Abstract: An engine exhaust purification device comprises: a selective reduction type NOx catalyst; an oxidation catalyst disposed on an upstream side of the NOx catalyst; a reducing agent adding device which adds an NOx reducing agent to an exhaust gas of an engine; a control device which controls the reducing agent adding device; and an NO2 ratio calculation device which estimates an NO2 ratio of the exhaust gas flowing into the NOx catalyst. The NO2 ratio of the exhaust gas flowing into the NOx catalyst is calculated by a catalytic reaction model where the oxidation reaction of NO in the oxidation catalyst is numerically formulated, and the NO2 ratio is reflected to calculate an amount of ammonia adsorbed on the NOx catalyst by a catalytic reaction model where a chemical reaction concerned with the reduction of NOx in the NOx catalyst is numerically formulated.

Abstract: In order to maintain a high NOx purification rate of a NOx reduction catalytic converter even in the case in which an NOx emission amount from an engine changes suddenly, in an exhaust emission purifying apparatus for an engine that reduces and purifies NOx in exhaust gas using ammonia generated from an injection-supplied urea aqueous solution, after engine starting, when an exhaust temperature exceeds a predetermined temperature T (step S1), an amount of urea aqueous solution corresponding to an actual engine operating state is injection-supplied (steps S3 to S5). On the other hand, at a change of the transmission speed ratio based on a driver's shift operation, an engine operating state after the change of the transmission speed ratio is predicted (steps S2, S6), and an amount of urea aqueous solution corresponding to the predicted engine operating state is injection-supplied before the change of the transmission speed ratio is completed (steps S7, S8).

Abstract: In an exhaust filter, a urea hydrolysis catalyst is supported on a first portion of an inner wall of a cell passage on the inlet side, and a first NOx reducing catalyst is supported on a second portion of the inner wall of the inlet-side passage downstream of the first portion. A second NOx reducing catalyst is supported on a third portion of an inner wall of a cell passage on the outlet side where the third portion overlaps with the first portion in a direction of intersection with the exhaust flow into the exhaust filter or is downstream of the first portion. An oxidation catalyst is supported on a fourth portion of the inner wall of the outlet-side passage downstream of the third portion where the fourth portion overlaps with the second portion in the direction of intersection or is downstream of the second portion.

Abstract: In an exhaust emission purifying apparatus for an internal combustion engine, for adding a reducing agent for NOx to the exhaust gas to thereby purify NOx in the exhaust gas, the mixing of the reducing agent injected by an injection nozzle with the exhaust gas is accelerated. To this end, in the apparatus of the present invention, the injection nozzle for the urea water is disposed to be opposite to the flow of the exhaust gas, or to face upward in a vertical direction.

Abstract: In an exhaust gas purification apparatus for an engine includes a bubble generation device, the bubble generation device for mixing nano-sized to micro-sized bubbles into a liquid reducing agent or a precursor thereof injection-supplied from an injection nozzle is disposed in a reducing agent supply system running from a reducing agent tank to the injection nozzle. When the liquid reducing agent or the precursor thereof is injection-supplied from the injection nozzle, the liquid reducing agent or the precursor thereof is divided by bubbles, and the bubbles are radically inflated and burst by a pressure change and a temperature change at the time of injection-supplying, so that microparticulation of the liquid reducing agent or the precursor thereof is facilitated.

Abstract: An engine exhaust purification device comprises: a selective reduction type NOx catalyst; an oxidation catalyst disposed on an upstream side of the NOx catalyst; a reducing agent adding device which adds an NOx reducing agent to an exhaust gas of an engine; a control device which controls the reducing agent adding device; and an NO2 ratio calculation device which estimates an NO2 ratio of the exhaust gas flowing into the NOx catalyst. The NO2 ratio of the exhaust gas flowing into the NOx catalyst is calculated by a catalytic reaction model where the oxidation reaction of NO in the oxidation catalyst is numerically formulated, and the NO2 ratio is reflected to calculate an amount of ammonia adsorbed on the NOx catalyst by a catalytic reaction model where a chemical reaction concerned with the reduction of NOx in the NOx catalyst is numerically formulated.

Abstract: In an exhaust filter, a urea hydrolysis catalyst is supported on a first portion of an inner wall of a cell passage on the inlet side, and a first NOx reducing catalyst is supported on a second portion of the inner wall of the inlet-side passage downstream of the first portion. A second NOx reducing catalyst is supported on a third portion of an inner wall of a cell passage on the outlet side where the third portion overlaps with the first portion in a direction of intersection with the exhaust flow into the exhaust filter or is downstream of the first portion. An oxidation catalyst is supported on a fourth portion of the inner wall of the outlet-side passage downstream of the third portion where the fourth portion overlaps with the second portion in the direction of intersection or is downstream of the second portion.

Abstract: An engine exhaust emission purification apparatus for reducing and purifying NOx in the exhaust emission by using a liquid reducing agent having a temperature maintenance device for maintaining a temperature of at least a part of a liquid reducing agent supply system configured by an injection nozzle and piping of the injection nozzle at a temperature lower than a boiling point of a solvent of the liquid reducing agent or equal to or higher than a melting point of dissolved matter in which the liquid reducing agent existing in the liquid reducing agent supply system conducts heat exchange with the liquid reducing agent supply system thereby being maintained at a temperature lower than the boiling point of the solvent or equal to or higher than the melting point of the dissolved matter and resultantly, occurrence of precipitation of the dissolved matter due to evaporation of only the solvent in the liquid reducing agent supply system does not occur, and even if precipitation of the dissolved matter occurs, the

Abstract: An exhaust gas pressure P, exhaust gas temperatures TU and TD on upstream and downstream of a DPF, a rotation speed Ne, a load Q, and an intake flow rate F as various operating conditions are read, and an amount of PM generated for short time ?t is obtained to be added to a PM deposited amount m, and thus, to obtain an initial deposited amount. Exhaust gas properties and a space velocity SV are obtained based on various operating conditions, and the PM deposited amount m after a lapse of the short time ?t is estimated from a PM deposited amount estimation equation “m=m·exp(?B·?t)” having been derived considering the exhaust gas properties and the space velocity SV. When the PM deposited amount m is equal to or more than a predetermined value, a forced regeneration processing in the DPF is executed, and thereafter, the PM deposited amount m is reset to 0.

Abstract: The present invention provides an exhaust emission purifying apparatus. In the exhaust emission purifying apparatus, while an ammonia adsorbent is coated on a predetermined length portion on the exhaust inflow side of a carrier of a catalytic converter which reduces and purifies NOx in exhaust gas, a NOx reduction catalyst is coated on the remaining portion on the exhaust outflow side of the carrier of the catalytic converter. On the other hand, a first layer containing the ammonia adsorbent and the NOx reduction catalyst in a mixed state and a second layer containing a hydrolysis catalyst are coated in that order on a carrier surface of the catalytic converter. In a transition of an engine operation state, NOx is reduced and purified with the use of ammonia adsorbed to the ammonia adsorbent.

Abstract: In order to maintain a high NOx purification rate of a NOx reduction catalytic converter even in the case in which an NOx emission amount from an engine changes suddenly, in an exhaust emission purifying apparatus for an engine that reduces and purifies NOx in exhaust gas using ammonia generated from an injection-supplied urea aqueous solution, after engine starting, when an exhaust temperature exceeds a predetermined temperature T (step S1), an amount of urea aqueous solution corresponding to an actual engine operating state is injection-supplied (steps S3 to S5). On the other hand, at a change of the transmission speed ratio based on a driver's shift operation, an engine operating state after the change of the transmission speed ratio is predicted (steps S2, S6), and an amount of urea aqueous solution corresponding to the predicted engine operating state is injection-supplied before the change of the transmission speed ratio is completed (steps S7, S8).

Abstract: In order to suppress deposition of constituent of a reducing agent (dissolved matter) in an exhaust passage of an engine enhancing an elimination rate of NOx even when temperature of an exhaust emission from the engine is low, an exhaust emission purifying apparatus is provided with an electro-generative-heat carrier provided on an upstream side of an injection nozzle that supplies the reducing agent into the exhaust emission on upstream side of a reduction catalyst in an exhaust pipe, the exhaust emission being heated to a temperature equal to or higher than a melting point of the dissolved matter whereby deposition of the dissolved matter on an inner wall surface of the exhaust pipe is suppressed to effectively use the supplied reducing agent for catalytic reduction reaction, even when the exhaust emission temperature is lower than the melting point of the dissolved matter of the reducing agent.

Abstract: In an exhaust emission purifying apparatus for an internal combustion engine, for adding a reducing agent for NOx to the exhaust gas to thereby purify NOx in the exhaust gas, the mixing of the reducing agent injected by an injection nozzle with the exhaust gas is accelerated. To this end, in the apparatus of the present invention, the injection nozzle for the urea water is disposed to be opposite to the flow of the exhaust gas, or to face upward in a vertical direction.

Abstract: In relation to an exhaust gas purification system that mixes a liquid reducing agent with air and injection-supplies this mixture into an exhaust gas flowing on an upstream side of a reduction catalyst (20) to thereby effect reduction purification of NOx in exhaust gas, a technical attention is directed to the relation of respective elements of; the travel distance, the fuel consumption, the air consumption, or the running time and the like, and the liquid reducing agent consumption, to constitute a configuration such that a continual monitor as to whether the injection condition of liquid reducing agent is normal or abnormal is executed by judging whether or not the amount of liquid reducing agent consumed for a predetermined travel distance, a predetermined fuel consumption, a predetermined air consumption, or a predetermined running time, is within a predetermined range.

Abstract: In an exhaust gas purification apparatus for an engine includes a bubble generation device, the bubble generation device for mixing nano-sized to micro-sized bubbles into a liquid reducing agent or a precursor thereof injection-supplied from an injection nozzle is disposed in a reducing agent supply system running from a reducing agent tank to the injection nozzle. When the liquid reducing agent or the precursor thereof is injection-supplied from the injection nozzle, the liquid reducing agent or the precursor thereof is divided by bubbles, and the bubbles are radically inflated and burst by a pressure change and a temperature change at the time of injection-supplying, so that microparticulation of the liquid reducing agent or the precursor thereof is facilitated.

Abstract: A DPF disposed in an exhaust passage of a diesel engine is coated with a selective reducing catalyst, for selectively reducing and purifying NOx by using a reducing agent, and a thin film, having fine pores of size for allowing passage of the NOx and preventing passage of PM, in this order. In regeneration treatment of a DPF, the thin film prevents direct transmission of combustion heat of the PM to the selective reducing catalyst and suppresses a temperature rise of the selective reducing catalyst to thereby suppress deterioration of an active component.

Abstract: In an exhaust emission purifying apparatus for an internal combustion engine, for adding a reducing agent for NOx to the exhaust gas to thereby purify NOx in the exhaust gas, the mixing of the reducing agent injected by an injection nozzle with the exhaust gas is accelerated. To this end, in the apparatus of the present invention, the injection nozzle for the urea water is disposed to be opposite to the flow of the exhaust gas, or to face upward in a vertical direction.

Abstract: In an exhaust emission purifying apparatus for an internal combustion engine, for adding a reducing agent for NOx to the exhaust gas to thereby purify NOx in the exhaust gas, the mixing of the reducing agent injected by an injection nozzle with the exhaust gas is accelerated. To this end, in the apparatus of the present invention, the injection nozzle for the urea water is disposed to be opposite to the flow of the exhaust gas, or to face upward in a vertical direction.

Abstract: A NOx reduction catalyst and an ammonia slip oxidation catalyst are disposed in an exhaust system in this order, and also, an electric fan is disposed on piping which communicates an upper space of a storage tank storing therein a reducing agent with the exhaust upstream of the NOx reduction catalyst. Then, when the temperature of the ammonia slip oxidation catalyst reaches or exceeds the temperature for activating a catalyst thereof, the electric fan is operated for a predetermined period of time, so that the gas (ammonia series gas) in the upper space of the storage tank is forcibly discharged to the upstream side of the NOx reduction catalyst. Further, a discharge-forcing device, such as an electric fan or the like, forcibly discharging the gas in the upper space of the storage tank, an adsorbing device temporarily adsorbing thereto the forcibly discharged gas and an oxidation catalyst oxidizing the gas desorbed from the adsorbing device, may be disposed to the storage tank in this order.

Abstract: An exhaust gas pressure P, exhaust gas temperatures TU and TD on upstream and downstream of a DPF, a rotation speed Ne, a load Q, and an intake flow rate F as various operating conditions are read, and an amount of PM generated for short time ?t is obtained to be added to a PM deposited amount m, and thus, to obtain an initial deposited amount. Exhaust gas properties and a space velocity SV are obtained based on various operating conditions, and the PM deposited amount m after a lapse of the short time ?t is estimated from a PM deposited amount estimation equation “m=m·exp(?B·?t)” having been derived considering the exhaust gas properties and the space velocity SV. When the PM deposited amount m is equal to or more than a predetermined value, a forced regeneration processing in the DPF is executed, and thereafter, the PM deposited amount m is reset to 0.