Patents by Inventor Kiyoshi Tsuru
Kiyoshi Tsuru has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 5792286Abstract: A high-strength thin plate, such as for IC lead frames, of an iron-nickel-cobalt alloy which is able to withstand repeated bending and is corrosion resistance and etchable, the alloy containing 27 to 30 wt. % N:, 5 to 18 wt. % Co, 0.10 to 3.0 wt. % Mn, 0.10 wt. % or less Si, 0.010 to 0.075 wt. % C, 0.001 to 0.014 wt. % N, less than 2.0 ppm H, 0.0040 wt. % or less S, 0.004 wt. % or less P, 0.0050 wt. % or less O, 0.01 to 0.06 wt. % Cr, 0.01 to 1.0 wt. % Mo and the balance being Fe and unavoidable impurities wherein 63.5 wt. %.ltoreq.2Ni+Co+Mn.ltoreq.65 wt. % for Co<10 wt. % and 69.5 wt. %.ltoreq.2Ni+Co+Mn.ltoreq.74.5 wt. % for Co>10 wt. %.Type: GrantFiled: March 20, 1995Date of Patent: August 11, 1998Assignee: NKK CorporationInventors: Tadashi Inoue, Kiyoshi Tsuru, Naotsugu Yamanouchi, Tomoyoshi Okita
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Patent number: 5669989Abstract: A Ni--Fe magnetic alloy consists essentially of: 77 to 80 wt. % Ni, 3.5 to 5 wt. % Mo, 1.5 to 3 wt. % Cu, 0.1 to 1.1 wt. % Mn, 0.1 wt. % or less Cr, 0.003 wt. % or less S, 0.01 wt. % or less P, 0.005 wt. % or less 0, 0.003 wt. % or less N, 0.02 wt. % or less C, 0.001 to 0.05 wt. % Al, 1 wt. % or less Si, 2.6-6 of the weight ratio of Ca to S, (Ca/S), and the balance being Fe and inevitable impurities, satisfies an equation of 3.2.ltoreq.(2.02.times.?Ni!-11.13.times.?Mo!-1.25.times.?Cu!-5.03.times.?M n!)/(2.13.times.?Fe!).ltoreq.3.8; and has a Mo segregation ratio defined by a seregration equation satisfying 5% or less, the seregration equation being .vertline.(Mo content in a segregation region-Mo average content)/(Mo average content).vertline..times.100%. A method for producing a magnetic Ni--Fe alloy comprises the steps of: a first heating step of heating an alloy ingot to 1200.degree. to 1300.degree. C. for 10 to 30 hrs; slabbing the heated ingot at a finishing temperature of 950.degree. C.Type: GrantFiled: October 19, 1995Date of Patent: September 23, 1997Assignee: NKK CorporationInventors: Tadashi Inoue, Kiyoshi Tsuru, Shinichi Okimoto, Naokazu Yamamura, Tetsuo Yamamoto, Hirohisa Haiji
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Patent number: 5637161Abstract: A method for manufacturing an alloy sheet for a shadow mask is provided which includes: (i) annealing a hot-rolled sheet containing Fe and Ni at a temperature of 910.degree. to 990.degree. C.; (ii) cold-rolling the annealed hot-rolled sheet from step (i) to produce a cold-rolled sheet; (iii) crystallization annealing of the cold-rolled sheet from step (ii); (iv) cold-rolling the annealed cold rolled sheet from step (iii); (v) finish recrystallization annealing step of the cold-rolled sheet of step (iv); (vi) finish cold-rolling of the sheet from step (v) at a cold-rolling reduction ratio R (%) satisfying the following equations: 16.ltoreq.R.ltoreq.75 and 6.38 D-133.9.ltoreq.R.ltoreq.6.38 D-51.0 wherein D is the average austenite grain size in .mu.m; (vii) softening annealing the sheet from step (vi) at a temperature of 720.degree. to 790.degree. C. for 2 to 40 minutes before press-forming and at conditions of temperature T in .degree.C. and time t in minutes which satisfy the following equation :T.gtoreq.-53.Type: GrantFiled: April 25, 1995Date of Patent: June 10, 1997Assignee: NKK CorporationInventors: Tadashi Inoue, Kiyoshi Tsuru, Michihito Hiasa, Tomoyoshi Okita
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Patent number: 5628841Abstract: A thin Fe--Ni alloy sheet for shadow mask consists essentially of Ni of 34 to 38 wt. %, Si of 0.05 wt. % or less, B of 0.0005 wt. % or less, O of 0.002 wt. % or less and N of 0.0015% or less, the balance being Fe and inevitable impurities; said alloy sheet after annealing before press-forming having 0.2% proof stress of 28.5 kgf/mm.sup.2 or less; and a degree of {211} plane on a surface of said alloy sheet being 16% or less. And further modified similar alloy sheets are also provided.Further, a method for producing a thin Fe--Ni alloy sheet for shadow mask comprises the steps of: (a) hot-rolling of a slab into a hot-rolled alloy strip; (b) hot-rolled sheet annealing of the hot-rolled strip at 910 to 990.degree. C.; (c) cold-rolling of the annealed hot-rolled strip into a cold-rolled strip; (d) recrystallization annealing of the cold-rolled strip; (e) finish cold-rolling of the recrystallization annealed strip at a finish cold reduction ratio in response to austenite grain size D(D.mu.Type: GrantFiled: January 21, 1994Date of Patent: May 13, 1997Assignee: NKK CorporationInventors: Tadashi Inoue, Kiyoshi Tsuru, Tomoyoshi Okita, Michihito Hiasa
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Patent number: 5620535Abstract: An alloy sheet for making a shadow mask consists essentially of 34 to 38 wt. % Ni, 0.07 wt. % or less Si, 0.002 wt. % or less B, 0.002 wt. % or less O, less than 0.002 wt. % N and the balance being Fe and inevitable impurities;said alloy sheet after annealing before press-forming having 0.2% proof stress of 28 kgf/mm.sup.2 or less; anda gathering degree of {211} plane being 16% or less.A method for manufacturing an alloy sheet comprises:a finish cold-rolling step of cold-rolling the cold-rolled sheet at a cold-rolling reduction ratio in response to an average austenite grain size D (.mu.m), the reduction ratio of final cold-rolling R (%) satisfying the equations below;16.ltoreq.R.ltoreq.75,6.38D-133.9.ltoreq.R.ltoreq.6.38D-51.0a softening annealing step of annealing said cold rolled sheet in a temperature range of 720.degree. to 790.degree. C. for 2 to 40 min. before press-forming and on conditions satisfying the equation below;T.gtoreq.-53.8 log t+806,where T(.degree. C.) is the temperature and t (min.Type: GrantFiled: December 1, 1993Date of Patent: April 15, 1997Assignee: NKK CorporationInventors: Tadashi Inoue, Kiyoshi Tsuru, Michihito Hiasa, Tomoyoshi Okita
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Patent number: 5605582Abstract: An alloy sheet having a pierced hole face and providing a desirable etching performance, comprising {331}, {210}, and {211} planes on the surface; the gathering degree of the {311} plane being 14% or less, the gathering degree of the {210} plane being 14% or less, and the gathering degree of the {211} plane being 14% or less; and the ratio of the gathering degrees expressed by the equation {210}/({331}+{211}) being 0.2 to 1. An alloy sheet having a pierced hole face providing a desirable etching performance, comprising planes of {111}, {100}, {110}, {311}, {331}, {210} and {211}; the gathering degree of the {111} plane, S.sub.1, being 1 to 10%, the gathering degree of the {100} plane, S.sub.2, being 50 to 94%, the gathering degree of the {110} plane, S.sub.3, being 1 to 24%, the gathering degree of the {311} plane, S.sub.4, being 1 to 14%, the gathering degree of the {331} plane, S.sub.5, being 1 to 14%, the gathering degree of the {210} plane, S.sub.Type: GrantFiled: November 17, 1993Date of Patent: February 25, 1997Assignee: NKK CorporationInventors: Tadashi Inoue, Hidekazu Yoshizawa, Kiyoshi Tsuru, Yoshiaki Shimizu, Tomoyoshi Okita
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Patent number: 5605581Abstract: A thin Fe--Ni alloy sheet for shadow mask consists essentially of Ni of 34 to 38 wt. %, Si of 0.05 wt. % or less, B of 0.0005 wt. % or less, O of 0.002 wt. % or less and N of 0.0015 % or less, the balance being Fe and inevitable impurities; said alloy sheet after annealing before press-forming having 0.2% proof stress of 28.5 kgf/mm.sup.2 or less; and a degree of {211} plane on a surface of said alloy sheet being 16% or less. And further modified similar alloy sheets are also provided.Further, a method for producing a thin Fe--Ni alloy sheet for shadow mask comprises the steps of: (a) hot-rolling of a slab into a hot-rolled alloy strip; (b) hot-rolled sheet annealing of the hot-rolled strip at 910.degree. to 990.degree. C.; (c) cold-rolling of the annealed hot-rolled strip into a cold-rolled strip; (d) recrystallization annealing of the cold-rolled strip; (e) finish cold-rolling of the recrystallization annealed strip at a finish cold reduction ratio in response to austenite grain size D(D.mu.Type: GrantFiled: January 21, 1994Date of Patent: February 25, 1997Assignee: NKK CorporationInventors: Tadashi Inoue, Kiyoshi Tsuru, Tomoyoshi Okita, Michihito Hiasa
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Patent number: 5562783Abstract: An alloy sheet for making a shadow mask consists essentially of 34 to 38 wt. % Ni, 0.07 wt. % or less Si, 0.001 wt. % or less B, 0.003 wt. % or less O, 0.002 wt. % or less N, and the balance being Fe and inevitable impurities.The alloy sheet has an average austenite grain size (Dav) of 10.5 to 15.0 .mu.m, a ratio of a maximum size to the minimum size of austenite grains (Dmax/Dmin) of 1 to 15, a Vickers hardness (Hv) of 165 to 220 and satisfying a relation of10.times.Dav+80.gtoreq.Hv.gtoreq.10.times.Dav+50;and gathering degree of crystal planes on said alloy sheet surface of14% or less for {111} plane,5 to 75% for {100} plane,5 to 40% for {110} plane,20% or less for {311} plane,20% or less for {331} plane,20% or less for {210} plane, and20% or less for {211} plane.Type: GrantFiled: January 6, 1994Date of Patent: October 8, 1996Assignee: NKK CorporationInventors: Tadashi Inoue, Kiyoshi Tsuru, Michihito Hiasa, Tomoyoshi Okita
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Patent number: 5525164Abstract: A Ni--Fe magnetic alloy consists essentially of:77 to 80 wt. % Ni, 3.5 to 5 wt. % Mo, 1.5 to 3 wt. % Cu, 0.1 to 1.1 wt. % Mn, 0.1 wt. % or less Cr, 0.003 wt. % or less S, 0.01 wt. % or less P, 0.005 wt. % or less O, 0.003 wt. % or less N, 0.02 wt. % or less C, 0.001 to 0.05 wt. % Al, 1 wt. % or less Si, 2.6-6 of the weight ratio of Ca to S, (Ca/S), and the balance being Fe and inevitable impurities, satisfies an equation of 3.2.ltoreq.(2.02.times.[Ni]-11.13.times.[Mo]-1.25.times.[Cu]-5.03.times.[M n])/(2.13.times.[Fe]).ltoreq.3.8; and has a Mo segregation ratio defined by a seregration equation satisfying 5% or less, the seregration equation being .vertline.(Mo content in a segregation region-Mo average content)/(Mo average content).vertline..times.100%.A method for producing a magnetic Ni--Fe alloy comprises the steps of: a first heating step of heating an alloy ingot to 1200.degree. to 1300.degree. C. for 10 to 30 hrs; slabbing the heated ingot at a finishing temperature of 950.degree. C.Type: GrantFiled: March 8, 1995Date of Patent: June 11, 1996Assignee: NKK CorporationInventors: Tadashi Inoue, Kiyoshi Tsuru, Shinichi Okimoto, Naokazu Yamamura, Tetsuo Yamamoto, Hirohisa Haiji
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Patent number: 5522953Abstract: A method for manufacturing an alloy sheet comprising the steps of: (a) hot-rolling a slab containing Fe, Ni and Cr into a hot-rolled strip; (b) annealing the hot-rolled strip at a temperature of 810.degree. to 890.degree. C.; (c) cold-rolling the annealed hot-rolled strip at a reduction ratio of 81 to 94% into a cold-rolled sheet; (d) recrystallization annealing of the cold-rolled sheet; (e) finish cold-rolling the cold-rolled sheet subjected to the recrystallization annealing at a reduction ratio of 14 to 29%; (f) stress relief annealing of the cold-rolled sheet subjected to the finish cold-rolling; and (g) annealing, before press-forming. The cold-rolled sheet subjected to the stress relief annealing at a temperature of 740.degree. to 900.degree. C. for 2 to 40 minutes and satisfying the following equation: T.ltoreq.-123 logt+937, where T is a temperature (.degree.C.) and t is a time (minutes) for the annealing.Type: GrantFiled: March 3, 1995Date of Patent: June 4, 1996Assignee: NKK CorporationInventors: Tadashi Inoue, Kiyoshi Tsuru, Tomoyoshi Okita, Michihito Hiasa
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Patent number: 5520755Abstract: A thin Fe--Ni alloy sheet for shadow mask consists essentially of Ni of 34 to 38 wt. %, Si of 0.05 wt. % or less, B of 0.0005 wt. % or less, O of 0.002 wt. % or less and N of 0.0015% or less, the balance being Fe and inevitable impurities; said alloy sheet after annealing before press-forming having 0.2% proof stress of 28.5 kgf/mm.sup.2 or less; and a degree of {211} plane on a surface of said alloy sheet being 16% or less. And further modified similar alloy sheets are also provided.Further, a method for producing a thin Fe--Ni alloy sheet for shadow mask comprises the steps of: (a) hot-rolling of a slab into a hot-rolled alloy strip; (b) hot-rolled sheet annealing of the hot-rolled strip at 910.degree. to 990.degree. C.; (c) cold-rolling of the annealed hot-rolled strip into a cold-rolled strip; (d) recrystallization annealing of the cold-rolled strip; (e) finish cold-rolling of the recrystallization annealed strip at a finish cold reduction ratio in response to austenite grain size D(D.mu.Type: GrantFiled: November 18, 1994Date of Patent: May 28, 1996Assignee: NKK CorporationInventors: Tadashi Inoue, Kiyoshi Tsuru, Tomoyoshi Okita, Michihito Hiasa
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Patent number: 5503693Abstract: A thin Fe--Ni alloy sheet for shadow mask consists essentially of Ni of 34 to 38 wt. %, Si of 0.05 wt. % or less, B of 0.0005 wt. % or less, O of 0.002 wt. % or less and N of 0.0015% or less, the balance being Fe and inevitable impurities; said alloy sheet after annealing before press-forming having 0.2% proof stress of 28.5 kgf/mm or less; and a degree of {211 } plane on a surface of said alloy sheet being 16% or less. And further modified similar alloy sheets are also provided.Further, a method for producing a thin Fe--Ni alloy sheet for shadow mask comprises the steps of: (a) hot-rolling of a slab into a hot-rolled alloy strip; (b) hot-rolled sheet annealing of the hot-rolled strip at 910.degree. to 990.degree. C.; (c) cold-rolling of the annealed hot-rolled strip into a cold-rolled strip; (d) recrystallization annealing of the cold-rolled strip; (e) finish cold-rolling of the recrystallization annealed strip at a finish cold reduction ratio in response to austenite grain size D(D .mu.Type: GrantFiled: November 18, 1994Date of Patent: April 2, 1996Assignee: NKK CorporationInventors: Tadashi Inoue, Kiyoshi Tsuru, Tomoyoshi Okita, Michihito Hiasa
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Patent number: 5501749Abstract: A thin Fe--Ni alloy sheet for shadow mask consists essentially of Ni of 34 to 38 wt. %, Si of 0.05 wt. % or less, B of 0.0005 wt. % or less, O of 0.002 wt. % or less and N of 0.0015% or less, the balance being Fe and inevitable impurities; said alloy sheet after annealing before press-forming having 0.2% proof stress of 28.5 kgf/mm.sup.2 or less; and a degree of {211} plane on a surface of said alloy sheet being 16% or less. And further modified similar alloy sheets are also provided.Further, a method for producing a thin Fe--Ni alloy sheet for shadow mask comprises the steps of: (a) hot-rolling of a slab into a hot-rolled alloy strip; (b) hot-rolled sheet annealing of the hot-rolled strip at 910.degree. to 990.degree. C.; (c) cold-rolling of the annealed hot-rolled strip into a cold-rolled strip; (d) recrystallization annealing of the cold-rolled strip; (e) finish cold-rolling of the recrystallization annealed strip at a finish cold reduction ratio in response to austenite grain size D(D .mu.Type: GrantFiled: November 18, 1994Date of Patent: March 26, 1996Assignee: NKK CorporationInventors: Tadashi Inoue, Kiyoshi Tsuru, Tomoyoshi Okita, Michihito Hiasa
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Patent number: 5500057Abstract: A Ni-Fe magnetic alloy consists essentially of:77 to 80 wt. % Ni, 3.5 to 5 wt. % Mo, 1.5 to 3 wt. % Cu, 0.1 to 1.1 wt. % Mn, 0.1 wt. % or less Cr, 0.003 wt. % or less S, 0.01 wt. % or less P, 0.005 wt. % or less 0, 0.003 wt. % or less N, 0.02 wt. % or less C, 0.001 to 0.05 wt. % Al, 1 wt. % or less Si, 2.6-6 of the weight ratio of Ca to S, (Ca/S), and the balance being Fe and inevitable impurities, satisfies an equation of 3.2.ltoreq.(2.02.times.[Ni]-11.13.times.[Mo]-1.25.times.[Cu]-5.03.times.[M n])/ (2.13.times.[Fe]).ltoreq.3.8; and has a Mo segregation ratio defined by a seregration equation satisfying 5% or less, the seregration equation being .vertline.(Mo content in a segregation region-Mo average content)/ (Mo average content).vertline..times.100%.A method for producing a magnetic Ni-Fe alloy comprises the steps of: a first heating step of heating an alloy ingot to 1200.degree. to 1300.degree. C. for 10 to 30 hrs; slabbing the heated ingot at a finishing temperature of 950.degree. C.Type: GrantFiled: October 1, 1993Date of Patent: March 19, 1996Assignee: NKK CorporationInventors: Tadashi Inoue, Kiyoshi Tsuru, Shinichi Okimoto, Naokazu Yamamura, Tetsuo Yamamoto, Hirohisa Haiji
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Patent number: 5456771Abstract: A thin Fe-Ni alloy sheet for shadow mask consists essentially of Ni of 34 to 38 wt. %, Si of 0.05 wt. % or less, B of 0.0005 wt. % or less, 0 of 0.002 wt. % or less and N of 0.0015% or less, the balance being Fe and inevitable impurities; said alloy sheet after annealing before press-forming having 0.2% proof stress of 28.5 kgf/mm.sup.2 or less; and a degree of {211} plane on a surface of said alloy sheet being 16% or less. And further modified similar alloy sheets are also provided.Further, a method for producing a thin Fe-Ni alloy sheet for shadow mask comprises the steps of: (a) hot-rolling of a slab into a hot-rolled alloy strip; (b) hot-rolled sheet annealing of the hot-rolled strip at 910.degree. to 990.degree. C.; (c) cold-rolling of the annealed hot-rolled strip into a cold-rolled strip; (d) recrystallization annealing of the cold-rolled strip; (e) finish cold-rolling of the recrystallization annealed strip at a finish cold reduction ratio in response to austenite grain size D(D .mu.Type: GrantFiled: January 22, 1993Date of Patent: October 10, 1995Assignee: NKK CorporationInventors: Tadashi Inoue, Kiyoshi Tsuru, Tomoyoshi Okita, Michihito Hiasa
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Patent number: 5453138Abstract: An alloy sheet containing Fe, Ni and Cr has an average austenite grain size of 15 to 45 .mu.m and a degree of mixed grain for austenite grain size of 4.5 to 50%; the alloy sheet has a gathering degree of the {331} plane on a surface of the alloy sheet of 8 to 35%, a gathering degree of the {210} plane of 1 to 20% and a gathering degree of the {211} plane of 2 to 20%; the degree of mixed grain is expressed by the equation: (.vertline.0.5 Dmax-D.vertline./D).times.100 (%), where D is an average austenite grain size, and Dmax is a maximum austenite grain size in said alloy sheet.Type: GrantFiled: January 18, 1994Date of Patent: September 26, 1995Assignee: NKK CorporationInventors: Tadashi Inoue, Kiyoshi Tsuru, Tomoyoshi Okita, Michihito Hiasa
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Patent number: 5308723Abstract: The metallic sheet for shadow mask comprises a Fe-Ni alloy sheet having mainly of Fe and Ni; degrees of planes on a surface of the alloy sheet, the degree of {331} plane being 14% or less, the degree of {210} plane 10% or less and the degree of {211} plane 10% or less; and a ratio of degrees of planes which is {210}/[{331}+{211}] being 0.2 to 1.Another thin metallic sheet for shadow mask comprises a Fe-Ni alloy sheet having mainly of Fe and Ni; degrees of planes on a surface of the alloy sheet, that of {111} plane being 5% or less, that of {100} plane 50 to 93%, that of {110} 24% or less, that of {311} plane 1 to 10%, that of {331} 1 to 14%, that of {210} plane 1 to 10% and that of {211} plane 1 to 10%; a ratio of degrees of planes which is [{100}+{311}+{210}]/[{110}+{111}+{331}+{211}] being 0.8 to 20.Type: GrantFiled: January 21, 1993Date of Patent: May 3, 1994Assignee: NKK CorporationInventors: Tadashi Inoue, Hidekazu Yoshizawa, Kiyoshi Tsuru, Tomoyoshi Okita, Yoshiaki Shimizu
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Patent number: 5032365Abstract: A reaction tube of a reaction apparatus includes a circular cylindrical inner tube and an intermediate tube disposed concentrically with the inner tube. A catalyst used in reforming reactions is charged in the gap between the inner and the intermediate tubes. The inner tube accommodates filler particles and is provided with a hollow member disposed therein in contact with the filler particles and capable of absorbing stress resulting from thermal expansion of the filler particles. By virtue of the provision of the hollow member which absorbs thermal stress of the filler particles that are caused to undergo thermal expansion by a high-temperature gas, such as a combustion gas, flowing through the inside of the inner tube, the apparatus is capable of preventing any deformation or breakage of the inner tube.Type: GrantFiled: April 6, 1989Date of Patent: July 16, 1991Assignee: Mitsubishi Denki Kabushiki KaishaInventors: Atsushi Aono, Rooku Fujimoto, Nobuyuki Itoh, Tatsuya Ikeda, Kiyoshi Tsuru