Abstract: Optical products are disclosed that include a polymer substrate; a composite coating, deposited on the polymer substrate; a permeating adhesive, which permeates the composite coating and is in contact with the polymer substrate; and a protective layer, secured to the composite coating by the permeating adhesive. The composite coating includes at least a first layer and a second layer, each of which is provided with a binding group component which together form a complementary binding group pair. The optical products exhibit improved resistance to delamination during storage and use.

Abstract: Optical products and methods of making them are disclosed, the optical products comprising a polymeric substrate and a composite coating. The composite coating, in turn, comprises: a first layer comprising a polyionic binder, and a second layer comprising insoluble particles that absorb electromagnetic energy and insoluble particles that absorb relatively little visible light. Each of the first layer and the second layer includes a binding group component which together form a complimentary binding group pair.

Abstract: Optical products that include a composite coating, deposited on a substrate, provided with at least one bilayer having a first layer and a second layer, each provided with a binding group component which together form a complementary binding group pair. The at least one bilayer comprises a pigment blend that includes: a) at least two pigments that, when mixed together and formed into a bilayer, exhibit a color reflection value that is less than about 2.5; and b) one or more pigments that when mixed and formed into a bilayer selectively block visible light in a wavelength range of interest.

Abstract: Optical products that comprise a composite coating having multiple bilayers of a first layer and a second layer, each provided with a binding group component which together form a complementary binding group pair, the multiple bilayers comprising: at least one bilayer a) comprised of a first pigment or pigment blend that exhibits a color reflection value that is less than about 2.5; at least one bilayer b) comprised of a pigment or pigment blend that selectively blocks visible light in a wavelength range of interest; and at least one bilayer c) comprised of a second pigment or pigment blend that exhibits a color reflection value that is less than about 2.5, wherein the optical product selectively blocks visible light in the wavelength range of interest, while exhibiting a color reflection value that is less than about 2.5.

Abstract: Optical products that comprise a composite coating having multiple bilayers of a first layer and a second layer, each provided with a binding group component which together form a complementary binding group pair, the multiple bilayers comprising: at least one bilayer a) comprised of a first pigment or pigment blend that exhibits a color reflection value that is less than about 2.5; at least one bilayer b) comprised of a pigment or pigment blend that selectively blocks visible light in a wavelength range of interest; and at least one bilayer c) comprised of a second pigment or pigment blend that exhibits a color reflection value that is less than about 2.5, wherein the optical product selectively blocks visible light in the wavelength range of interest, while exhibiting a color reflection value that is less than about 2.5.

Abstract: Optical products that include a composite coating, deposited on a substrate, provided with at least one bilayer having a first layer and a second layer, each provided with a binding group component which together form a complementary binding group pair. The at least one bilayer comprises a pigment blend that includes: a) at least two pigments that, when mixed together and formed into a bilayer, exhibit a color reflection value that is less than about 2.5; and b) one or more pigments that when mixed and formed into a bilayer selectively block visible light in a wavelength range of interest.

Abstract: Optical products are disclosed that include a polymeric substrate, provided with an infrared-reflective metal layer on an outer surface thereof that is subject to oxidation. The optical products are further provided with a protective coating, comprising one or more of a metal oxide or a metal nitride, deposited directly on the infrared-reflective metal layer using chemical vapor deposition. The optical products are further provided with a composite pigment coating, deposited on the protective coating, that include at least a first layer and a second layer, at least one of which layers comprises a first pigment, wherein each of the first layer and the second layer includes a binding group component, each of which binding group components together form a complementary binding group pair.

Abstract: Optical products are disclosed that include a polymer substrate; a composite coating, deposited on the polymer substrate; a permeating adhesive, which permeates the composite coating and is in contact with the polymer substrate; and a protective layer, secured to the composite coating by the permeating adhesive. The composite coating includes at least a first layer and a second layer, each of which is provided with a binding group component which together form a complementary binding group pair. The optical products exhibit improved resistance to delamination during storage and use.

Abstract: Optical products are disclosed that include a polymeric substrate, provided with an infrared-reflective metal layer on an outer surface thereof that is subject to oxidation. The optical products are further provided with a protective coating, comprising one or more of a metal oxide or a metal nitride, deposited directly on the infrared-reflective metal layer using chemical vapor deposition. The optical products are further provided with a composite pigment coating, deposited on the protective coating, that include at least a first layer and a second layer, at least one of which layers comprises a first pigment, wherein each of the first layer and the second layer includes a binding group component, each of which binding group components together form a complementary binding group pair.

Abstract: An electromagnetic energy-absorbing optical product useful particularly for automotive and architectural window films is disclosed. The electromagnetic energy-absorbing optical product includes a polymeric substrate and a composite coating with the composite coating including first and second layers each containing a binding group component which together form a complimentary binding group pair.

Abstract: An electromagnetic energy-absorbing optical product useful as a composite for coloring an opaque article such as a paint composite or car wrap is disclosed. The electromagnetic energy-absorbing optical product includes a polymeric substrate and a composite coating with the composite coating including first and second layers each containing a binding group component which together form a complimentary binding group pair.

Abstract: An electromagnetic energy-absorbing optical product useful particularly for automotive and architectural window films is disclosed. The electromagnetic energy-absorbing optical product includes a polymeric substrate and a composite coating with the composite coating including first and second layers each containing a binding group component which together form a complimentary binding group pair.

Abstract: An electromagnetic energy-absorbing optical product useful as a composite for coloring an opaque article such as a paint composite or car wrap is disclosed. The electromagnetic energy-absorbing optical product includes a polymeric substrate and a composite coating with the composite coating including first and second layers each containing a binding group component which together form a complimentary binding group pair.

Abstract: An electromagnetic energy-absorbing optical product useful particularly for automotive and architectural window films is disclosed. The electromagnetic energy-absorbing optical product includes a polymeric substrate and a composite coating with the composite coating including first and second layers each containing a binding group component which together form a complimentary binding group pair.

Abstract: An electromagnetic energy-absorbing optical product useful particularly for automotive and architectural window films is disclosed. The electromagnetic energy-absorbing optical product includes a polymeric substrate and a composite coating with the composite coating including first and second layers each containing a binding group component which together form a complimentary binding group pair.

Abstract: An electromagnetic energy-absorbing optical product useful particularly for automotive and architectural window films is disclosed. The electromagnetic energy-absorbing optical product includes a polymeric substrate and a composite coating with the composite coating including first and second layers each containing a binding group component which together form a complimentary binding group pair.

Abstract: An electromagnetic energy-absorbing optical product useful particularly for automotive and architectural window films is disclosed. The electromagnetic energy-absorbing optical product includes a polymeric substrate and a composite coating with the composite coating including first and second layers each containing a binding group component which together form a complimentary binding group pair.

Abstract: One aspect of the invention relates to a method of preparing metal oxide coated substrates for various potential applications, and the coated substrate formed thereby.

Abstract: The present invention comprises an automated apparatus capable of spray depositing polyelectrolytes via the LbL mechanism with minimal or no human interaction. In certain embodiments, the apparatus sprays atomized polyelectrolytes onto a vertically oriented substrate. To counteract the effects of irregular spray patterns, the substrate is preferably slowly rotated about a central axis. In certain embodiments, the apparatus also includes a forced pathway for the droplets, such as a pathway created by using a vacuum. In this way, a thicker or three-dimensional substrate can be coated. In certain embodiments, the apparatus is designed so as to be scalable. Thus, through the use of multiple instantiations of the apparatus, a large or irregularly shaped substrate can be coated. Rolls of textile can therefore be coated using the apparatus. Additionally, the present invention includes a method to uniformly coat a substrate, such as a hydrophobic textile material, using aqueous solutions of polyelectrolytes.

Abstract: The present invention comprises an automated apparatus capable of spray depositing polyelectrolytes via the LbL mechanism with minimal or no human interaction. In certain embodiments, the apparatus sprays atomized polyelectrolytes onto a vertically oriented substrate. To counteract the effects of irregular spray patterns, the substrate is preferably slowly rotated about a central axis. In certain embodiments, the apparatus also includes a forced pathway for the droplets, such as a pathway created by using a vacuum. In this way, a thicker or three-dimensional substrate can be coated. In certain embodiments, the apparatus is designed so as to be scalable. Thus, through the use of multiple instantiations of the apparatus, a large or irregularly shaped substrate can be coated. Rolls of textile can therefore be coated using the apparatus. Additionally, the present invention includes a method to uniformly coat a substrate, such as a hydrophobic textile material, using aqueous solutions of polyelectrolytes.