Abstract: Aspects of the present disclosure provide a system for a carbon oxide electrolysis plant incorporating advanced electrochemical reactors incorporating membrane electrode assemblies as well as control mechanisms. The system provides efficient transport and production rates while minimizing the competing hydrogen formation reaction. The system may use multiple electrochemical reactors, scaling up production with high energy efficiency, while providing flexibility in the types of chemical product outputs.

Abstract: Provided herein are methods for operating carbon oxide (COx) reduction reactors (CRR) and related apparatus. In some embodiments, the methods involve shutting off, reducing, or otherwise controlling current during various operation stages including hydration, break-in, normal operation, planned shut-offs, and extended shutoff or storage periods.

Abstract: Provided herein are membrane electrode assemblies (MEAs) for COx reduction. According to various embodiments, the MEAs are configured to address challenges particular to COx including managing water in the MEA. Bipolar and anion-exchange membrane (AEM)-only MEAs are described along with components thereof and related methods of fabrication.

Abstract: Provided herein are methods for operating carbon oxide (COx) reduction reactors (CRR) and related apparatus. In some embodiments, the methods involve shutting off, reducing, or otherwise controlling current during various operation stages including hydration, break-in, normal operation, planned shut-offs, and extended shutoff or storage periods.

Abstract: A platform technology that uses a novel membrane electrode assembly, including a cathode layer, an anode layer, a membrane layer arranged between the cathode layer and the anode layer, the membrane conductively connecting the cathode layer and the anode layer, in a COx reduction reactor has been developed. The reactor can be used to synthesize a broad range of carbon-based compounds from carbon dioxide and other gases containing carbon.

Abstract: A method of forming a gas diffusion layer includes causing, at least in part, a stack of layers to be arranged between compressing surfaces of a press, the stack of layers including a plurality of gas diffusion layers. The method also includes causing, at least in part, the press to apply one or more compression cycles to the stack of layers to reduce a combined, uncompressed thickness of the plurality of gas diffusion layers between about 2% and about 30%.

Abstract: Provided herein are membrane electrode assemblies (MEAs) for COx reduction and carbon dioxide reduction reactors (CRRs) that include MEAs.

Abstract: A system optionally including a carbon oxide reactor. A method for carbon oxide reactor control, optionally including selecting carbon oxide reactor aspects based on a desired output composition, running a carbon oxide reactor under controlled process conditions to produce a desired output composition, and/or altering the process conditions to alter the output composition.

Abstract: Provided herein are membrane electrode assemblies (MEAs) for COx reduction. According to various embodiments, the MEAs are configured to address challenges particular to COx including managing water in the MEA. Bipolar and anion-exchange membrane (AEM)-only MEAs are described along with components thereof and related methods of fabrication.

Abstract: A platform technology that uses a novel membrane electrode assembly, including a cathode layer, an anode layer, a membrane layer arranged between the cathode layer and the anode layer, the membrane conductively connecting the cathode layer and the anode layer, in a COx reduction reactor has been developed. The reactor can be used to synthesize a broad range of carbon-based compounds from carbon dioxide and other gases containing carbon.

Abstract: Systems and methods for increasing the concentration of a desired COx reduction reaction product are described. In some embodiments, the systems and methods include ethylene purification.

Abstract: Disclosed are membrane electrode assemblies having a cathode layer comprising a carbon oxide reduction catalyst that promotes reduction of a carbon oxide; an anode layer comprising a catalyst that promotes oxidation of a water; a polymer electrolyte membrane (PEM) layer disposed between, and in contact with, the cathode layer and the anode layer; and a salt having a concentration of at least about 10 uM in at least a portion of the MEA.

Abstract: Disclosed are membrane electrode assemblies having a cathode layer comprising a carbon oxide reduction catalyst that promotes reduction of a carbon oxide; an anode layer comprising a catalyst that promotes oxidation of a water; a polymer electrolyte membrane (PEM) layer disposed between, and in contact with, the cathode layer and the anode layer; and a salt having a concentration of at least about 10 uM in at least a portion of the MEA.

Abstract: Provided herein are methods for operating carbon oxide (COX) reduction reactors (CRR) and related apparatus. In some embodiments, the methods involve shutting off, reducing, or otherwise controlling current during various operation stages including hydration, break-in, normal operation, planned shut-offs, and extended shutoff or storage periods.

Abstract: Methods and/or systems for operating a carbon oxide reduction electrolyzer may involve (a) performing normal operation at the electrolyzer; (b) performing a recovery or protection process including: (i) applying a modified current and/or voltage to the electrolyzer, and (ii) while applying the reverse current to the electrolyzer, flowing a recovery gas to the cathode; and (c) resuming normal operation at the electrolyzer. Applying a modified current and/or voltage may involve applying a short circuit to the electrolyzer, holding the electrolyzer electrodes at open circuit voltage, and/or applying a reverse current to the electrolyzer.

Abstract: Provided herein are methods for operating carbon oxide (COx) reduction reactors (CRR) and related apparatus. In some embodiments, the methods involve shutting off, reducing, or otherwise controlling current during various operation stages including hydration, break-in, normal operation, planned shut-offs, and extended shutoff or storage periods.

Abstract: Various COx electrolyzer cell architectures are provided, including various flow field designs and gas diffusion layer designs that may be particularly useful in the context of COx electrolyzer cells.

Abstract: A system optionally including a carbon oxide reactor. A method for carbon oxide reactor control, optionally including selecting carbon oxide reactor aspects based on a desired output composition, running a carbon oxide reactor under controlled process conditions to produce a desired output composition, and/or altering the process conditions to alter the output composition.

Abstract: A system optionally including a carbon oxide reactor. A method for carbon oxide reactor control, optionally including selecting carbon oxide reactor aspects based on a desired output composition, running a carbon oxide reactor under controlled process conditions to produce a desired output composition, and/or altering the process conditions to alter the output composition.

Abstract: A platform technology that uses a novel membrane electrode assembly including a cathode layer comprising a reduction catalyst and a first anion-and-cation-conducting polymer, an anode layer comprising an oxidation catalyst and a cation-conducting polymer, a membrane layer comprising a cation-conducting polymer, the membrane layer arranged between the cathode layer and the anode layer and conductively connecting the cathode layer and the anode layer, in a COx reduction reactor has been developed. The reactor can be used to synthesize a broad range of carbon-based compounds from carbon dioxide.