Abstract: A pH sensor including a reference electrode, a measuring electrode operatively connected to said reference electrode, a fluid conduit for containing an electrolyte in electrolytic contact with said reference electrode, a reservoir in fluid communication with said fluid conduit, a reference junction encasing said reference electrode, and an external junction, wherein said electrolyte comprises a viscous silica suspension to maintain a flow of said electrolyte from said reservoir to reduce inward diffusion through said external junction.

Abstract: The invention provides a sensor with a reference electrode and a flowing electrolyte which is particularly useful for measuring the ion concentration of a process solution. The invention includes a sensor having a pressurized reservoir which provides flow of an electrolyte, a non-metallic solution ground and a resistance temperature device bonded to a non-metallic solution ground. The invention provides sensors with greater accuracy and stability by minimizing or eliminating ingress of contaminants from a process solution through the external junction of the sensor.

Abstract: The invention provides a sensor with a reference electrode and a flowing electrolyte which is particularly useful for measuring the ion concentration of a process solution. The invention includes a sensor having a pressurized reservoir which provides flow of an electrolyte, a non-metallic solution ground and a resistance temperature device bonded to a non-metallic solution ground. The invention provides sensors with greater accuracy and stability by minimizing or eliminating ingress of contaminants from a process solution through the external junction of the sensor.

Abstract: The invention provides a sensor with a reference electrode and a flowing electrolyte which is particularly useful for measuring the ion concentration of a process solution. The invention includes a sensor having a pressurized reservoir which provides flow of an electrolyte, a non-metallic solution ground and a resistance temperature device bonded to a non-metallic solution ground. The invention provides sensors with greater accuracy and stability by minimizing or eliminating ingress of contaminants from a process solution through the external junction of the sensor.

Abstract: A level of a chemical in a fluid is accurately measured by an analyzer having an electrode assembly separated from the fluid by a membrane. The electrode assembly is energized to provide a steady state signal and a pulsed signal, both of which indicate the level of chemical in the fluid, but with only the pulsed signal being substantially unaffected by fouling of the membrane. The pulsed signal and the steady state signal are used to determine a predicted value that the steady state signal will have in the absence of fouling. The predicted value is then used to correct the steady state current to compensate for fouling of the membrane.

Abstract: An analyzer for detecting a selected chemical (such as oxygen) in a process fluid includes a plurality of electrodes that are separated from the fluid by a membrane that is permeable to the selected chemical, each of the electrodes when energized producing a signal in response to the selected chemical in the fluid. The selected chemical level in the process fluid is determined based on the signal produced by a first one of the electrodes, and the determined level is used with the signal produced by a second one of the electrodes to detect whether the membrane has become faulty (e.g., fouled by materials in the process fluid).

Abstract: A method is provided for accurately determining the complexing capacity (or free HF concentration) of a pickling liquor. A sample of pickling liquor is obtained and an excess of ferric ion is added thereto to complex with all of the free HF in the sample. A back titration is performed to determine the residual free ferric ion. The difference between the amount of ferric ion added and that found by the titration is related to the free HF in the original sample.The method is useful in conjunction with an automated, on-line system which periodically monitors a pickling bath and makes any necessary adjustments thereto.

Abstract: Apparatus for railway cars to handle the ingress and egress of passengers through a door opening where the apparatus selectively provides at the exterior of the car at the door opening an adjustable height platform, steps or a ground-to-car floor platform lift. The apparatus is storable within the railway car and extendable exteriorly of the railway car where it can then be selectively conditioned for a desired passenger handling mode as a platform positioned at a desired height between the car floor and ground, a series of steps extending between the car floor and ground, or a platform lift movable between ground level and car floor level.

Abstract: A gas chromatograph for measuring the amounts of selected sample gas components such as oxygen and carbon monoxide. The system comprises a high-temperature (600.degree. C.) zirconia cell detector supplied on one side with a continuous stream of oxygen flowing at a constant rate. A voltage source connected to the zirconia cell transports all of this oxygen to the other side of the cell, resulting in a constant background cell current. Sample components from the chromatographic column are injected sequentially into the oxygen stream. When oxygen is injected the cell current increases due to the increase in total oxygen available for transport through the cell. When carbon monoxide is injected, it is fully combusted with the oxygen, and the current correspondingly decreases due to reduction of the oxygen available for transport. The deviation in cell current with reference to the background current is integrated for each component to produce output signals indicating the amount of the component.

Abstract: An ion-sensitive electrode, usable for measuring the activity or concentration of a predetermined ion in a fluid stream of an industrial process, includes a vessel partially filled with an electrolyte and fabricated with one wall portion thereof comprising a rigid, porous fritted back-up element and a relatively thin, ion-sensitive, non-porous membrane. Being preferably made of the same ion-sensitive material as the membrane, the back-up element is produced using a sintering process which results in a porous solid having maze-like passages extending randomly therethrough in all directions. One surface of the back-up element is fused to and supports a thin layer of ion-sensitive material that has been applied to the back-up element, heated to its molten working temperature and then cooled to form the non-porous membrane. Located within the vessel, the back-up element also serves to transport the electrolyte through its passages for wetting the interior surface of the thin membrane fused to the back-up element.

Abstract: An amperometric analysis system and method includes a flow tube constituting the amperometric cell in which magnetic flow metering electrodes function also as the counter and test electrodes for amperometric measurement. By combining the magnetic flow measurement with the amperometric measurement, additional electrodes are not needed to obtain the flow signal for compensating the amperometric measurement. Ultrasonic drivers are mounted on the end of the shank of the counter and test electrodes and driven by an ultrasonic oscillator to activate the electrodes to keep them clean. Complementary cleaning can be obtained through the simultaneous application of an electrochemical anodic pulse. The system includes a three-electrode circuit potentiostat in which the potential of the test electrode is fixed versus a reference electrode and the current flows between the test electrode and the counter electrode.

Abstract: An automatic titration system and method in which the titrant is generated electrolytically and a two-position slider type ceramic sample valve, reliably, accurately and repetitively obtains a volumetric sample from a process loop and introduces it to a titration cell containing a generator or working compartment and an auxiliary compartment separated by a porous frit. The system also includes a two-position slider type ceramic reagent valve for introducing reagent into the titration cell. Titrant created at a generator electrode surface is dispersed into the bulk of the solution by a magnetically coupled impeller in the working compartment which mixes and also pumps the contents of the cell through the reagent and sample valves in a closed loop. Generator and auxiliary electrodes are connected to a current source which provides the electrolysis current.