Abstract: A molten iron refining method having, an auxiliary material, and an oxidizing gas supplied through a top-blowing lance, to a cold iron source and molten pig iron that are contained/fed in a converter-type vessel, and molten iron is subjected to a refining process. A pre-charged cold iron source is charged into the converter-type vessel at an amount not larger than 0.15 times. A furnace-top-added cold iron source that's part or all of the cold iron source and added from a furnace top is fed during the refining process. A burner at a leading end of the top-blowing lance that spray holes through which a fuel and a combustion-supporting gas are ejected. During the refining process, a powdery auxiliary material processed into powder that's part of the auxiliary material is blown in, to pass through a flame formed by the burner.

Abstract: A method that, regarding a process of refining molten iron, can increase the thermal margin and the amount of cold iron source to be used. A burner having jetting holes for jetting a fuel and a combustion supporting gas is provided at a leading end part of one lance that top-blows an oxidizing gas to molten iron contained in a converter-type vessel, or at a leading end part of another separate lance. A powdery auxiliary raw material or an auxiliary raw material processed into a powder form that is blown into the molten iron from the one lance or the other lance passes through a flame formed by the burner. This top-blowing lance for a converter is configured to secure a predetermined heating time and powder-fuel ratio. Also, a method for adding an auxiliary raw material and a method for refining of molten iron that use this top-blowing lance.

Abstract: Proposed is a molten iron refining method capable of securing an in-flame staying time period of a heat transfer medium without being influenced by height adjustments of a blowing-purpose oxygen-blowing lance. As far as to a position lower than an upper end inside a converter-type vessel 1, a blowing-purpose oxygen-blowing lance 3 that supplies oxidizing gas and is capable of ascending and descending and at least one burner lance 4 capable of ascending and descending independently of the blowing-purpose oxygen-blowing lance are inserted. From the blowing-purpose oxygen-blowing lance, either oxidizing gas or oxidizing gas and CaO-containing refining agent are blown onto the molten iron. Also, a flame is formed by causing the burner lance to discharge fuel gas and combustion supporting gas. Powder particles discharged from the burner lance are caused to pass through the flame and to be blown onto the molten iron in a heat-transferred state, so that the molten iron is thermally compensated.

Abstract: Proposed is a method for removing phosphorus from a phosphorus-containing substance which is applicable in an industrial scale so as to effectively reduce phosphorus contained in the phosphorus-containing substance. In this method, the phosphorus-containing substance used as a raw material for metal smelting or metal refining is reacted with a nitrogen-containing gas at a treatment temperature T (° C.) which is lower than a melting temperature (Tm) of the substance, so that phosphorus is removed preferably in the form of phosphorus nitride (PN). In this regard, a nitrogen partial pressure and an oxygen partial pressure in the nitrogen-containing gas are preferably controlled, thereby reducing a load of dephosphorization process, for example.

Abstract: A method removes phosphorus from a phosphorus-containing substance. In the method, the phosphorus-containing substance that is used as a raw material for metal smelting or refining is reacted with a nitrogen-containing gas so that phosphorus in the phosphorus-containing substance is removed through nitriding. Prior to a treatment of a nitriding removal of phosphorus from the phosphorus-containing substance, a treatment is performed in which the phosphorus-containing substance is heated to an unmolten state temperature range so as to react with a reducing agent, thereby reducing at least a part of metal oxide in the phosphorus-containing substance.

Abstract: In a method for oxygen-blowing refining of molten iron, an oxygen-containing gas as a main supply gas is supplied from an inlet side of a blowing nozzle for the oxygen-containing gas passing through an outer shell of the top-blowing lance and blown from the blowing nozzle while a control gas is jetted toward inside of the blowing nozzle for at least part of a period of the oxygen-blowing refining from a spout arranged in a side face of the nozzle at a site where the cross-sectional area of the nozzle minimum takes the minimum in the axial direction of the nozzle or a neighborhood thereof so that at least part of the spout exists in each space formed by dividing into two portions by an arbitrary plane passing through a central axis of the nozzle.

Abstract: Proposed is a method for removing phosphorus from a phosphorus-containing substance which is applicable in an industrial scale so as to effectively reduce phosphorus contained in the phosphorus-containing substance. In this method, the phosphorus-containing substance used as a raw material for metal smelting or metal refining is reacted with a nitrogen-containing gas at a treatment temperature T (° C.) which is lower than a melting temperature (Tm) of the substance, so that phosphorus is removed preferably in the form of phosphorus nitride (PN). In this regard, a nitrogen partial pressure and an oxygen partial pressure in the nitrogen-containing gas are preferably controlled, thereby reducing a load of dephosphorization process, for example.

Abstract: In a method for oxygen-blowing refining of molten iron, an oxygen-containing gas as a main supply gas is supplied from an inlet side of a blowing nozzle for the oxygen-containing gas passing through an outer shell of the top-blowing lance and blown from the blowing nozzle while a control gas is jetted toward inside of the blowing nozzle for at least part of a period of the oxygen-blowing refining from a spout arranged in a side face of the nozzle at a site where the cross-sectional area of the nozzle minimum takes the minimum in the axial direction of the nozzle or a neighborhood thereof so that at least part of the spout exists in each space formed by dividing into two portions by an arbitrary plane passing through a central axis of the nozzle.

Abstract: A method for refining hot metal in a converter using a top-blowing lance having a refining powder supply channel, a combustion oxidizing gas supply channel, and a refining oxidizing gas supply channel that are separate from each other includes supplying at least one of a lime-based flux, iron oxide, and a combustible material as a refining powder from the refining powder supply channel to a surface of the hot metal using a fuel gas or a mixture of the fuel gas and an inert gas as a carrier gas while supplying a combustion oxidizing gas from the combustion oxidizing gas supply channel to form a flame below a leading end of the top-blowing lance, and supplying a refining oxidizing gas from the refining oxidizing gas supply channel to the surface of the hot metal.

Abstract: A top-blowing lance includes a refining oxygen gas blowing nozzle having a plurality of ejection openings through which oxygen gas is blown into an iron bath in a reaction vessel, the ejection openings being disposed along a circular orbit at intervals, and a burner nozzle having an axis coaxial with the central axis of the circular orbit, forming a flame inside the refining oxygen gas blowing nozzle, and having ejection openings for blowing a powder heated by the flame into the iron bath, wherein an indicator A that indicates the positional relationship between the ejection openings of the refining oxygen gas blowing nozzle and the ejection openings of the burner nozzle satisfies the specified conditions.

Abstract: A method for refining hot metal in a converter using a top-blowing lance having a refining powder supply channel, a combustion oxidizing gas supply channel, and a refining oxidizing gas supply channel that are separate from each other includes supplying at least one of a lime-based flux, iron oxide, and a combustible material as a refining powder from the refining powder supply channel to a surface of the hot metal using a fuel gas or a mixture of the fuel gas and an inert gas as a carrier gas while supplying a combustion oxidizing gas from the combustion oxidizing gas supply channel to form a flame below a leading end of the top-blowing lance, and supplying a refining oxidizing gas from the refining oxidizing gas supply channel to the surface of the hot metal.

Abstract: A top-blowing lance includes a refining oxygen gas blowing nozzle having a plurality of ejection openings through which oxygen gas is blown into an iron bath in a reaction vessel, the ejection openings being disposed along a circular orbit at intervals, and a burner nozzle having an axis coaxial with the central axis of the circular orbit, forming a flame inside the refining oxygen gas blowing nozzle, and having ejection openings for blowing a powder heated by the flame into the iron bath, wherein an indicator A that indicates the positional relationship between the ejection openings of the refining oxygen gas blowing nozzle and the ejection openings of the burner nozzle satisfies the specified conditions.