Publication number: 20240262707
Abstract: A cathode active material includes a plurality of cathode active particles, each particle being of a composition expressed as: [Li1+?(NixMnyCoz)1??O2]?M1[Li1+?(Nix?Mny?Coz?)1??O2]?M2[Li1+?(Nix?Mny?Coz?)1??O2]1-?-?M3; or [Na1+?(NixMnyCoz)1??O2]?M1[Na1+?(Nix?Mny?Coz?)1??O2]?M2[Na1+?(Nix?Mny?Coz?)1??O2]1-?-?M3; wherein: M1 is a structure having a layered phase; M2 has structure comprising a Mn-rich and/or spinel phase; M3 has a rock salt or disordered rock salt phase; M1, M2, and M3 have different formulae; an inner most core portion of the particle is one of M1, M2, or M3; an interlayer may be any one of the remaining two of M1, M2, or M3; an outer most layer may be the remaining member of M1, M2, or M3; 0??<1, 0<?<1, ?0.1???0.1, ?0.3???0.3, ?0.5???0.5, 0?x?1, 0?y?0.5, 0?z?1, 0?x??0.5, 0.5?y??1, 0?z??0.5, and 0?x??1, 0?y??1, 0?z??1; and the sum of x, y and z is 1, the sum of x?, y? and z? is 1, and the sum of x?, y?, and z? is 1.
Type:
Application
Filed:
February 3, 2023
Publication date:
August 8, 2024
Applicant:
UCHICAGO ARGONNE, LLC
Inventors:
Alvin Dai, Tongchao Liu, Khalil Amine