Patents by Inventor Khalil Amine

Khalil Amine has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20250096236
    Abstract: This disclosure relates generally to battery cells, and more particularly, cathode active materials for use in lithium-ion battery cells.
    Type: Application
    Filed: August 22, 2024
    Publication date: March 20, 2025
    Inventors: Hongli Dai, Chi-kai Lin, James A. Gilbert, Khalil Amine, Jihyeon Gim, John David Carter, Arthur Jeremy Kropf, Yingying Xie, Haiping Xu
  • Publication number: 20250096235
    Abstract: This disclosure relates to cathode active materials for use in lithium-ion battery cells.
    Type: Application
    Filed: August 22, 2024
    Publication date: March 20, 2025
    Inventors: Hongli Dai, Chi-kai Lin, James A. Gilbert, Khalil Amine, Jihyeon Gim, John David Carter, Arthur Jeremy Kropf, Yingying Xie, Haiping Xu
  • Publication number: 20250079514
    Abstract: A non-aqueous electrolyte comprising a salt, a non-aqueous solvent, and a compound of Formula (I) or Formula (II) or Formula (III) or Formula (IV) or Formula (V):
    Type: Application
    Filed: August 30, 2023
    Publication date: March 6, 2025
    Applicant: UCHICAGO ARGONNE, LLC
    Inventors: Chi Cheung Su, Khalil Amine
  • Patent number: 12176541
    Abstract: An electrochemical cell includes an anode that includes silicon, a conductive carbon, a lithium titanate, lithium metal, or a combination of any two or more thereof; a separator; a cathode having a cathode active material and a redox active species either mixed into the cathode or coated onto the cathode; and an electrolyte that includes a salt; and an aprotic solvent comprising a fluorinated ether solvent, a carbonate solvent, or a mixture thereof, with the proviso that the redox active species has substantially no solubility in the electrolyte. The redox active species may be a redox active organic compound or polymer.
    Type: Grant
    Filed: February 4, 2022
    Date of Patent: December 24, 2024
    Assignee: UChicago Argonne, LLC
    Inventors: Chi Cheung Su, Jiayan Shi, Rachid Amine, Khalil Amine
  • Publication number: 20240396089
    Abstract: An electrochemical cell includes a cathode comprising a cathode active material, an anode comprising an anode active material, and an electrolyte comprising a sulfonyl solvent, a terminally fluorinated glycol ether, and a salt. Other electrochemical cells include a cathode, an anode, a separator, and an electrolyte comprising: a lithium salt; a cathode stabilizing additive selected from the group consisting of vinylene carbonate, vinyl ethylene carbonate, LiBF2(C2O4), LiB(C2O4)2, LiPF2(C2O4)2, LiPF4(C2O4), LiPF6, LiAsF6, CsF, CsPF6, Li2(B12X12-iHi), Li2(B10X10-i?Hi?), or a mixture of any two or more thereof, wherein the cathode stabilizing additive is not the same as the lithium salt, wherein each X is independently at each occurrence a halogen, i is an integer from 0 to 12 and i? is an integer from 0 to 10; and a fluorinated organosulfate compound.
    Type: Application
    Filed: May 22, 2023
    Publication date: November 28, 2024
    Applicant: UCHICAGO ARGONNE, LLC
    Inventors: Chi Cheung SU, Khalil AMINE
  • Publication number: 20240356080
    Abstract: An electrochemical device comprising of a sulfur-based or alkali and/or alkali earth metal sulfide-based cathode, alkali and/or alkali earth metal-based anode with or without anode protection, a porous separator, non-aqueous electrolyte composition comprising of two or more alkali and/or alkali earth salts that has a total non-alkali/alkali earth metal NO3? (nitrate) salt concentration of below 0.1 M, one or more solvent, and the inclusion of a high donor number lithium salt; wherein the electrochemical device is a alkali and/or alkali earth metal sulfur battery.
    Type: Application
    Filed: April 21, 2023
    Publication date: October 24, 2024
    Applicant: UCHICAGO ARGONNE, LLC
    Inventors: Matthew Li, Yingying Xie, Khalil Amine, Chi Cheung Su
  • Publication number: 20240313209
    Abstract: A cathode active material includes a composition expressed as: Li1+?(NixMnyCoz)M1?(Nix?Mny?Coz?)M21??O2; or Na1+?(NixMnyCoz)M1?(Nix?Mny?Coz?)M21??O2; where: M1 represents a core composition comprising of Ni, Mn, and/or Co or a combination of at two of thereof; M2 represents a surface composition having at least 50% Co, and, optionally Ni and/or Mn; the structure of M2 may be a composite structure and includes a rock-salt or disordered rock-salt phase; 0.5??<1, 0?x?1, 0?y?0.5, 0?z?1, 0?x??0.5, 0?y??0.5, 0.5?z??1, and ?0.1???0.1; the sum of x, y and z is 0.9-1.1, and the sum of x?, y? and z? is 0.9-1.1.
    Type: Application
    Filed: May 23, 2024
    Publication date: September 19, 2024
    Applicant: UCHICAGO ARGONNE, LLC
    Inventors: Tongchao Liu, Khalil Amine
  • Patent number: 12095083
    Abstract: A cathode active material includes a composition expressed as: Li1+?(NixMnyCoz)M1?(Nix?Mny?Coz?)M21-?O2; or Na1+?(NixMnyCoz)M1?(Nix?Mny?Coz?)M21-?O2; where: M1 represents a core composition comprising of Ni, Mn, and/or Co or a combination of at two of thereof; M2 represents a surface composition having at least 50% Co, and, optionally Ni and/or Mn; the structure of M2 may be a composite structure and includes a rock-salt or disordered rock-salt phase; 0.5??<1, 0?x?1, 0?y?0.5, 0?z?1, 0?x??0.5, 0?y??0.5, 0.5?z??1, and ?0.1???0.1; the sum of x, y and z is 0.9-1.1, and the sum of x?, y? and z? is 0.9-1.1.
    Type: Grant
    Filed: March 4, 2020
    Date of Patent: September 17, 2024
    Assignee: UCHICAGO ARGONNE, LLC
    Inventors: Tongchao Liu, Khalil Amine
  • Publication number: 20240266527
    Abstract: A coated cathode material including high-nickel lithium cathode and a method of producing the same by atomic layer deposition.
    Type: Application
    Filed: February 6, 2023
    Publication date: August 8, 2024
    Applicant: UCHICAGO ARGONNE, LLC
    Inventors: Jihyeon Gim, Anil U. Mane, Jinhyup Han, Seoung-Bum Son, Pragathi Darapaneni, Eungje Lee, Khalil Amine, Jeffrey W. Elam, Jason R. Croy, Rajesh Pathak
  • Publication number: 20240262707
    Abstract: A cathode active material includes a plurality of cathode active particles, each particle being of a composition expressed as: [Li1+?(NixMnyCoz)1??O2]?M1[Li1+?(Nix?Mny?Coz?)1??O2]?M2[Li1+?(Nix?Mny?Coz?)1??O2]1-?-?M3; or [Na1+?(NixMnyCoz)1??O2]?M1[Na1+?(Nix?Mny?Coz?)1??O2]?M2[Na1+?(Nix?Mny?Coz?)1??O2]1-?-?M3; wherein: M1 is a structure having a layered phase; M2 has structure comprising a Mn-rich and/or spinel phase; M3 has a rock salt or disordered rock salt phase; M1, M2, and M3 have different formulae; an inner most core portion of the particle is one of M1, M2, or M3; an interlayer may be any one of the remaining two of M1, M2, or M3; an outer most layer may be the remaining member of M1, M2, or M3; 0??<1, 0<?<1, ?0.1???0.1, ?0.3???0.3, ?0.5???0.5, 0?x?1, 0?y?0.5, 0?z?1, 0?x??0.5, 0.5?y??1, 0?z??0.5, and 0?x??1, 0?y??1, 0?z??1; and the sum of x, y and z is 1, the sum of x?, y? and z? is 1, and the sum of x?, y?, and z? is 1.
    Type: Application
    Filed: February 3, 2023
    Publication date: August 8, 2024
    Applicant: UCHICAGO ARGONNE, LLC
    Inventors: Alvin Dai, Tongchao Liu, Khalil Amine
  • Patent number: 12021220
    Abstract: A cathode material comprising: a cathode active material of formula LiNixMnyCozO2 or NaNixMnyCozO2 and having a partial or whole particle concentration gradient, wherein at least two or three elements concentration gradually change in the part or whole particle from the center part to the surface part of the particle (i.e. along a vector radius); 0.5<x?1, 0?y?0.33, 0?z?0.33.
    Type: Grant
    Filed: April 12, 2023
    Date of Patent: June 25, 2024
    Assignee: UCHICAGO ARGONNE, LLC
    Inventors: Khalil Amine, Tongchao Liu, Jun Lu
  • Patent number: 12021226
    Abstract: An active cathode material containing particles with a core containing a lithium transition metal oxide, each core at least partially encapsulated by a layer including the lithium transition metal oxide and dopant cation; and an outer layer containing metal oxide; wherein the dopant cation is selected from the group consisting of Al, Ti, Sn, Mg, Zr, Cu, Fe, Ca, W, Ga, Sc, Y, La, Hf, V, In, Nb, Ta, and any combination of two or more thereof; and the dopant cation is present in an amount of 10 wt. % or less of the particle.
    Type: Grant
    Filed: June 30, 2017
    Date of Patent: June 25, 2024
    Assignees: UCHICAGO ARGONNE, LLC, BAYERISCHE MOTOREN WERKE AKTIENGESELLSCHAFT
    Inventors: Khalil Amine, Xiaoqiao Zeng, Zonghai Chen, Filippo Maglia
  • Patent number: 12009509
    Abstract: An electrochemical device includes a lithium anode having a red poly(benzonitrile) coating covering at least a portion of the anode; a separator and an air cathode comprising reduced graphene oxide over gas diffusion layer; and an electrolyte comprising an ether solvent, benzonitrile, and a lithium salt.
    Type: Grant
    Filed: January 26, 2023
    Date of Patent: June 11, 2024
    Assignee: UCHICAGO ARGONNE, LLC
    Inventors: Hsien-Han Wang, Ritesh Jagatramka, Samuel Plunkett, Larry A. Curtiss, Khalil Amine
  • Patent number: 11955636
    Abstract: An electrochemical device includes a cathode comprising a first cathode component of lithium and SexSy; and a second cathode component of an alkali metal and/or alkaline earth metal sulfur and/or selenide, different from the first cathode component; an initial discharge product of a polyselenide and/or polysulfide anion charge compensated by an alkali metal and/or alkaline earth metal cation; an anode; a porous separator; and a non-aqueous electrolyte with one or more lithium salts, and one or more solvents; wherein the electrochemical device is a lithium sulfur and/or lithium selenide battery.
    Type: Grant
    Filed: September 17, 2021
    Date of Patent: April 9, 2024
    Assignee: UCHICAGO ARGONNE, LLC
    Inventors: Matthew Li, Khalil Amine, Jun Lu
  • Publication number: 20240110292
    Abstract: The present invention provides, in part, methods and processes for the production of lithium superoxide (LiO2) which is free of other lithium-oxygen compounds, as well as compositions and electrochemical cells comprising lithium superoxide (e.g., lithium superoxide that is free of other lithium-oxygen compounds).
    Type: Application
    Filed: September 22, 2022
    Publication date: April 4, 2024
    Applicant: UCHICAGO ARGONNE, LLC
    Inventors: Larry A. Curtiss, Hsien-Hau Wang, Khalil Amine, Samuel Plunkett
  • Publication number: 20240105916
    Abstract: The present invention provides, in part, electrodes (e.g., cathodes) comprising electroactive materials (e.g., cathode active materials), a primary coating comprising a high entropy metal oxide (HEO), and optionally a secondary coating layer comprising an ionic and electronic conductive polymer, as well as an energy storage device thereof, and methods for making the same.
    Type: Application
    Filed: September 28, 2022
    Publication date: March 28, 2024
    Applicant: UCHICAGO ARGONNE, LLC
    Inventors: Guiliang Xu, Yuzi Liu, Chen Zhao, Khalil Amine
  • Publication number: 20240105998
    Abstract: The present invention provides, in part, an electrochemical energy storage device comprising a metal anode, a separator, a high-mass-loading selenium-sulfur cathode and a lean electrolyte. In particular, the electrolyte described herein employs active solid-electrolyte interphase engineering salts and features unique solvating structure. The combination of high-mass-loading S cathode and the particular electrolytes can enhance one or more of the following cell properties: energy density, cycling stability, safety, and working temperature window.
    Type: Application
    Filed: September 28, 2022
    Publication date: March 28, 2024
    Applicant: UCHICAGO ARGONNE, LLC
    Inventors: Guiliang Xu, Chen Zhao, Khalil Amine
  • Patent number: 11923527
    Abstract: An electrochemical device includes an anode containing a phosphorus-carbon composite including a conductive carbon matrix and nano-sized phosphorus particles, wherein the nano-sized phosphorus particles are uniformly dispersed on the surface and/or pores of the carbon matrix.
    Type: Grant
    Filed: September 10, 2020
    Date of Patent: March 5, 2024
    Assignee: UCHICAGO ARGONNE, LLC
    Inventors: Guiliang Xu, Zonghai Chen, Khalil Amine
  • Publication number: 20230327208
    Abstract: A lithium ion battery includes a cathode including a cathode active material; an anode including silicon, a conductive carbon, lithium metal, or a combination of any two or more thereof; a separator; and an electrolyte including a lithium sulfonylimide salt, a dicarbonyl solvent, and a fluorinated ether solvent.
    Type: Application
    Filed: April 11, 2022
    Publication date: October 12, 2023
    Applicant: UCHICAGO ARGONNE, LLC
    Inventors: Chi Cheung Su, Khalil Amine
  • Patent number: 11769905
    Abstract: An electrochemical device includes a cathode including elemental selenium, elemental sulfur, or selenium-sulfur containing composite; a negative electrode; a separator; and an electrolyte including a poly(alkyleneoxide) siloxane; and a salt; wherein a concentration of the salt in the electrolyte is sufficient to minimize dissolution of polysulfides/polyselenides formed during cycling of the device.
    Type: Grant
    Filed: August 7, 2017
    Date of Patent: September 26, 2023
    Assignee: UChicago Argonne, LLC
    Inventors: Gui-Liang Xu, Jianzhao Liu, Zonghai Chen, Khalil Amine