Abstract: A nanosecond pulser system is disclosed. In some embodiments, the nanosecond pulser system may include a nanosecond pulser having a nanosecond pulser input; a plurality of switches coupled with the nanosecond pulser input; one or more transformers coupled with the plurality of switches; and an output coupled with the one or more transformers and providing a high voltage waveform with a amplitude greater than 2 kV and a frequency greater than 1 kHz based on the nanosecond pulser input. The nanosecond pulser system may also include a control module coupled with the nanosecond pulser input; and an control system coupled with the nanosecond pulser at a point between the transformer and the output, the control system providing waveform data regarding an high voltage waveform produced at the point between the transformer and the output.

Abstract: A controller for an injection molding system is in communication with a melt flow control unit, a gas assist control unit, and a gas counter pressure control unit. The controller can effect real-time adjustments to gas assist pressure and/or gas counter pressure as a function of melt pressure or flow front position.

Abstract: Disclosed herein are metal-organic frameworks and methods of making and use thereof.

Abstract: A molding system and a method for operation of the molding system are provided. The method includes flowing a molten polymeric material into a shot tuning chamber from an upstream device, adjusting a temperature of and/or pressure applied to the molten polymeric material in the shot tuning chamber, and flowing the molten polymeric material from the shot tuning chamber into a mold cavity.

Abstract: Photopolymers, monomers, compositions including photopolymers and a dopant, and methods, including methods for eliciting a photomechanical response. The dopant may be a triplet sensitizing dopant. The exposing of compositions to the one or more wavelengths of electromagnetic radiation may elicit a photomechanical response via a triplet excited state mechanism.

Abstract: Provided herein are photochemical separations. The methods herein can include exposing a first metal complex and a second metal complex to light to facilitate an irreversible chemical reaction to form a modified first metal complex. The modified first metal complex then may be separated from the second metal complex. Compositions also are provided.

Abstract: A controller for an injection molding system is in communication with a melt flow control unit, a gas assist control unit, and a gas counter pressure control unit. The controller can effect real-time adjustments to gas assist pressure and/or gas counter pressure as a function of melt pressure or flow front position.

Abstract: Provided herein are photochemical separations. The methods herein can include exposing a first metal complex and a second metal complex to light to facilitate an irreversible chemical reaction to form a modified first metal complex. The modified first metal complex then may be separated from the second metal complex. Compositions also are provided.

Abstract: A molding system and a method for operation of the molding system are provided. The method includes flowing a molten polymeric material from an upstream device into an in-mold tuning chamber in a filling position where the in-mold tuning chamber is positioned at least partially within a mold cavity. The method also includes adjusting at least one of a temperature of and a pressure applied to the molten polymeric material in the in-mold tuning chamber to create a first tuned molten polymeric material and releasing the tuned molten polymeric material into the mold cavity from the in-mold tuning chamber.

Abstract: A molding system and a method for operation of the molding system are provided. The method includes flowing a molten polymeric material from an upstream device into an in-mold tuning chamber in a filling position where the in-mold tuning chamber is positioned at least partially within a mold cavity. The method also includes adjusting at least one of a temperature of and a pressure applied to the molten polymeric material in the in-mold tuning chamber to create a first tuned molten polymeric material and releasing the tuned molten polymeric material into the mold cavity from the in-mold tuning chamber.

Abstract: A molding system and a method for operation of the molding system are provided. The method includes flowing a molten polymeric material into a shot tuning chamber from an upstream device, adjusting a temperature of and/or pressure applied to the molten polymeric material in the shot tuning chamber, and flowing the molten polymeric material from the shot tuning chamber into a mold cavity.

Abstract: A molding system and a method for operation of the molding system are provided. The method includes flowing a molten polymeric material into a shot tuning chamber from an upstream device, adjusting a temperature of and/or pressure applied to the molten polymeric material in the shot tuning chamber, and flowing the molten polymeric material from the shot tuning chamber into a mold cavity.

Abstract: An additive injection system for use in injection molding machines to inject additive materials, such as fluids or powders, downstream of a nozzle of the injection molding machine. The additive injection unit has an additive tank to store or contain additive material and additive injectors that inject an additive material into an injection molding machine. A pump pumps the additive material from the tank through a common manifold connected to the additive injectors to be injected into the injection molding machine. A controller controls operation of the additive injection device and one or more sensors coupled to the additive injection device can provide feedback to the controller.

Abstract: Non-time dependent measured variables are used to effectively determine an optimal ejection time of a part from a mold cavity. A system and/or approach may first measure at least one non-time dependent variable during an injection molding cycle. The part is ready to be ejected from the mold upon the measured variable reaching a threshold value indicative of, for example, a part temperature dropping below an activation temperature.

Abstract: Non-time dependent measured variables are used to effectively determine an optimal ejection time of a part from a mold cavity. A system and/or approach may first measure at least one non-time dependent variable during an injection molding cycle. The part is ready to be ejected from the mold upon the measured variable reaching a threshold value indicative of, for example, a part temperature dropping below an activation temperature.

Abstract: A method and system for adjusting melt pressure in an injection molding material that allows calculating a melt pressure of a molten plastic material to be injected and based on the calculated melt pressure and a desired melt pressure adjusting operation of an injection molding machine. This control of an injection molding cycle using the method and system of plastic melt pressure determination allows production of parts of increased quality and consistency.

Abstract: Transmission of low energy light is one of the primary loss mechanisms of a single junction solar cell. Molecular photon upconversion via triplet-triplet annihilation (TTA-UC)—combining two or more low energy photons to generate a higher energy excited state—is an intriguing strategy to surpass this limit. The present disclosure is directed to self-assembled multilayers, e.g., bi- or trilayers, on metal oxide surfaces as a strategy to facilitate TTA-UC emission and demonstrate direct charge separation of the upconverted state. A three-fold enhancement in transient photocurrent is achieved at light intensities as low as two equivalent suns.

Abstract: Forward and back electron transfer at molecule oxide interfaces are pivotal events in dye-sensitized solar cells, dye-sensitized photoelectrosynthesis cells and other applications. Disclosed herein are self-assembled multilayers as a strategy for manipulating electron transfer dynamics at these interfaces. The multilayer films are achieved by stepwise layering of bridging molecules, linking ions, and active molecule on an oxide surface. The formation of the proposed architecture is supported by ATR-IR and UV-Vis spectroscopy. Time-resolved emission and transient absorption establishes that the films exhibit an exponential decrease in electron transfer rate with increasing bridge length. The findings indicate that self-assembled multilayers offer a simple, straight forward and modular method for manipulating electron transfer dynamics at dye-oxide interfaces.

Abstract: An additive injection system for use in injection molding machines to inject additive materials, such as fluids or powders, downstream of a nozzle of the injection molding machine. The additive injection unit has an additive tank to store or contain additive material and additive injectors that inject an additive material into an injection molding machine. A pump pumps the additive material from the tank through a common manifold connected to the additive injectors to be injected into the injection molding machine. A controller controls operation of the additive injection device and one or more sensors coupled to the additive injection device can provide feedback to the controller.

Abstract: Disclosed herein are metal-organic frameworks and methods of making and use thereof.