Patents by Inventor Kiu-Seung Lee

Kiu-Seung Lee has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 10301747
    Abstract: The invention concerns fiber, and a process for making same, the fiber comprising a mixture of at least a first polymer and a second polymer, the first polymer having a structure derived from the reaction of one or more amine monomers and a plurality of acid monomers, wherein the one or more amine monomers includes at least 60 mole percent 5(6)-amino-2-(p-aminophenyl)benzimidazole, and the plurality of acid monomers include those having a structure of Cl—CO—Ar1—CO—Cl and Cl—CO—Ar2—CO—Cl wherein Ar1 is an aromatic group having para-oriented linkages and Ar2 is an aromatic group having meta-oriented linkages, and wherein the plurality of acid monomers has at least 50 mole percent of the monomer containing aromatic group Ar2; and the second polymer has a structure derived from the reaction of metaphenylene diamine and isophthaloyl chloride. This fiber has use in heat-resistant protective apparel fabrics and garments.
    Type: Grant
    Filed: October 29, 2014
    Date of Patent: May 28, 2019
    Assignee: E I DU PONT DE NEMOURS AND COMPANY
    Inventor: Kiu-Seung Lee
  • Patent number: 9790366
    Abstract: A composite polymer solution comprising a homogeneous mixture of a first polymer solution comprising a first polymer having a structure derived from the reaction of one or more amine monomers and a plurality of acid monomers, wherein i) the one or more amine monomers includes at least 60 mole percent 5(6)-amino-2-(p-aminophenyl)benzimidazole; and ii) the plurality of acid monomers include those having a structure of Cl—CO—Ar1—CO—Cl and Cl—CO—Ar2—CO—Cl wherein Ar1 is a para-oriented aromatic group and Ar2 is a meta-oriented aromatic group, and wherein the plurality of acid monomers has at least 50 mole percent of the monomer containing Ar2; and a second polymer solution comprising a second polymer having a structure derived from the reaction of metaphenylene diamine and isophthaloyl chloride.
    Type: Grant
    Filed: October 29, 2014
    Date of Patent: October 17, 2017
    Assignee: E I DU PONT DE NEMOURS AND COMPANY
    Inventor: Kiu-Seung Lee
  • Patent number: 9663875
    Abstract: This invention relates to a sheet comprising fibers and fibrids wherein either comprises a mixture of at least a first polymer and a second polymer; the first polymer derived from the reaction of one or more amine monomers and a plurality of acid monomers, wherein the one or more amine monomers includes at least 60 mole percent 5(6)-amino-2-(p-aminophenyl)benzimidazole, based on the total amount of amine monomers; and the plurality of acid monomers include those having a structure of Cl—CO—Ar1—CO—Cl & Cl—CO—Ar2—CO—Cl wherein Ar1 is an aromatic group having para-oriented linkages and Ar2 is an aromatic group having meta-oriented linkages, and wherein the plurality of acid monomers has at least 50 mole percent of the monomer containing aromatic group Ar2; and the second polymer derived from the reaction of metaphenylene diamine and isophthaloyl chloride.
    Type: Grant
    Filed: October 29, 2014
    Date of Patent: May 30, 2017
    Assignee: EI DU PONT DE NEMOURS AND COMPANY
    Inventor: Kiu-Seung Lee
  • Patent number: 9193841
    Abstract: This invention relates to a film comprising a mixture of at least a first polymer and a second polymer; the first polymer derived from the reaction of one or more amine monomers and a plurality of acid monomers, wherein the one or more amine monomers includes at least 60 mole percent 5(6)-amino-2-(p-aminophenyl)benzimidazole, based on the total amount of amine monomers; and the plurality of acid monomers include those having a structure of Cl—CO—Ar1—CO—Cl & Cl—CO—Ar2—CO—Cl wherein Ar1 is an aromatic group having para-oriented linkages and Ar2 is an aromatic group having meta-oriented linkages, and wherein the plurality of acid monomers has at least 50 mole percent of the monomer containing aromatic group Ar2; and the second polymer derived from the reaction of metaphenylene diamine and isophthaloyl chloride.
    Type: Grant
    Filed: October 29, 2014
    Date of Patent: November 24, 2015
    Assignee: E I DU PONT DE NEMOURS AND COMPANY
    Inventor: Kiu-Seung Lee
  • Patent number: 9127143
    Abstract: The invention concerns polymer powder comprising 2-(4-amino phenyl)-5 (6) amino benzimidazole (DAPBI), paraphenylene diamine, and terephthaloyl dichloride, capable of being dissolved in a solvent system comprising (i) N-methyl-2-pyrrolidone (NMP) or dimethylacetamide (DMAC) and (ii) an inorganic salt; wherein said polymer is capable of being redissolved in said solvent system after said polymer has been removed from said solvent system.
    Type: Grant
    Filed: July 27, 2012
    Date of Patent: September 8, 2015
    Assignee: E I DU PONT DE NEMOURS AND COMPANY
    Inventor: Kiu-Seung Lee
  • Publication number: 20150119533
    Abstract: This invention relates to a film comprising a mixture of at least a first polymer and a second polymer; the first polymer derived from the reaction of one or more amine monomers and a plurality of acid monomers, wherein the one or more amine monomers includes at least 60 mole percent 5(6)-amino-2-(p-aminophenyl)benzimidazole, based on the total amount of amine monomers; and the plurality of acid monomers include those having a structure of Cl—CO—Ar1—CO—Cl & Cl—CO—Ar2—CO—Cl wherein Ar1 is an aromatic group having para-oriented linkages and Ar2 is an aromatic group having meta-oriented linkages, and wherein the plurality of acid monomers has at least 50 mole percent of the monomer containing aromatic group Ar2; and the second polymer derived from the reaction of metaphenylene diamine and isophthaloyl chloride.
    Type: Application
    Filed: October 29, 2014
    Publication date: April 30, 2015
    Inventor: KIU-SEUNG LEE
  • Publication number: 20150113714
    Abstract: The invention concerns fiber, and a process for making same, the fiber comprising a mixture of at least a first polymer and a second polymer, the first polymer having a structure derived from the reaction of one or more amine monomers and a plurality of acid monomers, wherein the one or more amine monomers includes at least 60 mole percent 5(6)-amino-2-(p-aminophenyl)benzimidazole, and the plurality of acid monomers include those having a structure of Cl—CO—Ar1-CO—Cl & Cl—CO—Ar2-CO—Cl wherein Ar1 is an aromatic group having para-oriented linkages and Ar2 is an aromatic group having meta-oriented linkages, and wherein the plurality of acid monomers has at least 50 mole percent of the monomer containing aromatic group Ar2; and the second polymer has a structure derived from the reaction of metaphenylene diamine and isophthaloyl chloride. This fiber has use in heat-resistant protective apparel fabrics and garments.
    Type: Application
    Filed: October 29, 2014
    Publication date: April 30, 2015
    Inventor: Kiu-Seung LEE
  • Publication number: 20150119511
    Abstract: A composite polymer solution comprising a homogeneous mixture of at least a first polymer solution and a second polymer solution; the first polymer solution comprising an amide solvent and a first polymer having a structure derived from the reaction of one or more amine monomers and a plurality of acid monomers, wherein i) the one or more amine monomers includes at least 60 mole percent 5(6)-amino-2-(p-aminophenyl)benzimidazole, based on the total amount of amine monomers; and ii) the plurality of acid monomers include those having a structure of Cl—CO—Ar1—CO—Cl & Cl—CO—Ar2—CO—Cl wherein Ar1 is a para-oriented aromatic group and Ar2 is a meta-oriented aromatic group, and wherein the plurality of acid monomers has at least 50 mole percent of the monomer containing aromatic group Ar2; and the second polymer solution comprising an amide solvent and a second polymer having a structure derived from the reaction of metaphenylene diamine and isophthaloyl chloride.
    Type: Application
    Filed: October 29, 2014
    Publication date: April 30, 2015
    Inventor: KIU-SEUNG LEE
  • Publication number: 20150114582
    Abstract: This invention relates to a sheet comprising fibers and fibrids wherein either comprises a mixture of at least a first polymer and a second polymer; the first polymer derived from the reaction of one or more amine monomers and a plurality of acid monomers, wherein the one or more amine monomers includes at least 60 mole percent 5(6)-amino-2-(p-aminophenyl)benzimidazole, based on the total amount of amine monomers; and the plurality of acid monomers include those having a structure of Cl—CO—Ar1—CO—Cl & Cl—CO—Ar2—CO—Cl wherein Ar1 is an aromatic group having para-oriented linkages and Ar2 is an aromatic group having meta-oriented linkages, and wherein the plurality of acid monomers has at least 50 mole percent of the monomer containing aromatic group Ar2; and the second polymer derived from the reaction of metaphenylene diamine and isophthaloyl chloride.
    Type: Application
    Filed: October 29, 2014
    Publication date: April 30, 2015
    Inventor: KIU-SEUNG LEE
  • Patent number: 8907051
    Abstract: The invention concerns processes for forming a polymer comprising residues of 2-(4-amino phenyl)-5(6) amino benzimidazole (DAPBI), paraphenylene diamine (PPD), and terephthaloyl dichloride, comprising the steps of: (a) forming a solution of oligomers having amine end groups from two moles of DAPBI and one mole of terephthaloyl dichloride in a solvent system comprising an organic solvent and an inorganic salt; (b) adding PPD to the solution of oligomers; and (c) adding additional terephthaloyl dichloride to form a polymer.
    Type: Grant
    Filed: July 27, 2012
    Date of Patent: December 9, 2014
    Assignee: E I du Pont de Nemours and Company
    Inventor: Kiu-Seung Lee
  • Patent number: 8907052
    Abstract: The invention concerns processes for forming a polymer comprising residues of 2-(4-amino phenyl)-5(6)amino benzimidazole (DAPBI), paraphenylene diamine (PPD), and terephthaloyl dichloride, comprising the steps of: (a) forming a slurry of DAPBI in a solvent system comprising an organic solvent and an inorganic salt; (b) adding less than a stoichiometric amount, relative to the amount of DAPBI, of terephthaloyl dichloride to the slurry; (c) agitating the slurry to react the DAPBI and terephthaloyl dichloride to form an oligomeric solution; (d) adding PPD to the oligomeric solution and agitating until essentially all of the PPD is dissolved, followed by the addition of terephthaloyl dichloride to form a prepolymer solution; and (e) allowing the prepolymer solution to form a polymer.
    Type: Grant
    Filed: July 27, 2012
    Date of Patent: December 9, 2014
    Assignee: E I du Pont de Nemours and Company
    Inventor: Kiu-Seung Lee
  • Patent number: 8835600
    Abstract: The invention concerns processes for forming a polymer comprising residues of 2-(4-amino phenyl)-5 (6) amino phenyl benzimidazole (DAPBI), paraphenylene diamine, and terephthaloyl dichloride, comprising the steps of: a) forming a solution of DAPBI and paraphenylene diamine dihydrochloride in a solvent system comprising an organic solvent and an inorganic salt; b) cooling the solution to a temperature of 30° C. or less; c) adding a stoichiometric amount of terephthaloyl dichloride, relative to the total amount of the DAPBI and the paraphenylene diamine dihydrochloride, to the solution; and d) agitating the solution of step c) to form a polymer.
    Type: Grant
    Filed: July 27, 2012
    Date of Patent: September 16, 2014
    Assignee: E I du Pont de Nemours and Company
    Inventor: Kiu-Seung Lee
  • Patent number: 8822632
    Abstract: The invention concerns processes for forming a polymer comprising residues of 2-(4-amino phenyl)-5 (6) amino benzimidazole (DAPBI), paraphenylene diamine, and terephthaloyl dichloride, the process comprising: (a) forming a solution of oligomers having chloride end groups from one mole of paraphenylene diamine and 1.3 to 5 moles of terephthaloyl dichloride a solvent system comprising an organic solvent and an inorganic salt; and (b) adding DAPBI and terephthaloyl dichloride to the solution of oligomers to form a polymer.
    Type: Grant
    Filed: July 27, 2012
    Date of Patent: September 2, 2014
    Assignee: E I du Pont de Nemours and Company
    Inventor: Kiu-Seung Lee
  • Patent number: 8809434
    Abstract: The invention concerns processes for forming a polymer comprising residues of terephthaloyl chloride, paraphenylene diamine, and a salt of formula I wherein A? is a halogen anion, HSO4?, OH?, NO3?, C2H3O2?, or H2PO4?; the process comprising the steps of: a) forming a mixture comprising salt of formula I and paraphenylene diamine in a solvent system comprising an organic solvent and an inorganic salt; and b) adding terephthaloyl chloride to the mixture and allowing the formation of the polymer.
    Type: Grant
    Filed: July 27, 2012
    Date of Patent: August 19, 2014
    Assignee: EI du Pont de Nemours and Company
    Inventor: Kiu-Seung Lee
  • Patent number: 8716433
    Abstract: The invention concerns polymer comprising residues of 2-(4-amino phenyl)-5 (6) amino benzimidazole (DAPBI), paraphenylene diamine, and terephthaloyl dichloride, the polymer having a IPC peak block ratio of 1.45 to 1.47 and an inherent viscosity of greater than 2 dl/g.
    Type: Grant
    Filed: July 27, 2012
    Date of Patent: May 6, 2014
    Assignee: E I du Pont de Nemours and Company
    Inventor: Kiu-Seung Lee
  • Patent number: 8716431
    Abstract: The invention concerns processes for forming a polymer comprising residues of 2-(4-amino phenyl)-5(6)amino benzimidazole (DAPBI), paraphenylene diamine, and terephthaloyl dichloride, comprising the steps of: (a) forming a slurry of DAPBI and paraphenylene diamine in a solvent system comprising an organic solvent and an inorganic salt; and (b) adding a stoichiometric amount of terephthaloyl dichloride to the slurry in a single addition and allowing the formation of the polymer.
    Type: Grant
    Filed: July 27, 2012
    Date of Patent: May 6, 2014
    Assignee: E I du Pont de Nemours and Company
    Inventor: Kiu-Seung Lee
  • Patent number: 8716432
    Abstract: The invention concerns processes for forming a polymer comprising residues of 2-(4-amino phenyl)-5(6) amino benzimidazole (DAPBI), paraphenylene diamine (PPD), and terephthaloyl dichloride, comprising the steps of: (a) forming a slurry of DAPBI in a solvent system comprising an organic solvent and an inorganic salt; (b) adding terephthaloyl dichloride to the slurry terephthaloyl dichloride in the amount of up to one-half mole for every mole of DAPBI in the slurry; (c) agitating the slurry to react the DAPBI and terephthaloyl dichloride to form an oligomeric solution; (d) adding PPD to the oligomeric solution and agitating until substantially all of the PPD is dissolved, (e) adding terephthaloyl dichloride in an amount of greater than one mole for every mole of PPD in the solution to form a prepolymer solution; and (e) agitating the prepolymer solution to form a polymer.
    Type: Grant
    Filed: July 27, 2012
    Date of Patent: May 6, 2014
    Assignee: E I du Pont de Nemours and Company
    Inventor: Kiu-Seung Lee
  • Patent number: 8716434
    Abstract: The invention concerns polymer comprising 2-(4-amino phenyl)-5 (6) amino benzimidazole (DAPBI), PPD, and terephthaloyl dichloride, the polymer having a IPC peak block ratio of 1.52 to 1.56 and an inherent viscosity of greater than 2 dl/g.
    Type: Grant
    Filed: July 27, 2012
    Date of Patent: May 6, 2014
    Assignee: E I du Pont de Nemours and Company
    Inventor: Kiu-Seung Lee
  • Publication number: 20130261239
    Abstract: The invention concerns processes for forming a polymer comprising residues of 2-(4-amino phenyl)-5(6) amino phenyl benzimidazole (DAPBI), paraphenylene diamine (PPD), and terephthaloyl dichloride, comprising the steps of: (a) forming a solution of oligomers having amine end groups from two moles of DAPBI and one mole of terephthaloyl dichloride in a solvent system comprising an organic solvent and an inorganic salt; (b) adding PPD to the solution of oligomers; and (c) adding additional terephthaloyl dichloride to form a polymer.
    Type: Application
    Filed: July 27, 2012
    Publication date: October 3, 2013
    Applicant: E.I. DU PONT DE NEMOURS AND COMPANY
    Inventor: KIU-SEUNG LEE
  • Publication number: 20130261258
    Abstract: The invention concerns polymer powder comprising 2-(4-amino phenyl)-5(6) amino phenyl benzimidazole (DAPBI), paraphenylene diamine, and terephthaloyl dichloride, capable of being dissolved in a solvent system comprising (i) N-methyl-2-pyrrolidone (NMP) or dimethylacetamide (DMAC) and (ii) an inorganic salt; wherein said polymer is capable of being redissolved in said solvent system after said polymer has been removed from said solvent system.
    Type: Application
    Filed: July 27, 2012
    Publication date: October 3, 2013
    Applicant: E I DU PONT DE NEMOURS AND COMPANY
    Inventor: KIU-SEUNG LEE