Patents by Inventor Kevin R. Squire

Kevin R. Squire has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 9580533
    Abstract: The present invention relates to a branched modifier and a composition comprising more than 25 wt % (based on the weight of the composition) of one or more linear ethylene polymers having a g?vis of 0.97 or more and an Mw of 20,000 g/mol or more and at least 0.1 wt % of a branched modifier where the modifier has a g?vis of less than 0.97, wherein the ethylene polymer has a g?vis of at least 0.01 units higher than the g?vis of the branched modifier.
    Type: Grant
    Filed: September 20, 2012
    Date of Patent: February 28, 2017
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Peijun Jiang, Kevin R. Squire, Jianya Cheng, Pradeep P. Shirodkar, Johannes M. Soulages, Keith E. Jolibois, Ronald R. Thackston, Andrew G. Narvaez, Jr.
  • Patent number: 9068034
    Abstract: This invention relates to in-reactor polymer blends comprising at least 60 mole % of propylene and from 0.01 to 10 mole % of at least one diene selected from the group of C6 to C12 ?,?-diene, norbornadiene, vinyl norbornene and mixtures thereof with the balance being ethylene. The blend comprises first and second polymers having different crystallinities and or different Tg's.
    Type: Grant
    Filed: September 11, 2012
    Date of Patent: June 30, 2015
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Kevin R. Squire, Charles J. Ruff, Cesar A. Garcia-Franco, Peijun Jiang
  • Patent number: 8481647
    Abstract: This invention relates to an in-reactor polymer blend comprising: (a) a first ethylene-containing polymer having a density of greater than 0.90 g/cm3 and a Mw of more than 20,000 g/mol and (b) a second ethylene-containing polymer having a density of less than 0.90 g/cm3 wherein the polymer blend has a Tm of at least 90° C. (DSC second melt), a density of less than 0.92 g/cm3, and the densities of the first and second polymers differ by at least 1%.
    Type: Grant
    Filed: December 19, 2011
    Date of Patent: July 9, 2013
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Peijun Jiang, Armenag H. Dekmezian, Kevin R. Squire, Cesar A. Garcia-Franco
  • Patent number: 8426529
    Abstract: Disclosed is a selected type of copolymer composition comprising copolymers having units derived from ethylene and dicyclopentadiene (DCPD) co-monomers. Such copolymer compositions: a) have a DCPD-derived comonomer unit content of from about 25 mole % to about 45 mole %; b) have a Weight Average Molecular Weight, Mw, of greater than about 170,000; c) comprise amorphous material and have glass transition temperatures, Tg, of from about 8° C. to about 129° C., which also fit the equation Tg (in ° C.)?[(mole % DCPD×3.142)?4.67]; and d) comprise no significant amount of crystalline polyethylene homopolymer or crystallizable polyethylene segments within the ethylene-dicyclopentadiene copolymers. Such copolymers can be readily derivatized by hydrogenation and/or epoxidation to provide polymeric materials suitable for use as engineering thermoplastics.
    Type: Grant
    Filed: May 10, 2007
    Date of Patent: April 23, 2013
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Lisa Saunders Baugh, Abhimanyu Onkar Patil, Christian Peter Mehnert, Kevin R. Squire, Kenneth A. Cook, Caiguo Gong, Enock Berluche, Karla Schall Colle, Alan J. Oshinski, Stephen Zushma, Beverly J. Poole
  • Publication number: 20130059981
    Abstract: This invention relates to an in-reactor polymer blend comprising: (a) a first ethylene-containing polymer having a density of greater than 0.90 g/cm3 and a Mw of more than 20,000 g/mol and (b) a second ethylene-containing polymer having a density of less than 0.90 g/cm3 wherein the polymer blend has a Tm of at least 90° C. (DSC second melt), a density of less than 0.92 g/cm3, and the densities of the first and second polymers differ by at least 1%.
    Type: Application
    Filed: December 19, 2011
    Publication date: March 7, 2013
    Inventors: Peijun JIANG, Armenag H. Dekmezian, Kevin R. Squire, Cesar A. Garcia-Franco
  • Publication number: 20130005908
    Abstract: This invention relates to in-reactor polymer blends comprising at least 60 mole % of propylene and from 0.01 to 10 mole % of at least one diene selected from the group of C6 to C12 ?,?-diene, norbornadiene, vinyl norbornene and mixtures thereof with the balance being ethylene. The blend comprises first and second polymers having different crystallinities and or different Tg's.
    Type: Application
    Filed: September 11, 2012
    Publication date: January 3, 2013
    Inventors: Kevin R. Squire, Charles J. Ruff, Cesar A. Garcia-Franco, Peijun Jiang
  • Patent number: 8344070
    Abstract: A polymer composition comprises (a) least 40 wt % (based upon the weight of the composition) of a cyclic olefin polymer comprising at least one acyclic olefin and at least 20 wt % of one or more cyclic olefins (based upon the weight of the cyclic olefin polymer), wherein at least a portion of the cyclic olefin polymer has a glass transition temperature of greater than 100° C.; (b) an acyclic olefin polymer modifier in an amount up to 40 wt % (based upon the weight of the composition); and (c) at least 10 wt % (based upon the weight of the composition) of one of more fillers. The polymer composition has a notched Izod impact resistance measured at 23° C. of greater than 100 J/m and a flexural modulus (1% secant method) of greater than 1400 MPa.
    Type: Grant
    Filed: June 20, 2007
    Date of Patent: January 1, 2013
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Kevin R. Squire, Alan J. Oshinski, Kevin D. Robinson, Christian Peter Mehnert, Marsha M. Arvedson, Beverly J. Poole, Abhimanyu Onkar Patil, Lisa Saunders Baugh, Karla Schall Colle
  • Patent number: 8288480
    Abstract: This invention relates to in-reactor polymer blends comprising at least 60 mole % of propylene and from 0.01 to 10 mole % of at least one diene selected from the group of C6 to C12 ?,?-diene, norbornadiene, vinyl norbornene and mixtures thereof with the balance being ethylene. The blend comprises first and second polymers having different crystallinities and or different Tg's.
    Type: Grant
    Filed: December 15, 2009
    Date of Patent: October 16, 2012
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Peijun Jiang, Kevin R. Squire, Charles J. Ruff, Cesar A. Garcia-Franco
  • Publication number: 20120149846
    Abstract: This invention relates to an in-reactor polymer blend comprising: (a) a first ethylene-containing polymer having a density of greater than 0.90 g/cm3 and a Mw of more than 20,000 g/mol and (b) a second ethylene-containing polymer having a density of less than 0.90 g/cm3 wherein the polymer blend has a Tm of at least 90° C. (DSC second melt), a density of less than 0.92 g/cm3, and the densities of the first and second polymers differ by at least 1%.
    Type: Application
    Filed: December 19, 2011
    Publication date: June 14, 2012
    Inventors: Peijun JIANG, Armenag H. Dekmezian, Kevin R. Squire, Cesar A. Garcia-Franco
  • Patent number: 8106127
    Abstract: An in-reactor polymer blend comprises (a) a propylene-containing first polymer; and (b) an ethylene-containing second polymer such that the polymer blend comprises between about 50 wt % and about 80 wt % units derived from ethylene and between about 50 wt % and about 20 wt % units derived from propylene. The blend is substantially free of dienes and the content of ethylene in the second polymer in the form of ethylene-ethylene-ethylene triads is at least 40%. The second polymer contains at least 0.1 branch having 8 or more carbon atoms per 10,000 carbons. In addition, the blend has a strain hardening index of at least 1.8, a shear thinning slope in the plot of log(dynamic viscosity) versus log(frequency) of less than ?0.2 and exhibits at least two peaks when subjected to Differential Scanning Calorimetry (first melt) corresponding to a first melting point of at least 150° C. and a second melting point of at least 40° C.
    Type: Grant
    Filed: December 15, 2009
    Date of Patent: January 31, 2012
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Carlos U. De Gracia, Kevin R. Squire, Peijun Jiang, Armenag H. Dekmezian, Beverly J. Poole, Cesar A. Garcia-Franco
  • Patent number: 8101685
    Abstract: This invention relates to an in-reactor polymer blend comprising: (a) a first ethylene-containing polymer having a density of greater than 0.90 g/cm3 and a Mw of more than 20,000 g/mol and (b) a second ethylene-containing polymer having a density of less than 0.90 g/cm3, wherein the polymer blend has a Tm of at least 90° C. (DSC second melt), a density of less than 0.92 g/cm3, and the densities of the first and second polymers differ by at least 1%. Specifically this invention relates to an in-reactor polymer blend comprising: (a) a first ethylene polymer comprising 90 to 100 wt % ethylene and from 0 to less than 10 wt % comonomer, said first ethylene polymer component having density of greater than 0.920 g/cm3, an Mw of 20,000 g/mol or more; and (b) a second ethylene polymer comprising from 70 to 90 wt % ethylene and 30 to 10 wt % comonomer, said second ethylene polymer having a density of 0.910 g/cm3 or less, wherein the polymer blend has: (a) a Tm of at least 100° C. over a density ranging from 0.
    Type: Grant
    Filed: December 15, 2009
    Date of Patent: January 24, 2012
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Peijun Jiang, Armenag H. Dekmezian, Kevin R. Squire, Cesar A. Garcia-Franco
  • Patent number: 8022142
    Abstract: An in-reactor polymer blend including (a) a propylene-containing first polymer; and (b) propylene-containing second polymer having a different crystallinity from the first polymer. The polymer blend has a melting temperature, Tm, of at least 135° C., a melt flow rate of at least 70 dg/min, a tensile strength of at least 8 MPa, an elongation at break of at least 300%.
    Type: Grant
    Filed: December 15, 2008
    Date of Patent: September 20, 2011
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Peijun Jiang, Armenag H. Dekmezian, Kevin R. Squire, Carlos U. de Gracia, Keith Edward Jolibois, Cesar A. Garcia-Franco, Ronald Raymond Thackston
  • Publication number: 20100152383
    Abstract: This invention relates to an in-reactor polymer blend comprising: (a) a first ethylene-containing polymer having a density of greater than 0.90 g/cm3 and a Mw of more than 20,000 g/mol and (b) a second ethylene-containing polymer having a density of less than 0.90 g/cm3, wherein the polymer blend has a Tm of at least 90° C. (DSC second melt), a density of less than 0.92 g/cm3, and the densities of the first and second polymers differ by at least 1%. Specifically this invention relates to an in-reactor polymer blend comprising: (a) a first ethylene polymer comprising 90 to 100 wt % ethylene and from 0 to less than 10 wt % comonomer, said first ethylene polymer component having density of greater than 0.920 g/cm3, an Mw of 20,000 g/mol or more; and (b) a second ethylene polymer comprising from 70 to 90 wt % ethylene and 30 to 10 wt % comonomer, said second ethylene polymer having a density of 0.910 g/cm3 or less, wherein the polymer blend has: (a) a Tm of at least 100° C. over a density ranging from 0.
    Type: Application
    Filed: December 15, 2009
    Publication date: June 17, 2010
    Inventors: Peijun Jiang, Armenag H. Dekmezian, Kevin R. Squire, Cesar A. Garcia-Franco
  • Publication number: 20100152390
    Abstract: An in-reactor polymer blend comprises (a) a propylene-containing first polymer; and (b) an ethylene-containing second polymer such that the polymer blend comprises between about 50 wt % and about 80 wt % units derived from ethylene and between about 50 wt % and about 20 wt % units derived from propylene. The blend is substantially free of dienes and the content of ethylene in the second polymer in the form of ethylene-ethylene-ethylene triads is at least 40%. The second polymer contains at least 0.1 branch having 8 or more carbon atoms per 10,000 carbons. In addition, the blend has a strain hardening index of at least 1.8, a shear thinning slope in the plot of log(dynamic viscosity) versus log(frequency) of less than ?0.2 and exhibits at least two peaks when subjected to Differential Scanning Calorimetry (first melt) corresponding to a first melting point of at least 150° C. and a second melting point of at least 40° C.
    Type: Application
    Filed: December 15, 2009
    Publication date: June 17, 2010
    Inventors: Carlos U. De Gracia, Kevin R. Squire, Peijun Jiang, Armenag H. Dekmezian, Beverly J. Poole, Cesar A. Garcia-Franco
  • Publication number: 20100152382
    Abstract: An in-or polymer blend including (a) a propylene-containing first polymer; and (b) propylene-containing second polymer having a different crystallinity from the first polymer. The polymer blend has a melting temperature, Tm, of at least 135° C., a melt flow rate of at least 70 dg/min, a tensile strength of at least 8 MPa, an elongation at break of at least 300%.
    Type: Application
    Filed: December 15, 2008
    Publication date: June 17, 2010
    Inventors: Peijun Jiang, Armenag H. Dekmezian, Kevin R. Squire, Carlos U. De Gracia, Keith Edward Jolibois, Cesar A. Garcia-Franco, Ronald Raymond Thackston
  • Publication number: 20100152388
    Abstract: This invention relates to in-reactor polymer blends comprising at least 60 mole % of propylene and from 0.01 to 10 mole % of at least one diene selected from the group of C6 to C12 ?,?-diene, norbornadiene, vinyl norbornene and mixtures thereof with the balance being ethylene. The blend comprises first and second polymers having different crystallinities and or different Tg's.
    Type: Application
    Filed: December 15, 2009
    Publication date: June 17, 2010
    Inventors: Peijun Jiang, Kevin R. Squire, Charles J. Ruff, Cesar A. Garcia-Franco
  • Publication number: 20090318597
    Abstract: A polymer composition comprises (a) least 40 wt % (based upon the weight of the composition) of a cyclic olefin polymer comprising at least one acyclic olefin and at least 20 wt % of one or more cyclic olefins (based upon the weight of the cyclic olefin polymer), wherein at least a portion of the cyclic olefin polymer has a glass transition temperature of greater than 100° C.; (b) an acyclic olefin polymer modifier in an amount up to 40 wt % (based upon the weight of the composition); and (c) at least 10 wt % (based upon the weight of the composition) of one of more fillers. The polymer composition has a notched Izod impact resistance measured at 23° C. of greater than 100 J/m and a flexural modulus (1% secant method) of greater than 1400 MPa.
    Type: Application
    Filed: June 20, 2007
    Publication date: December 24, 2009
    Inventors: Kevin R. Squire, Alan J. Oshinski, Kevin D. Robinson, Christian Peter Mehnert, Marsha M. Arvedson, Beverly J. Poole, Abhimanyu Onkar Patil, Lisa Saunders Baugh, Karla Schall Colle
  • Publication number: 20080221275
    Abstract: Provided are selected types of terpolymer components comprising terpolymers having monomer units derived from ethylene (E), dicyclopentadiene (DCPD) and norbornene-based (NB) co-monomers. Such terpolymer components have certain specified amounts of each co-monomer as well as certain specified molecular weight and glass transition temperature characteristics. Terpolymer components which are derivatized by hydrogenation and/or by epoxidation and/or hydroxylation are also disclosed, as well as thermoplastic polyolefin compositions which contain the terpolymer components and which have especially desirable structural and thermal properties. Also provided are processes for preparing and derivatizing the terpolymer components herein.
    Type: Application
    Filed: February 29, 2008
    Publication date: September 11, 2008
    Inventors: Lisa S. Baugh, Enock Berluche, Abhimanyu O. Patil, Beverly J. Poole, Kevin D. Robinson, Kevin R. Squire
  • Patent number: 7417093
    Abstract: In a process for functionalizing an ?-olefin/diene copolymer, a copolymer comprising units derived from at least one ?-olefin and units derived from at least one diene, which copolymer contains at least one double bond, is contacted in a reaction medium with an alkyl hydroperoxide in the presence of a catalyst comprising a metal of Group 5 or 6 of the Periodic Table or a compound thereof, under reaction conditions which promote formation of an oxirane ring or hydroxyl groups at the site of the double bond.
    Type: Grant
    Filed: May 21, 2007
    Date of Patent: August 26, 2008
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Karla S. Colle, Caiguo Gong, Kevin R. Squire
  • Publication number: 20080033112
    Abstract: A polymer composition comprises (a) greater than 50 wt % (based upon the weight of the composition) of a cyclic olefin copolymer comprising at least one acyclic olefin and at least 20 weight % of one or more cyclic olefins (based upon the weight of the cyclic olefin copolymer), wherein at least a portion of the cyclic olefin copolymer has a glass transition temperature of greater than 150° C.; and (b) less than 50 wt % (based upon the weight of the composition) of an acyclic olefin polymer modifier, at least a portion of the modifier having a glass transition temperature of less than ?30° C.; and no portion of the modifier having a softening point greater than +30° C., wherein the Bicerano solubility parameter of the modifier being no more than 0.6 J0.5/cm1.5 less than the Bicerano solubility parameter of the cyclic olefin copolymer. The polymer composition has a notched Izod impact resistance measured at 23° C. of greater than 500 J/m and a heat distortion temperature measured using a 0.
    Type: Application
    Filed: June 20, 2007
    Publication date: February 7, 2008
    Inventors: Kevin R. Squire, Alan J. Oshinski, Kevin D. Robinson, Christian Peter Mehnert, Marsha M. Arvedson, Beverly J. Poole, Abhimanyu Onkar Patil, Lisa Saunders Baugh, Karla Schall Colle