Abstract: Freestanding porous polyethylene thin film, and a method for preparing a freestanding porous polyethylene thin film. The method includes dissolving polyethylene in an organic solvent to form a solution under reflux conditions; adding a swellable pocket forming agent to the solution and mixing the solution until the swellable pocket forming agent is well-dispersed therein; applying the well-dispersed solution onto a solid substrate through spin coating to form a thin film on the solid substrate; peeling the thin film off the solid substrate; and extracting the swellable pocket forming agent from the peeled thin film by washing the peeled thin film in water, thereby obtaining a freestanding porous polyethylene thin film with swellable pockets, macro-voids, and micropores. The freestanding porous polyethylene thin film can be used as an oil sorbent. The freestanding porous polyethylene thin film has about 500 to about 800 swellable cavities per cm2.

Abstract: Polypropylene (PP) and polyethylene (PE) blends derived from plastic waste streams and a method to prepare reusable oil sorbents. A method includes separating plastics of group-A from group-B using a float-sink technique, where group-A comprises various PP and PE materials, and group-B comprises polystyrene, polyethylene terephthalate, and polyvinyl chloride; dissolving the group-A plastics in a solvent; adding a cavity forming agent to the solution; applying the solution onto a solid substrate through spin-coating followed by controlled heating; and extracting the cavity forming agent, obtaining a thin film sorbent with swellable cavities for oil sorption. The film contains 400-800 swellable 3D cavities/cm2, each cavity capable of swelling 20-30 times the thickness of the film when contacted with oil.

Abstract: Processes are described for the production of a pitch for use in the manufacture of carbon composite materials. The process comprises the steps of providing a purified coal product (PCP), wherein the PCP is in particulate form, and wherein at least about 90% by volume (% v) of the particles are no greater than about 25 ?m in diameter; wherein the PCP has an ash content of less than about 10% m; and combining the PCP with a feedstock for pitch to create a combined blended mixture suitable for thermal reaction followed by distillation to create a resultant pitch. The combined blended mixture comprises at least around 0.1% m and at most around 90% m PCP. Composite materials that find utility as carbon electrodes, particularly electrolytic baked carbon anodes, can be made from combining the pitch and PCP with a filler material, such as a pet coke.

Abstract: Freestanding microporous thin films, made using plastic waste, can be used as a hydrophobic coating, filtration membranes, or oil-sorbents. A method for producing the microporous thin film involves dissolving the plastic in an organic solvent to obtain a solution; and applying the solution onto a solid substrate through spin-coating followed by controlled heating, resulting in a freestanding porous thin film. Plastic waste comprises recycled polyethylene (PE), polypropylene (PP), polyvinyl chloride (PVC), or polystyrene (PS), recovered from a waste plastic material derived from post-consumer and/or industrial waste. The approach of fabricating multi-functional thin films from plastic waste combines an effective way to address multiple environmental issues simultaneously.

Abstract: A method of preparing an adsorbent can include pyrolyzing palm fiber to provide an palm fiber char, activating the palm fiber char, dissolving at least one polymer in an organic solvent to obtain a solution, dispersing the activated palm fiber char in the solution to provide a mixture, extracting the solvent from the mixture to provide a composite, and annealing the composite to provide the adsorbent. The adsorbent can be porous.

Abstract: A method of preparing an adsorbent can include pyrolyzing olive stone to provide an olive stone char, activating the olive stone char, dissolving a polymer in an organic solvent to obtain a solution, dispersing the activated olive stone char in the solution to provide a mixture, extracting the solvent from the mixture to provide a composite, and annealing the composite to provide the adsorbent. The adsorbent can be porous.

Abstract: A method for making an adsorbent composite can include activating dried lemon peel pieces to obtain activated lemon peel pieces; pyrolyzing the activated lemon peel pieces to obtain activated lemon peel char; dissolving at least one polymer in an organic solvent to obtain a polymer solution; dispersing the activated lemon peel char in the polymer solution to obtain a mixture; extracting the organic solvent from the mixture to obtain a composite; and annealing the composite to provide the adsorbent composite.

Abstract: Sponge-like porous polypropylene thin film, and a method for preparing a sponge-like porous polypropylene thin film. The method includes dissolving polypropylene in an organic solvent to form a solution under reflux condition; adding a cavity forming agent to the solution and mixing the solution until the cavity forming agent is well-dispersed therein; applying the well-dispersed solution onto the solid substrate through spin coating to form a thin film on the solid substrate; peeling the thin film off the solid substrate; extracting the cavity forming agent from the peeled thin film by washing the peeled thin film in an aqueous or nonaqueous solvent, thereby obtaining a sponge-like porous polypropylene thin film with cavities, macro-voids, and micropores. The sponge-like porous polypropylene thin film is used as an oil sorbent. The sponge-like porous polypropylene thin film has about 400 to about 700 swellable cavities per cm2.

Abstract: Polypropylene (PP) superhydrophobic sheets and a fabrication method thereof are provided. Superhydrophobic PP sheets of varying thickness having a base layer and a top layer may be fabricated using recycled or waste PP, where the fabrication process uses 20% of total plastic waste to prepare said sheets having contact angles ranging from 140 to 160 degrees. The polypropylene (PP) superhydrophobic sheets may impart protective water-repellent properties against the elements.

Abstract: Polypropylene (PP) superhydrophobic sheets and a fabrication method using a stream of polypropylene from plastic waste thereof are provided. Superhydrophobic PP sheets of varying thickness having a base layer and a top layer may be fabricated using recycled or waste polypropylene, where the fabrication process uses 20% of total plastic waste to prepare said sheets having contact angles ranging from 140 to 160 degrees. The polypropylene superhydrophobic sheets may impart protective water-repellent properties against the elements.