Abstract: An adhesive article including a tie layer and a silicone adhesive is disclosed. The tie layer includes a segmented copolymer having a first segment that is one of (a) a polyether comprising one of PTMO or PEO/PPO or (b) a polysiloxane. The segmented copolymer has a water absorbency of less than about 13%.

Abstract: A method of making a silicone gel adhesive is described comprising providing an acrylic polymer, the acrylic polymer comprising at least 50 wt.-% of polymerized units of C1-C32 (meth)acrylate ester monomer; providing at least one non-functional polydiorganosiloxane, hydroxy-functional polydiorganosiloxane, or a mixture thereof; combining the acrylic polymer and polydiorganosiloxane into a mixture; coating the mixture onto a substrate, and subjecting the mixture to radiation thereby crosslinking the mixture. Also described is a silicone gel adhesive comprising a crosslinked material at least one non-functional polydiorganosiloxane, hydroxy-functional polydiorganosiloxane, or a mixture thereof; and an acrylic polymer comprising at least 50 wt.-% of polymerized units of alkyl (meth)acrylate monomers and a gel content of at least 20 wt.-%.

Abstract: Provided are adhesive articles that include a silicone adhesive and a substrate, with a primer layer interposed between the silicone adhesive and the substrate. The primer layer includes a polymer having a polyorganosiloxane pendant group P represented by the formula (I) where each R1 is independently an alkyl, haloalkyl, arylalkyl, alkenyl, aryl, or aryl substituted with an alkyl, alkoxy, or halo; R2 is an alkyl or an alkenyl group; R3 is an alkylene or an arylalkylene group; and n is an integer in the range of 1 to 20. The primer layer typically improves the adhesion between the silicone adhesive and a wide variety of substrates.

Abstract: Blend compositions include at least one polydiorganosiloxane polyoxamide copolymer, and at least 70% by weight of at least one silicone tackifying resin. The blend composition is non-tacky at room temperature up to a temperature of at least 100° C. The polydiorganosiloxane polyoxamide copolymer can be a linear or branched copolymer. The blend compositions provide solid, non-powdery, and non-tacky delivery vehicles for silicone tackifying resin.

Abstract: The present disclosure provides an adhesive composition including a silicone-based adhesive and cellulose nanocrystals dispersed in the silicone-based adhesive. The present disclosure also provides an article including a substrate and a layer of the adhesive composition adhered to the substrate. Further, the present disclosure provides a method of making an adhesive composition. The method comprises mixing cellulose nanocrystals in a silicone-based adhesive to disperse the cellulose nanocrystals. The present disclosure additionally provides a method of making an article including disposing a layer of the adhesive composition on a substrate. The presence of the cellulose nanocrystals advantageously increases the water uptake capacity of the silicone-based adhesive while maintaining acceptable adhesive performance.

Abstract: An article, including a network of interconnected polymeric strands; wherein each of the interconnected polymeric strands has a first surface adapted to contact a tissue site and a second surface opposite the first surface; wherein at least one of the interconnected polymeric stand has a plurality of features extending from the first surface of the interconnected polymeric strands; wherein at least one of the interconnected polymeric strands is non-linear; a plurality of openings between adjacent interconnected polymeric strands; an adhesive layer in contact with the second surface of the interconnected polymeric strands; and a filler in contact with the adhesive layer, the adhesive layer in between the network of interconnected polymeric strands and the filler; wherein the article is a negative pressure wound therapy article.

Abstract: The present invention is adhesive article including a tie layer and a silicone adhesive. The tie layer includes a segmented copolymer having a first segment that is one of (a) a polyether comprising one of PTMO or PEO/PPO or (b) a polysiloxane. The segmented copolymer has a water absorbency of less than about 13%.

Abstract: The disclosed medical dressing has a dressing body and a flap. The dressing body has a first major surface and opposite second major surface containing a skin-contact adhesive. The flap has a fixed end integrally connected to the dressing body and a movable free end. The second major surface of the flap has a securing adhesive for contact with the first major surface of the dressing body.

Abstract: Blend compositions include at least one polydiorganosiloxane polyoxamide copolymer, and at least 70% by weight of at least one silicone tackifying resin. The blend composition is non-tacky at room temperature up to a temperature of at least 100° C. The polydiorganosiloxane polyoxamide copolymer can be a linear or branched copolymer. The blend compositions provide solid, non-powdery, and non-tacky delivery vehicles for silicone tackifying resin.

Abstract: Medical articles include a substrate with a layer of a siloxane-based gel adhesive composition. The gel adhesive composition includes a crosslinked polymeric siloxane matrix, and an extractable polymeric fluid with a weight average molecular weight greater than 275,000 grams/mole. The extractable polymeric fluid is 26-80 weight % of the gel adhesive composition. The gel adhesive composition may also include a siloxane tackifying resin.

Abstract: Tapes including an elastomeric backing layer having two major surfaces, wherein the backing layer includes a high temperature resistant elastomer (e.g., a high consistency silicone rubber elastomer), and a pressure sensitive adhesive layer, wherein the pressure sensitive adhesive layer comprises a silicone pressure sensitive adhesive.

Abstract: A method of making a silicone gel adhesive is described comprising providing an acrylic polymer, the acrylic polymer comprising at least 50 wt.-% of polymerized units of C1-C32 (meth)acrylate ester monomer; providing at least one non-functional polydiorganosiloxane, hydroxy-functional polydiorganosiloxane, or a mixture thereof; combining the acrylic polymer and polydiorganosiloxane into a mixture; coating the mixture onto a substrate, and subjecting the mixture to radiation thereby crosslinking the mixture. Also described is a silicone gel adhesive comprising a crosslinked material at least one non-functional polydiorganosiloxane, hydroxy-functional polydiorganosiloxane, or a mixture thereof; and an acrylic polymer comprising at least 50 wt.-% of polymerized units of alkyl (meth)acrylate monomers and a gel content of at least 20 wt.-%.

Abstract: An article, including a network of interconnected polymeric strands; wherein each of the interconnected polymeric strands has a first surface adapted to contact a tissue site and a second surface opposite the first surface; wherein at least one of the interconnected polymeric stand has a plurality of features extending from the first surface of the interconnected polymeric strands; wherein at least one of the interconnected polymeric strands is non-linear; a plurality of openings between adjacent interconnected polymeric strands; an adhesive layer in contact with the second surface of the interconnected polymeric strands; and a filler in contact with the adhesive layer, the adhesive layer in between the network of interconnected polymeric strands and the filler; wherein the article is a negative pressure wound therapy article.

Abstract: Described herein is a backing comprising a sorbent material entrapped in a non-woven fiber matrix, wherein the backing comprises a first and a second major surface; and a first adhesive layer contacting the first major surface of the backing, wherein the first adhesive layer comprises a pressure sensitive adhesive.

Abstract: The present disclosure provides an adhesive composition including a silicone-based adhesive and cellulose nanocrystals dispersed in the silicone-based adhesive. The present disclosure also provides an article including a substrate and a layer of the adhesive composition adhered to the substrate. Further, the present disclosure provides a method of making an adhesive composition. The method comprises mixing cellulose nanocrystals in a silicone-based adhesive to disperse the cellulose nanocrystals. The present disclosure additionally provides a method of making an article including disposing a layer of the adhesive composition on a substrate. The presence of the cellulose nanocrystals advantageously increases the water uptake capacity of the silicone-based adhesive while maintaining acceptable adhesive performance.

Abstract: Adhesive compositions are provided that contain a crosslink product resulting from exposure of a (meth)acrylic-based composition to electron beam radiation, gamma ray radiation, or both. More particularly, the (meth)acrylic-based composition includes a (meth)acrylic-based diblock copolymer and an optional (meth)acrylic-based triblock copolymer. These adhesive compositions are particularly well suited for application to biological surface such as skin.

Abstract: The disclosed medical dressing has a dressing body and a flap. The dressing body has a first major surface and opposite second major surface containing a skin-contact adhesive. The flap has a fixed end integrally connected to the dressing body and a movable free end. The second major surface of the flap comprises a securing adhesive for contact with the first major surface of the dressing body.

Abstract: A medical dressing (100) with a dressing body (102) and a flap (104). The flap can include a fixed end (120) coupled to the dressing body, and a free end (122) movable with respect to the dressing body between a first position and a second position in which the free end is positioned in overlapping relationship with the dressing body. A second major surface (116) of at least the free end of the flap can be configured to be secured to the dressing body, and the flap can be located toward a proximal end of the dressing body, such that a distal portion of the dressing body is free of the flap. The dressing body can be adhered to skin with a skin-contact adhesive (e.g., a silicone adhesive) (115), and the flap can be secured to the dressing body with a securing adhesive (e.g. an acrylate adhesive) (117) that can have a higher adhesion or adhesive strength.

Abstract: Blended, release materials containing crosslinked silicones, crosslinked fluorosilicones, and nonfunctional fluorosilicones are described. Articles including release liners and adhesive articles are also described, as are methods of making such blended release materials and articles incorporating them.

Abstract: Adhesive articles that include a substrate and a silicone adhesive are disclosed. The articles also include a polymer containing poly(propylene oxide) units and optionally poly(ethylene oxide) units and having a number average molecular weight of at least 1000 grams per mole. The polymer may either be incorporated into the substrate or may be used as a primer on the substrate. If the polymer includes poly(ethylene oxide) units, the copolymer typically has a weight ratio of poly(ethylene oxide) to poly(propylene oxide) of up to 3:1, or if the copolymer has a number average molecular weight of at least 10,000 grams per mole, the weight ratio of poly(ethylene oxide) to poly(propylene oxide) is up to 2:1. Methods of making the adhesive articles are also disclosed.