Abstract: A method of operating a low pressure drop fuel cell stack comprising a plurality of low pressure drop fuel cells wherein during low pressure and low power operation, a heat transfer rate of a cathode flow field plate of each fuel cell is greater than a heat transfer rate of an anode flow field plate of the same fuel cell. Thus, a temperature gradient is created between an anode electrode and a cathode electrode of each fuel cell, as well as reactant fluids in at least one anode flow field and at least one cathode flow field of the same fuel cell.

Abstract: Low temperature fuel cells, e.g. solid polymer fuel cells, can operate directly on a fuel comprising dimethyl ether with dimethyl ether being oxidized at the fuel cell anode. Being highly soluble in water, dimethyl ether can be supplied as a liquid aqueous fuel solution. As a fuel, dimethyl ether provides similar power characteristics as methanol but typically with a greater Faradaic efficiency in liquid feed solid polymer fuel cells.

Abstract: Disclosed are reactant feed apparatus for liquid-fueled direct feed fuel cells, including miniaturized versions thereof. More specifically, disclosed is a fuel flow device for delivering liquid fuel to such direct feed fuel cells. The fuel flow device comprises a fuel flow-routing device and an enclosure/partition assembly containing the liquid fuel to be delivered. When the fuel flow device is fluidly connected to the fuel cell, it operates to deliver the liquid fuel to an anode flow field thereof by using the pressurized anodic exhaust gases exiting therefrom as the source of power for pumping the liquid fuel from the enclosure into the fuel cell.

Abstract: In an operating liquid feed fuel cell system, fuel concentration in the fuel stream can be calculated as a function of the observed current, the temperature of the fuel stream entering the fuel cell stack, and the temperature of the fuel cell stack itself, thereby eliminating the need for a separate sensor. Typically, methanol will be used as the fuel and the liquid feed fuel cell system will thus be a direct methanol fuel cell system.

Abstract: In an electrochemical fuel cell, a sufficient quantity of catalyst, effective for promoting the reaction of reactant supplied to an electrode, is disposed within the volume of the electrode so that a reactant introduced at a first major surface of the electrode is substantially completely reacted upon contacting the second major surface. Crossover of reactant from one electrode to the other electrode through the electrolyte in an electrochemical fuel cell is thereby reduced.

Abstract: In an electrochemical fuel cell, a sufficient quantity of catalyst, effective for promoting the reaction of reactant supplied to an electrode, is disposed within the volume of the electrode so that a reactant introduced at a first major surface of the electrode is substantially completely reacted upon contacting the second major surface. Crossover of reactant from one electrode to the other electrode through the electrolyte in an electrochemical fuel cell is thereby reduced.

Abstract: In an operating liquid feed fuel cell system, fuel concentration in the fuel stream can be calculated as a function of the observed current, the temperature of the fuel stream entering the fuel cell stack and the temperature of the fuel cell stack itself, thereby eliminating the need for a separate sensor. Typically, methanol will be used as the fuel and the liquid feed fuel cell system will thus be a direct methanol fuel cell system.

Abstract: The measuring range of a fuel cell based concentration sensor can be extended by decreasing the load across the fuel cell terminals and by increasing the amount of oxidant supplied to the fuel cell. In this way, such a sensor avoids saturation, for example, when measuring methanol concentrations from 0 M to over 4 M in liquid aqueous solution. Such a sensor is suitable for use in measuring fuel concentrations in the recirculating fuel stream of certain fuel cell stacks (for example, direct methanol fuel cell stacks).

Abstract: A flow field plate for a liquid feed fuel cell has a liquid reactant (for example, fuel) flow field comprising a plurality of horizontal parallel substantially straight channels formed on one major surface of the plate. The plate has another reactant (for example, oxidant) flow field on the other major surface of the plate. The liquid reactant channels may have an open width less than about 0.75 millimeter and/or a length to cross sectional area ratio between about 2180:1 to about 6200:1. A simple four-port configuration is employed for the inlets and outlets for the reactants. The liquid reactant can also serve as a coolant for the fuel cell.

Abstract: Application of two-dimensional materials (TDMs) that are exfoliated transition metal dichalcogenides in electrochemical fuel cells to remove contaminants that are harmful to the fuel cells; to effect proper transport and containment of various fluids in fuel cells to achieve proper and efficient operation; to protect various surfaces and materials commonly comprised in or used for fuel cells and critical to their operation; and to purify and lower the freezing point of cooling water used for the fuel cell stacks. Disclosed are methods whereby the TDM is used as a barrier to prevent unwanted crossover (between electrodes through a polymer electrolyte membrane or PEM) of chemical species; where the TDM is used to coat and/or encapsulate catalyst particles, carbon catalyst support, PEMs, and chemical or metal hydrides, to protect the same from unwanted exposure to chemical species; and where the TDM is used to purify and lower the freezing point of fuel cell stack cooling water.

Abstract: A method of commencing operation of a fuel cell system which includes a fuel reformer is provided. During a start-up period, the same fuel which is used in the feedstock to the reformer is directed to at least a portion of the fuel cells in the system. These fuel cells provide output power by direct oxidation of the fuel, at least until the reformer is operational, producing a hydrogen-containing gas stream suitable for the fuel cells. Thus, useful output power can be obtained from the system without the delay typically associated with start-up of the reformer.

Abstract: Liquid feed fuel cell performance can be increased by impregnating electrode substrates with a proton conducting ionomer prior to incorporation of the electrocatalyst, and optionally also after application of the electrocatalyst. Ionomer impregnation is particularly effective for direct methanol fuel cell anodes that comprise carbonaceous substrates.

Abstract: Fuel cell performance in liquid feed fuel cells with an electrode comprising a carbonaceous substrate and an electrocatalyst can be increased by oxidizing the carbon substrate, particularly by electrochemical methods in acidic aqueous solution, prior to incorporation of the electrocatalyst. The treated substrate may thereafter be advantageously impregnated with a proton conducting ionomer to prevent excessive penetration of the applied catalyst into the substrate. The treatment method is particularly effective for direct methanol fuel cell anodes.

Abstract: In an electrochemical fuel cell, a sufficient quantity of catalyst, effective for promoting the reaction of reactant supplied to an electrode, is disposed within the volume of the electrode so that a reactant introduced at a first major surface of the electrode is substantially completely reacted upon contacting the second major surface. Crossover of reactant from one electrode to the other electrode through the electrolyte in an electrochemical fuel cell is thereby reduced.

Abstract: In an electrochemical fuel cell, a sufficient quantity of catalyst, effective for promoting the reaction of reactant supplied to an electrode, is disposed within the volume of the electrode so that a reactant introduced at a first major surface of the electrode is substantially completely reacted upon contacting the second major surface. Crossover of reactant from one electrode to the other electrode through the electrolyte in an electrochemical fuel cell is thereby reduced.

Abstract: A fuel cell electric power generation system using air as both a coolant and an oxidant comprises an electric power generation subsystem, an air filter subsystem, a power and control electronics unit (PEU) subsystem comprising a DC/DC converter, and an air fan subsystem. The subsystems are arranged such that air circulation through the system is improved and the risk of moisture damage to sensitive PEU components is reduced. In one embodiment, the air filter subsystem is positioned ahead of the PEU subsystem, which is positioned ahead of the power generation subsystem, which is positioned ahead of the air fan subsystem in the direction of air flow, such that air is drawn by the air fan subsystem through the air filter subsystem, over the PEU subsystem, and through the electric power generation subsystem providing filtered air to cool the PEU prior to entering the fuel cell stack to provide oxygen for the electrochemical reaction.