Abstract: A polytetrafluoroethylene having a breaking strength of 10.0 N or more and a thermal instability index (TII) of 20 or more. Also disclosed is a stretched body including the polytetrafluoroethylene.

Abstract: A composition including a polytetrafluoroethylene and a polymer (I) containing a polymerization unit (I) based on a monomer represented by the following general formula (I), the composition having a standard specific gravity of 2.200 or less: CX1X3=CX2R(—CZ1Z2-A0)m??(I) wherein X1 and X3 are each independently F, Cl, H, or CF3; A0 is an anionic group; X2 is H, F, an alkyl group, or a fluorine-containing alkyl group; R is a linking group; Z1 and Z2 are each independently H, F, an alkyl group, or a fluorine-containing alkyl group; and m is an integer of 1 or more.

Abstract: There is provided a method for producing a fluoropolymer, the method including polymerizing a fluoromonomer in an aqueous medium to obtain a polymerization dispersion containing the fluoropolymer, and bringing the fluoropolymer in the polymerization dispersion into contact with an alcohol having 3 to 5 carbon atoms to coagulate the fluoropolymer to thereby obtain the fluoropolymer.

Abstract: Provided is a method for producing a composition containing a fluororesin, the method comprising polymerizing tetrafluoroethylene in an aqueous medium in the presence of a polymer (I) containing a polymerization unit (I) derived from a monomer (I) represented by the general formula (I) to obtain a polymerization dispersion containing a fluororesin containing a tetrafluoroethylene unit, coagulating the fluororesin in the polymerization dispersion to obtain a coagulate, and washing the coagulate to obtain a composition containing the fluororesin, wherein (1) the coagulation is carried out by bringing the fluororesin in the polymerization dispersion into contact with an organic solvent, and/or (2) the washing is carried out by bringing the coagulate into contact with an organic solvent, CX1X3?CX2R(—CZ1Z2-A0)m??(I) wherein the definitions of the reference signs in the formula are as provided in the specification.

Abstract: A composition including a polytetrafluoroethylene and a polymer (I) containing a polymerization unit (I) based on a monomer represented by the following general formula (I), the composition having a standard specific gravity of 2.200 or less: CX1X3?CX2R(—CZ1Z2-A0)m??(I) wherein X1 and X3 are each independently F, Cl, H, or CF3; A0 is an anionic group; X2 is H, F, an alkyl group, or a fluorine-containing alkyl group; R is a linking group; Z1 and Z2 are each independently H, F, an alkyl group, or a fluorine-containing alkyl group; and m is an integer of 1 or more.

Abstract: A metal pattern forming method has: producing a first base having a pattern of lyophilic portions which have lyophilic properties with respect to a liquid containing a metal component and liquid-repellent portions which have liquid-repellent properties with respect to the liquid containing a metal component; producing a second base which holds the liquid containing a metal component; and transferring the liquid containing a metal component from the second base to the lyophilic portions of the first base by bringing the first base and the second base into contact with each other. With the metal pattern forming method, it is possible to form a metal pattern with high accuracy in which the metal is prevented from adhering to an unnecessary position on the base.

Abstract: Composition including (a) a fluoropolymer; and (b1) at least one of a compound represented by the formula (4) ((H—(CF2)7—COO)pM1) or the formula (4?) ((H—(CF2)8—COO)pM1) of the present disclosure, both respectively in an amount of 100 ppb or less relative to the fluoropolymer, or (b2) at least one of a compound represented by the formula (5) ((H—(CF2)13—COO)pM1) or the formula (5?) ((H—(CF2)14—COO)pM1) of the present disclose, both respectively in an amount of 100 ppb or less relative to the fluoropolymer.

Abstract: A composition including a fluoropolymer and substantially free from a compound represented by the following formula (3): (H—(CF2)8—SO3)qM2, wherein M2 is H, a metal atom, NR54, imidazolium optionally containing a substituent, pyridinium optionally containing a substituent, or phosphonium optionally containing a substituent; R5s are each H or an organic group and are the same as or different from each other; and q is 1 or 2.

Abstract: A method for producing a polytetrafluoroethylene powder, which includes subjecting tetrafluoroethylene to suspension polymerization in an aqueous medium to prepare a suspension-polymerized particle of non melt-processible polytetrafluoroethylene, drying the suspension-polymerized particle to prepare a dry particle, subjecting the dry particle to fluorine radical treatment to prepare a fluorine radical-treated particle, and crushing the fluorine radical-treated particle to produce a polytetrafluoroethylene powder. Also disclosed is a polytetrafluoroethylene formed article obtained by forming the polytetrafluoroethylene powder, as well as a polytetrafluoroethylene compression-molded article obtained by compression molding the polytetrafluoroethylene powder.

Abstract: Provided is a method for producing a fluoropolymer composition, comprising bringing a fluoropolymer raw material into contact with an oxidizing agent, wherein the fluoropolymer raw material is obtained by polymerizing a fluoromonomer in an aqueous medium in the presence of a polymer (I) containing a polymerization unit (I) derived from a monomer (I) represented by the general formula (I). CX1X3?CX2R(—CZ1Z2-A0)m??(I) wherein X1 and X3 are each independently F, Cl, H, or CF3; X2 is H, F, an alkyl group, or a fluorine-containing alkyl group; A0 is an anionic group; R is a linking group; Z1 and Z2 are each independently H, F, an alkyl group, or a fluorine-containing alkyl group; and m is an integer of 1 or more.

Abstract: A method for producing a fluoropolymer which method includes polymerizing a perfluoromonomer in an aqueous medium in the presence of a polymer (1) to obtain a fluoropolymer, wherein the content of a polymerized unit derived from the perfluoromonomer in the fluoropolymer is 90 mol % or more based on all polymerized units of the fluoropolymer, the polymer (1) is a polymer of a monomer (1) represented by the general formula (1): CF2?CF—O—R-(Rf-SO3M)m, a polymerized unit (1) derived from the monomer (1) in the polymer (1) is 50% by mass or more based on all polymerized units of the polymer (1), and the content of a dimer and a trimer of the monomer (1) in the polymer (1) is 1.0% by mass or less based on the polymer (1).

Abstract: A method for producing polytetrafluoroethylene, which includes polymerizing tetrafluoroethylene in an aqueous medium in the presence of a nucleating agent and a hydrocarbon anionic surfactant to obtain polytetrafluoroethylene. A total amount of the nucleating agent and the hydrocarbon anionic surfactant at the initiation of polymerization is more than 50 ppm based on the aqueous medium.

Abstract: The present disclosure provides a method for producing a fluororesin, which includes polymerizing a fluorine-containing monomer in the presence of a compound (1) having triple bond and a hydrophilic group and an aqueous medium to produce a fluororesin, a fluororesin comprising a unit based on a compound (1) having triple bond and a hydrophilic group, and a fluorine-containing monomer unit, and an aqueous dispersion comprising the fluororesin and an aqueous medium.

Abstract: A method for producing a fluoropolymer, which includes polymerizing a fluoromonomer in an aqueous medium in the presence of a polymer (1), the polymer (1) including a polymerized unit derived from a monomer CX2?CY(—CZ2—O—Rf-A), wherein X is the same or different and is —H or —F; Y is —H, —F, an alkyl group, or a fluorine-containing alkyl group; Z is the same or different and is —H, —F, an alkyl group, or a fluoroalkyl group; Rf is a C1-C40 fluorine-containing alkylene group or a C-C100 fluorine-containing alkylene group and having an ether bond; and A is —COOM, —SO3M, or —OSO3M, wherein M is —H, a metal atom, —NR74, imidazolium optionally having a substituent, pyridinium optionally having a substituent, or phosphonium optionally having a substituent, wherein R7 is H or an organic group, providing that at least one of X, Y, and Z contains a fluorine atom.

Abstract: A method for producing a polytetrafluoroethylene, which includes polymerizing tetrafluoroethylene in an aqueous medium in the presence of a polymer (1) to obtain the polytetrafluoroethylene, wherein the polymer (1) is a polymer of a monomer (1) represented by the general formula (1): CF2?CF(—O—Rf-A), has a weight average molecular weight of 1.4×104 or more, wherein a content of a polymerization unit (1) based on the monomer (1) is 40 mol % or more based on all polymerization units constituting the polymer (1), and a content of a dimer and a trimer of the monomer (1) is 1.0% by mass or less based on the polymer (1).

Abstract: A method for producing a fluoropolymer, which includes polymerizing a fluoromonomer in an aqueous medium in the presence of a polymer (1), the polymer (1) including a polymerized unit derived from a monomer CX2?CY(—CZ2—O—Rf-A), wherein X is the same or different and is —H or —F; Y is —H, —F, an alkyl group, or a fluorine-containing alkyl group; Z is the same or different and is —H, —F, an alkyl group, or a fluoroalkyl group; Rf is a C1-C40 fluorine-containing alkylene group or a C—C100 fluorine-containing alkylene group and having an ether bond; and A is —COOM, —SO3M, or —OSO3M, wherein M is —H, a metal atom, —NR74, imidazolium optionally having a substituent, pyridinium optionally having a substituent, or phosphonium optionally having a substituent, wherein R7 is H or an organic group, providing that at least one of X, Y, and Z contains a fluorine atom.

Abstract: A method for producing a fluoropolymer which includes polymerizing a fluoromonomer in an aqueous medium in the presence of a surfactant to provide a fluoropolymer, the surfactant being represented by the general formula (1): CR1R2R4—CR3R5—X-A, wherein R1 to R5 are each H or a monovalent substituent, with the proviso that at least one of R1 and R3 represents a group represented by the general formula: —Y—R6 and at least one of R2 and R3 represents a group represented by the general formula: —X-A or a group represented by the general formula: —Y—R6; and A is the same or different at each occurrence and is —COOM, —SO3M, or —OSO3M. Also disclosed is a surfactant for polymerization represented by the general formula (1), a method for producing a fluoropolymer using the surfactant, a composition including a fluoropolymer and the surfactant and a molded body including the composition.

Abstract: A method for producing a fluoropolymer which includes polymerizing a fluoromonomer in an aqueous medium in the presence of a surfactant to provide a fluoropolymer, the surfactant being represented by the general formula (1): CR1R2R4—CR3R5—X-A, wherein R1 to R5 are each H or a monovalent substituent, with the proviso that at least one of R1 and R3 represents a group represented by the general formula: —Y—R6 and at least one of R2 and R5 represents a group represented by the general formula: —X-A or a group represented by the general formula: —Y—R6; and A is the same or different at each occurrence and is —COOM, —SO3M, or —OSO3M. Also disclosed is a surfactant for polymerization represented by the general formula (1), a method for producing a fluoropolymer using the surfactant and a composition including a fluoropolymer and the surfactant.

Abstract: A composition including a fluoropolymer and substantially free from a compound represented by the following formula (3): (H—(CF2)8—SO3)qM2, wherein M2 is H, a metal atom, NR54, imidazolium optionally containing a substituent, pyridinium optionally containing a substituent, or phosphonium optionally containing a substituent; R5s are each H or an organic group and are the same as or different from each other; and q is 1 or 2.

Abstract: A metal pattern forming method has: producing a first base having a pattern of lyophilic portions which have lyophilic properties with respect to a liquid containing a metal component and liquid-repellent portions which have liquid-repellent properties with respect to the liquid containing a metal component; producing a second base which holds the liquid containing a metal component; and transferring the liquid containing a metal component from the second base to the lyophilic portions of the first base by bringing the first base and the second base into contact with each other. With the metal pattern forming method, it is possible to form a metal pattern with high accuracy in which the metal is prevented from adhering to an unnecessary position on the base.