Abstract: The lubricating oil for refrigerator according to the present invention is a lubricating oil for refrigerator using 1,1,1,2-tetrafluoroethane refrigerant. Having esters as base oil, its viscosity range is between 2-30 mm/s at 100.degree.C. By adding esters alone or by adding esters having different viscosity to esters base oil, or by adding polymer, the viscosity is adjusted to obtain the lubricating oil suitable for various types of refrigerators. The lubricating oil thus obtained has excellent compatibility with 1,1,1,2-tetrafluoroethane refrigerant, which is an alternative to freon, and has low hygroscopic property and high heat-resistant property.By reducing the total acid number to 0.05 mg KOH/g or less, the corrosion-resistant property and insulating property of lubricating oil are not decreased, and the lubricating oil for refrigerator having having high refrigerant stability, hydrolytic stability and insulating property can be obtained.

Abstract: This invention relates to a method for catalytically manufacturing a low pour point petroleum product from distillates of crude oil, and more particularly to a method for economically manufacturing a low pour point petroleum product, such as the insulating oil, the lubricating oil used for various types of freezing devices, or the base oil for such lubricating oil, from a paraffin-based crude oil as the starting material without using any special rare crude oil such as naphthene-based crude oil. The catalyst comprises zeolite TSZ.