Teijin, Limited
    Inventors: Yorikazu Tamura, Akihiro Aoki, Keizo Shimada
  • Patent number: 4278779
    Abstract: An aromatic polyamide composition which is suitable for producing filaments or fibers having an excellent heat-resisting property and a superior dyeing property, which comprises:(A) 50 to 95% by weight of poly-m-phenylene isophthalamide, and;(B) 5 to 50% by weight of at least one other aromatic polyamide comprising:(1) an amine moiety consisting essentially of (a) 35 to 100 molar % of at least one xylylene diamine and, (b) 0 to 65 molar % of at least one other aromatic diamine, and;(2) an acid moiety consisting essentially of at least one aromatic dicarboxylic acid.
    Type: Grant
    Filed: July 19, 1979
    Date of Patent: July 14, 1981
    Inventors: Yasuo Nakagawa, Keizo Shimada, Tsutomu Nakamura, Kichiro Matsuda
  • Patent number: 4250073
    Abstract: An aromatic polyamide composition usable for producing shaped articles, for instance, filaments, comprises the components of an aromatic polyamide resin (P), a polar amide solvent (S) and an auxiliary solvent (H) consisting of a halogenated hydrocarbon, for example, dichloromethane and dichloroethane, the proportions of the components (P), (S) and (H) being on or within a quadrilateral A C D E defined by the co-ordinates:A (P 5.0, S 30.0, H 65.0 )C (P 45.0, S 30.0, H 25.0)D (P 57.0, S 38.0, H 5.0) andF (P 5.0, S 90.0, H 5.0).The composition also contains a solubility enhancing agent consisting of one or more inorganic halide, such as alkali metal halides, alkaline earth metal halides and ammonium halides, in amount of from 5 to 60%, based on the weight of the polyamide resin.
    Type: Grant
    Filed: August 14, 1979
    Date of Patent: February 10, 1981
    Assignee: Teijin Limited
    Inventors: Yorikazu Tamura, Akihiro Aoki, Hiroshi Mera, Keizo Shimada
  • Patent number: 4245066
    Abstract: A wholly aromatic polyamide composition which is suitable for producing filaments or fibers having not only an excellent heat-resisting property but also, a superior dyeing property, which comprises:(A) 50 to 95% by weight of poly-m-phenylene isophthalamide, and;(B) 5 to 50% by weight of at least one other aromatic polyamide comprising:(1) an amine moiety consisting of essentially of (a) 35 to 100 molar % of at least one phenylene diamine in which the phenylene group has 1 to 4 substituents respectively selected, independently from each other, from the group consisting of halogen atoms and alkyl radicals having 1 to 4 carbon atoms, and (b) 0 to 65 molar % of at least one other aromatic diamine, and;(2) an acid moiety consisting essentially of at least one aromatic dicarboxylic acid.
    Type: Grant
    Filed: July 19, 1979
    Date of Patent: January 13, 1981
    Assignee: Teijin Limited
    Inventors: Yasuo Nakagawa, Keizo Shimada, Tsutomu Nakamura
  • Patent number: 4167506
    Abstract: A group of novel polynuclear heterocyclic compounds having a diazaphenalene skeleton. These compounds assume orange to reddish violet colors according to the types of substituents on the diazaphenalene skeleton, and have excellent thermal stability and weatherability and good dispersibility in polymeric materials. They are useful as orange to reddish violet pigments, especially for coloring polymeric materials.
    Type: Grant
    Filed: September 13, 1977
    Date of Patent: September 11, 1979
    Assignee: Teijin Limited
    Inventors: Keizo Shimada, Toshiaki Harada, Masahiro Koga, Shizuo Nagahama, Hiroyoshi Minematsu, Hidetsugu Yoshida
  • Patent number: 4150025
    Abstract: A compound of the formula ##STR1## wherein R.sub.1 represents a hydrogen atom or a lower alkyl group; R.sub.2 and R.sub.5, independently from each other, represent a hydrogen atom, a halogen atom or a lower alkyl group; one of R.sub.3 and R.sub.4 represents an imido group of the formula ##STR2## in which Y represents a 1,2-phenylene, 1,2-naphthylene, 2,3-naphthylene or 1,8-naphtylene group optionally containing at least one substituent, and the other represents a hydrogen atom, a halogen atom or a lower alkyl group; R.sub.6 represents a hydrogen atom, a halogen atom, a lower alkyl group or a lower alkoxy group; and X represents a halogen atom; with the proviso that when R.sub.3 represents the imido group, R.sub.2 represents a hydrogen or halogen atom. This compound can be prepared by reacting a corresponding quinaldine derivative with a tetrahalophthalic acid or a reactive derivative thereof. A yellow organic pigment comprising this compound as a coloring ingredient is useful for coloring polymeric materials.
    Type: Grant
    Filed: February 10, 1977
    Date of Patent: April 17, 1979
    Assignee: Teijin Limited
    Inventors: Keizo Shimada, Toshiaki Harada, Masahiro Koga
  • Patent number: 4077960
    Abstract: A compound of the formula ##STR1## wherein Y represents an arylene group optionally substituted by a halogen atom, an arylsulfonyl group or an acyl group, Z represents a 1,2-naphthylene, 2,3-naphthylene, 1,8-naphthylene or 2, 2'-biphenylene group optionally substituted by a halogen atom, and either one or both of the rings A and B optionally contain a substituent. This compound can be obtained by reacting a quinoline derivative with an aryldicarboxylic acid or its reactive derivative, and if desired, halogenating the resulting product. A yellow organic pigment comprising this compound as a coloring ingredient is useful for coloring polymeric materials.
    Type: Grant
    Filed: June 8, 1976
    Date of Patent: March 7, 1978
    Assignee: Teijin Limited
    Inventors: Keizo Shimada, Toshiaki Harada, Masahiro Koga
  • Patent number: 4067870
    Abstract: A compound of the following formula ##STR1## wherein R represents an alkyl group containing 1 to 4 carbon atoms or a phenyl group; X.sub.1 represents a chlorine or bromine atom; Y represents the group of the formula ##STR2## WHEREIN X.sub.2 and X.sub.3 each represent a chlorine or bromine atom, and n is an integer of 2 to 4; and ring A may be substituted by an alkyl group containing 1 to 4 carbon atoms and or a halogen atom.The compound of formula (I) can be easily produced by reacting a quinoline derivative of the formula ##STR3## wherein R, X.sub.1 and the ring A are the same as defined above, with an aryldicarboxylic acid or its reactive derivatives.The compounds of formula (I) are useful as yellow organic pigments.
    Type: Grant
    Filed: August 26, 1976
    Date of Patent: January 10, 1978
    Assignee: Teijin Limited
    Inventors: Keizo Shimada, Toshiaki Harada, Masahiro Koga, Shizuo Nagahama
  • Patent number: 3966830
    Abstract: A process for nitrating halogenated benzene derivatives which comprises reacting in the vapor phase a halogenated benzene derivative with at least one member selected from the group consisting of nitric acid, nitrogen dioxide and nitrogen pentoxide in the presence of at least one solid inorganic oxide selected from the group consisting of silica, alumina and silica-alumina.
    Type: Grant
    Filed: November 12, 1974
    Date of Patent: June 29, 1976
    Assignee: Teijin Limited
    Inventors: Keizo Shimada, Takeo Nishikawa, Toshiaki Harada, Shizuo Nagahama
  • Patent number: 3936509
    Abstract: A process for separating dimethyl naphthalenes having a component comprising 2,6-dimethyl naphthalene in the form of complexes with a complex-forming compound, which comprises contacting a dimethyl naphthalene isomer mixture comprising at least 2,6-dimethyl naphthalene or a hydrocarbon mixture containing said dimethyl naphthalene isomer mixture with a complex-forming compound selected from the group consisting of nitro compounds of 2,6-naphthalene dicarboxylic acid, trimellitic anhydride and 2-chloro-5-nitrobenzoic acid, thereby to form a mixture of complexes of the dimethyl naphthalenes with said complex-forming compound having a main component comprising a complex of 2,6-dimethyl naphthalene with the complex-forming compound, and separating the complexes in the solid state from the reaction mixture.
    Type: Grant
    Filed: November 4, 1974
    Date of Patent: February 3, 1976
    Assignee: Teijin Limited
    Inventors: Shizuo Nagahama, Keizo Shimada, Takeo Nishikawa, Toshiaki Harada