Patents by Inventor Kimberly Gheysen Raiford
Kimberly Gheysen Raiford has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
-
Patent number: 9728800Abstract: A proton exchange membrane and a membrane electrode assembly for an electrochemical cell such as a fuel cell are provided. A catalytically active component is disposed within the membrane electrode assembly. The catalytically active component comprises particles containing a metal oxide such as silica, metal or metalloid ions such as ions that include boron, and a catalyst. A process for increasing peroxide radical resistance in a membrane electrode is also provided that includes the introduction of the catalytically active component described into a membrane electrode assembly.Type: GrantFiled: January 6, 2014Date of Patent: August 8, 2017Assignee: THE CHEMOURS COMPANY FC, LLCInventors: Kimberly Gheysen Raiford, Junaid Ahmed Siddiqui
-
Patent number: 8722569Abstract: A catalytically active component is provided which comprises particles containing a metal oxide such as silica, metal or metalloid ions such as ions that include boron, and a catalyst. When introduced into the membrane electrode assembly of a fuel cell, the particles increase peroxide radical resistance in a membrane electrode.Type: GrantFiled: February 28, 2007Date of Patent: May 13, 2014Assignee: E I du Pont de Nemours and CompanyInventors: Junaid Ahmed Siddiqui, Kimberly Gheysen Raiford
-
Publication number: 20140120455Abstract: A proton exchange membrane and a membrane electrode assembly for an electrochemical cell such as a fuel cell are provided. A catalytically active component is disposed within the membrane electrode assembly. The catalytically active component comprises particles containing a metal oxide such as silica, metal or metalloid ions such as ions that include boron, and a catalyst. A process for increasing peroxide radical resistance in a membrane electrode is also provided that includes the introduction of the catalytically active component described into a membrane electrode assembly.Type: ApplicationFiled: January 6, 2014Publication date: May 1, 2014Applicant: E I DU PONT DE NEMOURS AND COMPANYInventors: Kimberly Gheysen Raiford, Junaid Ahmed Siddiqui
-
Patent number: 8663866Abstract: A proton exchange membrane and a membrane electrode assembly for an electrochemical cell such as a fuel cell are provided. A catalytically active component is disposed within the membrane electrode assembly. The catalytically active component comprises particles containing a metal oxide such as silica, metal or metalloid ions such as ions that include boron, and a catalyst. A process for increasing peroxide radical resistance in a membrane electrode is also provided that includes the introduction of the catalytically active component described into a membrane electrode assembly.Type: GrantFiled: February 28, 2007Date of Patent: March 4, 2014Assignee: E I du Pont de Nemours and CompanyInventors: Kimberly Gheysen Raiford, Junaid Ahmed Siddiqui
-
Publication number: 20120052407Abstract: The present invention relates to a process for increasing an ion exchange membrane's resistance to peroxide radical attack in a fuel cell environment comprising the use of catalytically active components capable of decomposing hydrogen peroxide as well as a method for preparing a catalytically active component for use therein. Thus, a process has been developed for reducing or preventing proton exchange membrane degradation due to its interaction with hydrogen peroxide, where the catalytically active components serve as hydrogen peroxide scavengers to protect the PEM from chemical reaction with hydrogen peroxide by decomposing the hydrogen peroxide to H2O and O2 rather than the radicals that degrade the PEM.Type: ApplicationFiled: November 8, 2011Publication date: March 1, 2012Applicant: E. I. DU PONT DE NEMOURS AND COMPANYInventors: Kimberly Gheysen Raiford, Dennis Edward Curtin, Kostantinos Kourtakis
-
Publication number: 20070212593Abstract: A proton exchange membrane and a membrane electrode assembly for an electrochemical cell such as a fuel cell are provided. A catalytically active component is disposed within the membrane electrode assembly. The catalytically active component comprises particles containing a metal oxide such as silica, metal or metalloid ions such as ions that include boron, and a catalyst. A process for increasing peroxide radical resistance in a membrane electrode is also provided that includes the introduction of the catalytically active component described into a membrane electrode assembly.Type: ApplicationFiled: February 28, 2007Publication date: September 13, 2007Inventors: Kimberly Gheysen Raiford, Junaid Ahmed Siddiqui
-
Publication number: 20070213209Abstract: A catalytically active component is provided which comprises particles containing a metal oxide such as silica, metal or metalloid ions such as ions that include boron, and a catalyst. When introduced into the membrane electrode assembly of a fuel cell, the particles increase peroxide radical resistance in a membrane electrode.Type: ApplicationFiled: February 28, 2007Publication date: September 13, 2007Inventors: Junaid Ahmed Siddiqui, Kimberly Gheysen Raiford
-
Patent number: 6297304Abstract: Fluorinated diesters useful for imparting repellency of low surface tension fluids to thermoplastic polymers of formulae Rf—O—C(O)—(CH2)n—C(O)—O—R1; Rf—O—C(O)—CH2—CH(R2)—C(O)—O—Rf; a mixture of Rf—O—C(O)—(CH2)n—C(O)—O—R1, Rf—O—C(O)—(CH2)n—C(O)—Rf, and R1—O—C(O)—(CH2)n—C(O)—O—R1; and [F(CF2)xCH2CH2—S—CH2]2—C—[CH2—O—C(O)—C17H35]2; wherein Rf is F(CF2)x—(CH2)m wherein x is 4 to 20 and m is 2 to 6, or F(CF2)x—SO2N(R3)—R4 wherein x is 4 to 20; R1 is a saturated aliphatic hydrocarbon with an average carbon chain length of 12 to 66 carbons; R2 is a saturated or unsaturated hydrocarbon with 1-20 carbon atoms; R3 is an alkyl radical having 1 to 4 carbon atoms; R4 is an alkylene radical having 1 to 12 carbon atoms; n is 1 to 20, and x is 4 to 20 are discloseType: GrantFiled: June 21, 1999Date of Patent: October 2, 2001Assignee: E. I. du Pont de Nemours and CompanyInventors: Kimberly Gheysen Raiford, Theodor Arthur Liss, Edward James Greenwood, Jack Robert Kirchner
-
Patent number: 6114419Abstract: Fluorinated imides useful for imparting repellency of low surface tension fluids to thermoplastic polymers of formulae ##STR1## wherein R.sub.1 is F(CF.sub.2).sub.x --(CH.sub.2).sub.m, or F(CF.sub.2).sub.x SO.sub.2 N(R.sub.5) (CH.sub.2)p wherein x is from about 4 to about 20, m is from about 2 to about 6, p is from 1 to about 12, and R.sub.5 is an alkyl radical of from 1 to about 4 carbons;R.sub.2 is a linear, branched or cyclic alkylene or poly(oxyalkylene) hydrocarbon group having from about 2 to about 15 carbons;R.sub.3 is selected from the group consisting of F(CF.sub.2).sub.x --(CH.sub.2).sub.m, F(CF.sub.2).sub.x --(CH.sub.2).sub.m --OC(O)--(CH.sub.2).sub.n, and F(CF.sub.2).sub.x SO.sub.2 N(R.sub.5)(CH.sub.2).sub.p OC(O)(CH.sub.2).sub.n wherein x is from about 4 to about 20, m is from about 2 to about 6, n is about 2 to about 12, p is from 1 to about 12, and R.sub.5 is an alkyl radical of from 1 to about 4 carbons;R.sub.4 is an alkyl or alkenyl group of from about 4 to about 20 carbons, andR.sub.Type: GrantFiled: April 7, 1998Date of Patent: September 5, 2000Assignee: E. I. du Pont de Nemours and CompanyInventors: Theodor Arthur Liss, Kimberly Gheysen Raiford, Edward James Greenwood
-
Patent number: 6063474Abstract: A composition having repellency to low surface tension fluids comprising a material prepared by forming a mixture of a polymer selected from the group consisting of polyolefin, polyamide, polyester, polyacrylate, and blends and copolymers thereof, and a fluorochemical compound comprising a fluorocarbon/hydrocarbon ester of the formulae:R.sub.f --O--C(O)--R.sub.1 or R.sub.f --C(O)--O--R.sub.1whereinRf is selected from the group consisting of:1) F(CF.sub.2).sub.x --(CH.sub.2).sub.m wherein x is from about 4 to about 20 and m is from about 0 to about 6; and2) F(CF.sub.2).sub.x --SO.sub.2 N(R.sub.2)--R.sub.3 where x is a positive integer from about 4 to about 20, R.sub.2 is an alkyl radical of from about 1 to about 4 carbon atoms, R.sub.3 is an alkylene radical of from about 1 to about 12 carbon atoms; andR.sub.1 is an aliphatic hydrocarbon having from about 12 to about 76 carbon atoms; andprovided that said fluorochemical compound is other than perfluoroalkylethyl stearate; andmelt extruding the mixture.Type: GrantFiled: August 14, 1998Date of Patent: May 16, 2000Assignee: E. I. du Pont de Nemours and CompanyInventors: Kimberly Gheysen Raiford, Theodor Arthur Liss, Edward James Greenwood
-
Patent number: 5977390Abstract: Fluorinated diesters useful for imparting repellency of low surface tension fluids to thermoplastic polymers of formulaeR.sub.f --O--C(O)--(CH.sub.2).sub.n --C(O)--O--R.sub.1 ;R.sub.f --O--C(O)--CH.sub.2 --CH(R.sub.2)--C(O)--O--R.sub.f ;a mixture of R.sub.f --O--C(O)--(CH.sub.2).sub.n --C(O)--O--R.sub.1,R.sub.f --O--C(O)--(CH.sub.2).sub.n --C(O)--R.sub.f, and R.sub.1 --O--C(O)--(CH.sub.2).sub.n --C(O)--O--R.sub.1 ;and [F(CF.sub.2).sub.x CH.sub.2 CH.sub.2 --S--CH.sub.2 ].sub.2 --C--[CH.sub.2 --O--C(O)--C.sub.17 H.sub.35 ].sub.2 ;wherein R.sub.f is F(CF.sub.2).sub.x --(CH.sub.2).sub.m wherein x is 4 to 20 and m is 2 to 6, or F(CF.sub.2).sub.x --SO.sub.2 N(R.sub.3)--R.sub.4 wherein x is 4 to 20; R.sub.1 is a saturated aliphatic hydrocarbon with an average carbon chain length of 12 to 66 carbons; R.sub.2 is a saturated or unsaturated hydrocarbon with 1-20 carbon atoms; R.sub.3 is an alkyl radical having 1 to 4 carbon atoms; R.sub.Type: GrantFiled: May 14, 1997Date of Patent: November 2, 1999Assignee: E. I. du Pont de Nemours and CompanyInventors: Kimberly Gheysen Raiford, Theodor Arthur Liss, Edward James Greenwood, Jack Robert Kirchner
-
Patent number: 5898046Abstract: A composition having repellency to low surface tension fluids comprising a material prepared by forming a mixture of a polymer selected from the group consisting of polyolefin, polyamide, polyester, polyacrylate, and blends and copolymers thereof, and a fluorochemical compound comprising a fluorocarbon/hydrocarbon ester of the formulae:R.sub.f --O--C(O)--R.sub.1 or R.sub.f --C(O)--O--R.sub.1whereinR.sub.f is selected from the group consisting of:1) F(CF.sub.2).sub.x --(CH.sub.2).sub.m wherein x is from about 4 to about 20 and m is from about 0 to about 6; and2) F(CF.sub.2).sub.x --SO.sub.2 N(R.sub.2)--R.sub.3 where x is a positive integer from about 4 to about 20, R.sub.2 is an alkyl radical of from about 1 to about 4 carbon atoms, R.sub.3 is an alkylene radical of from about 1 to about 12 carbon atoms; andR.sub.1 is an aliphatic hydrocarbon having from about 12 to about 76 carbon atoms; andprovided that said fluorochemical compound is other than perfluoroalkylethyl stearate; andmelt extruding the mixture.Type: GrantFiled: October 7, 1997Date of Patent: April 27, 1999Assignee: E. I. du Pont de Nemours and CompanyInventors: Kimberly Gheysen Raiford, Theodor Arthur Liss, Edward James Greenwood
-
Patent number: 5798402Abstract: Compositions and processes for imparting repellency to low surface tension fluids in thermoplastic polymers, said compositions containing compounds of formulae R.sub.f SO.sub.2 (CH.sub.2).sub.n C(O).sub.2 OR, RSO.sub.2 (CH.sub.2).sub.n C(O)OR.sub.f and R.sub.f SO.sub.2 R wherein R.sub.f is F(CF.sub.2).sub.x --(CH.sub.2).sub.m wherein x is 4 to 20 and m is 2 to 6, R is a saturated aliphatic hydrocarbon with an average carbon chain length of 12 to 66 carbons; and n is 1 to 4 are disclosed.Type: GrantFiled: December 21, 1995Date of Patent: August 25, 1998Assignee: E. I. du Pont de Nemours and CompanyInventors: Patrick Henry Fitzgerald, Kimberly Gheysen Raiford, Edward James Greenwood
-
Patent number: 5789491Abstract: Fluorinated imides useful for imparting repellency of low surface tension fluids to thermoplastic polymers of formulae ##STR1## wherein R.sub.1 is F(CF.sub.2).sub.x --(CH.sub.2).sub.m, or F(CF.sub.2).sub.x SO.sub.2 N(R.sub.5)(CH.sub.2)p wherein x is from about 4 to about 20, m is from about 2 to about 6, p is from 1 to about 12, and R.sub.5 is an alkyl radical of from 1 to about 4 carbons;R.sub.2 is a linear, branched or cyclic alkylene or poly(oxyalkylene) hydrocarbon group having from about 2 to about 15 carbons;R.sub.3 is selected from the group consisting of F(CF.sub.2).sub.x --(CH.sub.2).sub.m, F(CF.sub.2).sub.x --(CH.sub.2).sub.m --OC(O)--(CH.sub.2).sub.n, and F(CF.sub.2).sub.x SO.sub.2 N(R.sub.5)(CH.sub.2).sub.p OC(O)(CH.sub.2).sub.nwherein x is from about 4 to about 20, m is from about 2 to about 6, n is about 2 to about 12, p is from 1 to about 12, and R.sub.5 is an alkyl radical of from 1 to about 4 carbons;R.sub.4 is an alkyl or alkenyl group of from about 4 to about 20 carbons, andR.sub.Type: GrantFiled: June 19, 1997Date of Patent: August 4, 1998Assignee: E. I. du Pont de Nemours and CompanyInventors: Theodor Arthur Liss, Kimberly Gheysen Raiford, Edward James Greenwood