Abstract: A reflective mask blank includes a substrate; a multilayer reflective film that reflects EUV light; a protection film that protects the multilayer reflective film; and a phase shift film that shifts a phase of the EUV light, the substrate, the multilayer reflective film, the protection film, and the phase shift film being arranged in this order. The phase shift film contains at least one first element X1 selected from the first group consisting of ruthenium (Ru), iridium (Ir), platinum (Pt), palladium (Pd), and gold (Au), and at least one second element X2 selected from the second group consisting of oxygen (O), boron (B), carbon (C), and nitrogen (N). In the phase shift film, a chemical shift of a peak of 3d5/2 or a peak of 4f7/2 of the first element X1 observed by X-ray electron spectroscopy is less than 0.3 eV.

Abstract: According to the present invention, an exhaust gas purification catalyst that has both a warming performance and a high load performance is provided. By the present invention, provided is the exhaust gas purification catalyst including a base material and a catalyst coated layer. The catalyst coated layer includes a former stage part and a latter stage part. An alumina content X1 in the former stage part per volume of the base material is not more than an alumina content X2 in the latter stage part per volume of the base material A ratio (Y2/Y1) of a coating amount Y2 in the latter stage part per volume of the base material to a coating amount Y1 in the former stage part per volume of the base material satisfies 1.0<(Y2/Y1)?2.0.

Abstract: This exhaust gas cleaning catalytic device includes a base material and a first catalyst coat layer on the base material. The first catalyst coat layer has a pre-stage section on an exhaust gas flow upstream side, and a post-stage section on an exhaust gas flow downstream side. The first catalyst coat layer pre-stage section and post-stage section each contain inorganic oxide particles and rhodium supported by the inorganic oxide particles, while at least some of the inorganic oxide particles contain ceria. The ceria amount per unit length of the first catalyst coat layer post-stage section is larger than the ceria amount per unit length of the first catalyst coat layer pre-stage section. The first catalyst coat layer pre-stage section is disposed in such a manner that the end portion on the exhaust gas flow upstream side thereof is in direct contact with the exhaust gas flow.

Abstract: This exhaust gas cleaning catalytic device includes a base material and a first catalyst coat layer on the base material. The first catalyst coat layer has a pre-stage section on an exhaust gas flow upstream side, and a post-stage section on an exhaust gas flow downstream side. The first catalyst coat layer pre-stage section and post-stage section each contain inorganic oxide particles and rhodium supported by the inorganic oxide particles, while at least some of the inorganic oxide particles contain ceria. The ceria amount per unit length of the first catalyst coat layer post-stage section is larger than the ceria amount per unit length of the first catalyst coat layer pre-stage section. The first catalyst coat layer pre-stage section is disposed in such a manner that the end portion on the exhaust gas flow upstream side thereof is in direct contact with the exhaust gas flow.

Abstract: An exhaust gas purifying catalyst according to the present invention is provided with a base material 10 and a catalyst-coated layer 30. The catalyst-coated layer 30 is provided with a lower layer 34 and an upper layer 32. The upper layer 32 contains Rh and/or Pt as a noble metal catalyst. The lower layer 34 contains Pd as a noble metal catalyst. The lower layer 34 is provided with a front-stage lower layer 34a positioned on an upstream side and a rear-stage lower layer 34b positioned on a downstream side. The front-stage lower layer 34a is a Ce-free layer that does not contain a Ce-containing oxide. The rear-stage lower layer 34b is a Ce-containing layer that contains a Ce-containing oxide with a pyrochlore structure.

Abstract: An exhaust gas purification device which has improved exhaust gas purification performance. An exhaust gas purification device which includes a first catalyst layer that contains: a Pd-supporting catalyst which is obtained by having alumina carrier particles support Pd; a first Rh-supporting catalyst which is obtained by having first ceria-zirconia carrier particles support Rh; and second ceria-zirconia carrier particles. This exhaust gas purification device is configured such that: the ceria concentration in the first ceria-zirconia carrier particles is 30 wt % or less; and the amount of ceria in the second ceria-zirconia carrier particles is larger than the amount of ceria in the first ceria-zirconia carrier particles.

Abstract: The exhaust gas purification catalyst according to the present invention includes a substrate 10 and a catalyst coat layer 30. The catalyst coat layer 30 is formed into a multilayer structure having a lower layer 32, a middle layer 34 and an upper layer 36. The upper layer 36 contains Rh and a Ce-containing oxide. The lower layer 32 contains Pd and a Ce-containing oxide. The middle layer 34 is a Ce-free layer that contains Pd but does not contain a Ce-containing oxide. A ratio (B/A) of the content B of Ce in the lower layer 32 to the content A of Ce in the upper layer 36 satisfies 2?(B/A).

Abstract: An exhaust gas-purifying catalyst includes a support and a catalytic metal supported thereby. The support includes a composite oxide represented by AO.xB2-?C?O3, wherein A represents at least one of an element having a valence of 1 and an element having a valence of 2, B represents an element having a valence of 3, C represents one or more elements selected from iridium, ruthenium, tantalum, niobium, molybdenum, and tungsten, x represents a numerical value of 1 to 6, and ? represents a numerical value greater than 0 and less than 2. The catalytic metal includes one or more precious metals selected from rhodium, palladium, and platinum.

Abstract: An exhaust gas purifying catalyst according to the present invention is provided with a base material 10 and a catalyst-coated layer 30. The catalyst-coated layer 30 is provided with a lower layer 34 and an upper layer 32. The upper layer 32 contains Rh and/or Pt as a noble metal catalyst. The lower layer 34 contains Pd as a noble metal catalyst. The lower layer 34 is provided with a front-stage lower layer 34a positioned on an upstream side and a rear-stage lower layer 34b positioned on a downstream side. The front-stage lower layer 34a is a Ce-free layer that does not contain a Ce-containing oxide. The rear-stage lower layer 34b is a Ce-containing layer that contains a Ce-containing oxide with a pyrochlore structure.

Abstract: An exhaust gas purification device which has improved exhaust gas purification performance. An exhaust gas purification device which includes a first catalyst layer that contains: a Pd-supporting catalyst which is obtained by having alumina carrier particles support Pd; a first Rh-supporting catalyst which is obtained by having first ceria-zirconia carrier particles support Rh; and second ceria-zirconia carrier particles. This exhaust gas purification device is configured such that: the ceria concentration in the first ceria-zirconia carrier particles is 30 wt % or less; and the amount of ceria in the second ceria-zirconia carrier particles is larger than the amount of ceria in the first ceria-zirconia carrier particles.

Abstract: An exhaust gas-purifying catalyst of the present invention comprises a substrate, and one or more catalytic layers provided on the substrate, wherein at least one of the catalytic layers (i) contains a precious metal, alumina, and an acidic oxide element, (ii) has a correlation coefficient ?Al,AE of 0.70 or more, and (iii) has a correlation coefficient ?PM,AE of 0.70 or more.

Abstract: A catalyst for exhaust gas purification, which is capable of effectively purifying an exhaust gas. A catalyst for exhaust gas purification, which includes first catalyst particles, second catalyst particles and carrier particles that support the first catalyst particles and the second catalyst particles. The first catalyst particles are Pd particles or Pd—Rh alloy particles; and the second catalyst particles are Pd—Rh alloy particles. The molar ratio of Rh to the total of Pd and Rh in the first catalyst particles is 0.50 times or less the molar ratio of Rh to the total of Pd and Rh in the second catalyst particles.

Abstract: An exhaust gas-purifying catalyst includes a support and a catalytic metal as one or more precious metals supported by the support. The support includes a composite oxide having a composition represented by a general formula AB?C?O3, wherein A represents one or more elements selected from the group consisting of lanthanum, neodymium, and yttrium, B represents iron or a combination of iron and aluminum, C represents one or more elements selected from the group consisting of iridium, ruthenium, tantalum, niobium, molybdenum, and tungsten, ? and ? each represents a numerical value within a range of more than 0 and less than 1, and ? and ? satisfy relational formulae of ?>? and ?+??1.

Abstract: The exhaust gas-purifying catalyst of the invention contains oxide particles having interdispersed therein A crystallites that are loaded with a noble metal and B crystallites that are not loaded with a noble metal. The A crystallites loaded with a noble metal are composed of an oxide containing at least one of zirconium (Zr) and cerium (Ce). The B crystallites not loaded with a noble metal are composed of a cerium (Ce)-containing oxide which has a higher Ce content (mol %) than the oxide making up the A crystallites. The oxide particles have a specific surface area after 5 hours of heat treatment at 1,150° C. in open air of 30 m2/g or more.

Abstract: The exhaust gas purifying catalyst presented here includes a substrate and a catalyst coat layer formed on the surface of the substrate. The catalyst coat layer is formed in a laminate structure having two layers, with a first layer being nearer to the surface of the substrate and a second layer being relatively further from this surface. The second layer includes a carrier and a noble metal supported on the carrier. The first layer is a noble metal-free layer that does not contain a noble metal but does contain an OSC material having oxygen storage capacity.

Abstract: An exhaust gas-purifying catalyst of the present invention comprises a substrate, and one or more catalytic layers provided on the substrate, wherein at least one of the catalytic layers (i) contains a precious metal, alumina, and an acidic oxide element, (ii) has a correlation coefficient ?Al,AE of 0.70 or more, and (iii) has a correlation coefficient ?PM,AE of 0.70 or more.

Abstract: An exhaust gas-purifying catalyst material includes first oxide particles having an average particle diameter Dav of 1 ?m to 95 ?m and having an oxygen storage capacity, second oxide particles having an average particle diameter Dav of 0.05 ?m to 0.5 ?m, containing a metal element, and having no oxygen storage capacity, precious metal particles, and acidic oxide particles. The material has a correlation coefficient ? of 0.45 or more obtained using first characteristic X-ray intensity for the metal element contained in the second oxide particle, second characteristic X-ray intensity for an element other than oxygen contained in the acidic oxide particle, and third characteristic X-ray intensity for a precious metal element contained in the precious metal particle.

Abstract: An exhaust gas-purifying catalyst material includes first oxide particles having an average particle diameter Dav of 1 ?m to 95 ?m and having an oxygen storage capacity, second oxide particles having an average particle diameter Dav of 0.05 ?m to 0.5 ?m, containing a metal element, and having no oxygen storage capacity, precious metal particles, and acidic oxide particles. The material has a correlation coefficient ? of 0.45 or more obtained using first characteristic X-ray intensity for the metal element contained in the second oxide particle, second characteristic X-ray intensity for an element other than oxygen contained in the acidic oxide particle, and third characteristic X-ray intensity for a precious metal element contained in the precious metal particle.

Abstract: The exhaust gas-purifying catalyst of the invention includes a noble metal, and crystallites that form CZ composite metal particles which serve as a carrier supporting the noble metal and contain at least zirconium (Zr) and cerium (Ce). The CZ composite oxide particles (crystallites) further contain crystal growth-suppressing fine particles which are fine metal particles comprising primarily a metallic element M that melts at 1,500° C. or above and which suppress crystal growth by the CZ composite oxide particles. The content of the metallic element M included in the CZ composite oxide particles, expressed in terms of the oxide thereof, is 0.5 mol % or less of the total oxide.

Abstract: An exhaust gas-purifying catalyst includes a support and a catalytic metal as one or more precious metals supported by the support. The support includes a composite oxide having a composition represented by a general formula AB?C?O3, wherein A represents one or more elements selected from the group consisting of lanthanum, neodymium, and yttrium, B represents iron or a combination of iron and aluminum, C represents one or more elements selected from the group consisting of iridium, ruthenium, tantalum, niobium, molybdenum, and tungsten, ? and ? each represents a numerical value within a range of more than 0 and less than 1, and ? and ? satisfy relational formulae of ?>? and ?+??1.