Patents by Inventor Kim O. Tresco
Kim O. Tresco has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 10563111Abstract: The invention provides concentrates for reducing the fluid loss on an oil base well drilling or servicing fluid, the concentrates comprising an oleagineous liquid and (1) a polymer which is solublized in the oleagineous liquid, or (2) a polymer which is solublized in the oleaginous liquid together with an organophilic polyphenolic material which is solublized and/or dispersed in the oleagineous liquid. The method of preparing the concentrate and the method of reducing the fluid loss of an oil base well drilling or servicing fluid utilizing the concentrates is also disclosed. The preferred oil soluble polymer is a styrene-butadiene rubber crumb. The preferred oleagineous liquid is an aromatic-free hydrogenated oil essentially containing only saturated hydrocarbons. The preferred polyphenolic material is a source of humic acid, such as mined lignite.Type: GrantFiled: February 28, 2017Date of Patent: February 18, 2020Assignee: TUCC Technology, LLCInventors: James W. Dobson, Jr., Kim O. Tresco
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Patent number: 10160897Abstract: Disclosed is an alkaline earth metal peroxide concentrate, or fluidized suspension, for addition to aqueous hydraulic fracturing fluids to efficiently decrease the viscosity of the hydrated, hydrophilic polysaccharide polymer in the system. The concentrate comprises a hydrophobic, water insoluble liquid, an organophilic clay suspension agent, a polar activator, a sparingly-soluble alkaline earth metal peroxide, and an anionic surfactant. Advantageously, these concentrations, or suspensions, exhibit high flash points, making them easier to transport using commercial transportation means.Type: GrantFiled: August 3, 2017Date of Patent: December 25, 2018Assignee: TUCC Technology, LLCInventors: James W. Dobson, Jr., Shauna L. Hayden, Kim O. Tresco
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Patent number: 9969927Abstract: A treatment fluid composition for treating a subterranean formation penetrated by a well bore is formed from an aqueous fluid, a hydratable polymer and an inorganic peroxide breaking agent, which is classified as a stable, non-oxidizer according to UN standards but which retains oxidizing properties as measured by the content of available oxygen. A method of treating a subterranean formation penetrated by a well bore may also be performed by forming a treatment fluid from an aqueous hydrated polymer solution. This is combined with a stable, inorganic peroxide breaking agent. The treating fluid is then introduced into the formation. An optional crosslinking agent capable of crosslinking the polymer may also be included.Type: GrantFiled: May 23, 2014Date of Patent: May 15, 2018Assignee: TUCC Technology, LLCInventors: James W. Dobson, Jr., Shauna L. Hayden, Kim O. Tresco
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Patent number: 9856409Abstract: A water-based drilling fluid which includes an aqueous fluid and a water-soluble dissipative surfactant composition is described, wherein the dissipative surfactant composition includes at least one fatty acid or ester derivative of a plant or vegetable oil. Also described are methods of using such aqueous-based drilling fluids including the dissipative surfactant composition as described in hydrocarbon recovery operations associated with oil/tar sand, where such fluids act to increase the dispersant qualities of hydrocarbons within the oil/tar sand, and where such fluid exhibit a reduced coefficient of friction.Type: GrantFiled: January 30, 2015Date of Patent: January 2, 2018Assignee: TUCC Technology, LLCInventors: James W. Dobson, Jr., Kim O. Tresco, Pierre J. Hinds
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Patent number: 9850417Abstract: A fluid pressure transmission pill (FPTP) having an ultra-high viscosity for use in association with hydrocarbon drilling and exploration operations, particularly, managed pressure drilling (MPD) operations, is described. The ultra-high viscosity pill is a weighted pill composition that includes a hydrocarbon fluid, a thixotropic viscosifying agent, one or more activators, an emulsifier/wetting agent, a fluid loss control additive, and a weighting material. In accordance with selected aspects of the described fluid pressure transmission pill, the ratio of the amount of the thixotropic viscosifying agent to the activator is a ratio of about 7:1, and the weighting material is a barium-containing solid-phase material. Also described are methods of use of such FPTP products in subterranean operations, such as well killing operations during managed pressure drilling.Type: GrantFiled: January 11, 2013Date of Patent: December 26, 2017Assignee: TUCC Technology, LLCInventors: James W. Dobson, Jr., Kim O. Tresco, Benjamin K. Geerdes
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Publication number: 20170327725Abstract: Disclosed is an alkaline earth metal peroxide concentrate, or fluidized suspension, for addition to aqueous hydraulic fracturing fluids to efficiently decrease the viscosity of the hydrated, hydrophilic polysaccharide polymer in the system. The concentrate comprises a hydrophobic, water insoluble liquid, an organophilic clay suspension agent, a polar activator, a sparingly-soluble alkaline earth metal peroxide, and an anionic surfactant. Advantageously, these concentrations, or suspensions, exhibit high flash points, making them easier to transport using commercial transportation means.Type: ApplicationFiled: August 3, 2017Publication date: November 16, 2017Inventors: James W. Dobson, JR., Shauna L. Hayden, Kim O. Tresco
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Patent number: 9725637Abstract: Disclosed is an alkaline earth metal peroxide concentrate, or fluidized suspension, for addition to aqueous hydraulic fracturing fluids to efficiently decrease the viscosity of the hydrated, hydrophilic polysaccharide polymer in the system. The concentrate comprises a hydrophobic, water insoluble liquid, an organophilic clay suspension agent, a polar activator, a sparingly-soluble alkaline earth metal peroxide, and an anionic surfactant. Advantageously, these concentrations, or suspensions, exhibit high flash points, making them easier to transport using commercial transportation means.Type: GrantFiled: February 5, 2013Date of Patent: August 8, 2017Assignee: TUCC Technology, LLCInventors: James W. Dobson, Jr., Shauna L. Hayden, Kim O. Tresco
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Publication number: 20170166796Abstract: The invention provides concentrates for reducing the fluid loss on an oil base well drilling or servicing fluid, the concentrates comprising an oleagineous liquid and (1) a polymer which is solublized in the oleagineous liquid, or (2) a polymer which is solublized in the oleaginous liquid together with an organophilic polyphenolic material which is solublized and/or dispersed in the oleagineous liquid. The method of preparing the concentrate and the method of reducing the fluid loss of an oil base well drilling or servicing fluid utilizing the concentrates is also disclosed. The preferred oil soluble polymer is a styrene-butadiene rubber crumb. The preferred oleagineous liquid is an aromatic-free hydrogenated oil essentially containing only saturated hydrocarbons. The preferred polyphenolic material is a source of humic acid, such as mined lignite.Type: ApplicationFiled: February 28, 2017Publication date: June 15, 2017Inventors: James W. Dobson, JR., Kim O. Tresco
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Publication number: 20150166866Abstract: A water-based drilling fluid which includes an aqueous fluid and a water-soluble dissipative surfactant composition is described, wherein the dissipative surfactant composition includes at least one fatty acid or ester derivative of a plant or vegetable oil. Also described are methods of using such aqueous-based drilling fluids including the dissipative surfactant composition as described in hydrocarbon recovery operations associated with oil/tar sand, where such fluids act to increase the dispersant qualities of hydrocarbons within the oil/tar sand, and where such fluid exhibit a reduced coefficient of friction.Type: ApplicationFiled: January 30, 2015Publication date: June 18, 2015Inventors: James W. Dobson, JR., Kim O. Tresco, Pierre J. Hinds
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Publication number: 20140349897Abstract: A treatment fluid composition for treating a subterranean formation penetrated by a well bore is formed from an aqueous fluid, a hydratable polymer and an inorganic peroxide breaking agent, which is classified as a stable, non-oxidizer according to UN standards but which retains oxidizing properties as measured by the content of available oxygen. A method of treating a subterranean formation penetrated by a well bore may also be performed by forming a treatment fluid from an aqueous hydrated polymer solution. This is combined with a stable, inorganic peroxide breaking agent. The treating fluid is then introduced into the formation. An optional crosslinking agent capable of crosslinking the polymer may also be included.Type: ApplicationFiled: May 23, 2014Publication date: November 27, 2014Applicant: TUCC Technology, LLCInventors: James W. Dobson, JR., Shauna L. Hayden, Kim O. Tresco
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Publication number: 20140051606Abstract: The invention provides concentrates for reducing the fluid loss on an oil base well drilling or servicing fluid, the concentrates comprising an oleagineous liquid and (1) a polymer which is solublized in the oleagineous liquid, or (2) a polymer which is solublized in the oleaginous liquid together with an organophilic polyphenolic material which is solublized and/or dispersed in the oleagineous liquid. The method of preparing the concentrate and the method of reducing the fluid loss of an oil base well drilling or servicing fluid utilizing the concentrates is also disclosed. The preferred oil soluble polymer is a styrene-butadiene rubber crumb. The preferred oleagineous liquid is an aromatic-free hydrogenated oil essentially containing only saturated hydrocarbons. The preferred polyphenolic material is a source of humic acid, such as mined lignite.Type: ApplicationFiled: August 20, 2013Publication date: February 20, 2014Applicant: TUCC Technology, LLCInventors: James W. Dobson, JR., Kim O. Tresco
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Publication number: 20140034323Abstract: Disclosed are treating fluid compositions for use in subterranean workover and hydrocarbon recovery operations, as well as methods of treating subterranean formations penetrated by a wellbore utilizing the treating fluid. The treating fluid compositions contain a first, aqueous liquid, and a crosslinkable organic polymer that is at least partly soluble in the liquid. The treating fluid further contains a borate crosslinking agent solution containing a primary, un-refined borate and a secondary, refined borate, the borate solution being present as a crosslinking agent upon addition to the first fluid admixture so as to crosslink the organic polymer and increase the viscosity and/or accelerate the crosslink time of the treating fluid.Type: ApplicationFiled: July 9, 2013Publication date: February 6, 2014Applicant: Texas United Chemical Company, LLCInventors: James W. Dobson, JR., Kim O. Tresco
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Patent number: 7897544Abstract: The invention discloses a compounded hydrocarbon oil which comprises a base hydrocarbon oil, preferably a mixture of paraffinic hydrocarbons, propylene carbonate, and a liquid fatty acid containing at least 12 carbon atoms per molecule, preferably tall oil fatty acid. The volume ratio of propylene carbonate to liquid fatty acid is from about 3.5 to 1 to about 7 to 1. Preferably the concentration of propylene carbonate is from about 0.002 gal/gal oil to about 0.0057 gal/gal oil and the concentration of the liquid fatty acid is from about 0.0003 gal/gal oil to about 0.0015 gal/gal oil. The invention further comprises a method of compounding the compounded hydrocarbon oil and an oil base drilling fluid prepared from the compounded hydrocarbon oil. Preferably the compounded hydrocarbon oil is characterized by an increase in the low shear rate viscosity of the oil of at least 5,000 centipoise or mixing 7.5 lb/bbl of an organoclay therein.Type: GrantFiled: December 16, 2005Date of Patent: March 1, 2011Assignee: Texas United Chemical Company, LLCInventors: James W. Dobson, Jr., Jorge M. Fernandez, Kim O. Tresco, Abmel Marquez Perez
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Publication number: 20110009298Abstract: A fluid pressure transmission pill (FPTP) having an ultra-high viscosity for use in association with hydrocarbon drilling and exploration operations, particularly, managed pressure drilling (MPD) operations, is described. The ultra-high viscosity pill is a weighted pill composition that includes a hydrocarbon fluid, a thixotropic viscosifying agent, one or more activators, an emulsifier/wetting agent, a fluid loss control additive, and a weighting material. In accordance with selected aspects of the described fluid pressure transmission pill, the ratio of the amount of the thixotropic viscosifying agent to the activator is a ratio of about 7:1, and the weighting material is a barium-containing solid-phase material. Also described are methods of use of such FPTP products in subterranean operations, such as well killing operations during managed pressure drilling.Type: ApplicationFiled: July 9, 2010Publication date: January 13, 2011Applicant: TEXAS UNITED CHEMICAL COMPANY, LLCInventors: James W. Dobson, JR., Kim O. Tresco, Benjamin K. Geerdes
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Patent number: 7214647Abstract: The invention provides well drilling and servicing fluids, and methods of drilling, completing, or working over a well therewith, preferred fluids comprise an aqueous liquid, a water soluble polymer viscosifier (preferably xanthan gum), a polymeric fluid loss control additive (preferably a partially depolymerized partially crosslinked hydroxyalkyl ether derivative of starch or a hydroxyalkyl ether derivative of a partially crosslinked and partially depolymerized starch), a bridging agent comprising a particulate calcined magnesia that has an Activity Index greater than about 800 seconds, and an additive selected from the group consisting of citric acid, alkali metal salts of citric acid, ammonium citrate, and mixtures thereof in an amount sufficient to increase the low shear rate viscosity of the fluids, preferably from about 0.05–5 ppb, most preferably from about 0.15–3 ppb.Type: GrantFiled: December 14, 2004Date of Patent: May 8, 2007Assignee: Texas United Chemical Company, LLC.Inventors: James W. Dobson, Jr., Kim O. Tresco, Jorge M. Fernandez
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Patent number: 7211546Abstract: The invention provides well drilling and servicing fluids, and methods of drilling, completing, or working over a well therewith, preferred fluids comprise an aqueous liquid, a water soluble polymer viscosifier (preferably xanthan gum), a polymeric fluid loss control additive (preferably a partially depolymerized partially crosslinked hydroxyalkyl ether derivative of starch or a hydroxyalkyl ether derivative of a partially crosslinked and partially depolymerized starch), a bridging agent comprising a particulate calcined magnesia that has an Activity Index greater than about 800 seconds, and citric acid in an amount sufficient to increase the low shear rate viscosity of the fluids. The invention further provides a method of increasing the low shear rate viscosity of fluids which contain a water soluble polymer and a calcined magnesia bridging agent which has an Activity Index greater than about 800 seconds.Type: GrantFiled: July 29, 2004Date of Patent: May 1, 2007Assignee: Texas United Chemical Company, LLC.Inventors: James W. Dobson, Jr., Kim O. Tresco, Jorge M. Fernandez
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Patent number: 6576597Abstract: Disclosed is a method of increasing the low shear rate viscosity and the shear thinning index of aqueous fluids containing a divalent cation salt, a crosslinked amylopectin starch which functions as both a viscosifier/suspending agent and as a fluid loss control additive, and a bridging agent, the fluids resulting from the method, and the use of the fluids in drilling a well, wherein the bridging agent is a sized particulate magnesium carbonate or a mixture of sized magnesium carbonate and sized calcium carbonate. The median (D50) particle size of the magnesium carbonate is from about 2 &mgr;m to about 10 &mgr;m. The weight ratio of calcium carbonate to magnesium carbonate is from about 70/30 to about 0/100.Type: GrantFiled: October 4, 2001Date of Patent: June 10, 2003Assignee: Texas United Chemical Company, LLC.Inventors: James W. Dobson, Jr., Kim O. Tresco
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Patent number: 6391830Abstract: The invention provides clay-free, preferably biopolymer free, well drilling and servicing fluids comprising an aqueous divalent cation-containig water soluble salt, a bridging agent, and a pre-gelatinized crosslinked amylopectin starch suspending agent and fluid loss control additive. The concentration of the starch derivative is sufficient to provide the fluid with the following charactristics: (a) a low shear rate viscosity less than about 10,000 centipoise; (b) a high shear rate viscosity at 511 sec−1 in the range from about 15 to about 70 centipoise measured at 120° F.; (c) a fluid loss less than about 10 milliliters as measured at 185° F. and 250 psi differential pressure across a 5 micron disk for 30 minutes; and (d) anti-settling characteristics as exhibited upon static aging the fluid for 16 hours at 185° F.Type: GrantFiled: April 2, 2001Date of Patent: May 21, 2002Assignee: Texas United Chemical Company, LLC.Inventors: James W. Dobson, Jr., Kim O. Tresco, Jeffrey S. Lay
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Publication number: 20020028750Abstract: Disclosed is a method of increasing the low shear rate viscosity and the shear thinning index of aqueous fluids containing a divalent cation salt, a crosslinked amylopectin starch which functions as both a viscosifier/suspending agent and as a fluid loss control additive, and a bridging agent, the fluids resulting from the method, and the use of the fluids in drilling a well, wherein the bridging agent is a sized particulate magnesium carbonate or a mixture of sized magnesium carbonate and sized calcium carbonate. The median (D50) particle size of the magnesium carbonate is from about 2 &mgr;m to about 10 &mgr;m. The weight ratio of calcium carbonate to magnesium carbonate is from about 70/30 to about 0/100.Type: ApplicationFiled: October 4, 2001Publication date: March 7, 2002Inventors: James W. Dobson, Kim O. Tresco
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Patent number: 6300286Abstract: The invention provides clay-free, preferably biopolymer free, well drilling and servicing fluids comprising an aqueous divalent cation-containing water soluble salt, a bridging agent, and a pre-gelatinized crosslinked amylopectin starch suspending agent and fluid loss control additive. The concentration of the starch derivative is sufficient to provide the fluid with the following charactersitics: (a) a low shear rate viscosity less than about 10,000 centipoise; (b) a high shear rate viscosity at 511 sec−1 in the range from about 15 to about 70 centipoise measured at 120° F.; (c) a fluid loss less than about 10 milliliters as measured at 185° F. and 250 psi differential pressure across a 5 micron disk for 30 minutes; and (d) anti-settling characteristics as exhibited upon static aging the fluid for 16 hours at 185° F.Type: GrantFiled: August 5, 1999Date of Patent: October 9, 2001Assignee: Texas United Chemical Company, L.L.C.Inventors: James W. Dobson, Jr., Kim O. Tresco, Jeffrey S. Lay