Abstract: A valve which is cobalt-free excellent in wear resistance and seizure resistance manufactured by forming valve seats for a valve disc and a valve body with a nickel base alloy in which silicide particles or boride particles of small particle size are finely dispersed, and the valve seat is bonded to the valve disc or the valve body by way of an insert material comprising a nickel base alloy of a lower melting point by transient liquid phase diffusion bonding.

Abstract: A valve which is cobalt-free excellent in wear resistance and seizure resistance manufactured by forming valve seats for a valve disc and a valve body with a nickel base alloy in which silicide particles or boride particles of small particle size are finely dispersed, and the valve seat is bonded to the valve disc or the valve body by way of an insert material comprising a nickel base alloy of a lower melting point by transient liquid phase diffusion bonding.

Abstract: Hard facing layers provided on engagement portions of a valve body and engagement portions of a valve box of a valve apparatus, consisting of cobalt-free Ni-base alloys. One of the Ni-base alloys for the hard facing layers comprises not more than 15% Fe and less than 2% W (tungsten), and the other comprises more than 15% Fe. More specifically, one of the cobalt-free Ni-base alloys essentially consists of, by weight, 15 to 20% Cr, 5 to 10% Si, 10 to 15% Fe, less than 2% W, and the balance of Ni and unavoidable impurities, and has a Vickers hardness (Hv) 510 to 630, and the other essentially consists of, by weight, 5 to 15% Cr, 5 to 10% Si, more than 15% and not more than 30% Fe, 1 to 4% W, and the balance of Ni and unavoidable impurities, and has a Vickers hardness (Hv) 400 to 470. The valve apparatus of the invention is suitably installed in a water pipe line which communicates with a nuclear reactor.