Abstract: Feed devices for liquid samples serve to convey liquid samples, for example to convey a liquid sample from waste water in a waste water treatment plant so as to monitor the treatment process. Known feed devices feed continuously at relatively low speeds. Films may accrete in the feed line that hinder the feeding and may react with the liquid sample. Therefore, the feed line must be cleaned frequently. In view of this, it is the object of the invention to improve the handling and the maintenance of a feed device for liquid samples. According to the invention, this object is solved by the fact that the feed pump (16) feeds in a pulse-like manner and the feed pump (16) as well as the feed line (18) are configured such that the expansion volume of the feed line (18) during the feed pulse is at most 50% of the pulse volume. Thereby, the feed line is cleaned and kept free of accretions.

Abstract: Gas-selective electrodes in liquid analyzing devices have a characteristic curve K with a linear portion L and a non-linear portion NL. In the non-linear portion NL, the characteristic previously could only be estimated so that determinations of the concentration were rather inexact. According to the present application, the electrode is rinsed with an acid and the zero point voltage UN at the electrode is determined during the rinsing. Using the zero point voltage UN, the non-linear portion NL of the characteristic K is determined with high precision so that even low concentrations c can be determined with great accuracy.

Abstract: A method for coating metallic surfaces with a paint or paint-like coating prior to forming.

Abstract: The invention relates to a method for coating a metallic strip. The strip or optionally, the strip sections produced from said strip in the subsequent process, is/are first coated with at least one anticorrosion layer—according to an alternative form of embodiment, this can be left out—and then with at least one layer of a paint-like coating containing polymers. After being coated with at least one anticorrosion layer or after being coated with at least one layer of a paint-like coating, the strip is divided into strip sections. The coated strip sections are then formed, joined and/or coated with at least one (other) paint-like coating and/or paint coating.

Abstract: A method for coating metallic surfaces with a paint or paint-like coating prior to forming.

Abstract: A composition and a method for coating a metallic surface with the composition, wherein the composition contains water, at least one organic film former containing a water-soluble polymer or a water-dispersible polymer; cations or a hexafluoro complex of cations of titanium, zirconium, hafnium, silicon, aluminum and boron; and at least one inorganic particle having an average particle diameter of 0.005 to 0.2 ?m as measured with a scanning electron microscope by contacting a metallic surface with the composition and forming a film by drying, the film having a thickness of 0.01 to 10 ?m.

Abstract: Metallic surfaces are coated with an aqueous, acidic phosphate solution containing 10 to 60 g/l zinc, 0.5 to 40 g/l manganese, 50 to 300 g/l phosphate ions calculated as P2O5, and optionally other components.

Abstract: A method for coating a metal strip or strip sections produced from the strip in a subsequent step are first coated with at least one anticorrosive coating and then with at least one coating of a paint-like polymer-containing coating. The coated strip is divided up in strip sections and the coated strip sections are then formed, joined and/or coated with at least one further paint-like coating and/or coat of paint. The paint-like coating is an aqueous dispersion that contains, in addition to water, at least one UV-crosslinkable water-soluble and/or water-dispersible resin, at least one wax as the forming additive, at least one photoinitiator, and at least one corrosion inhibitor. The coating is dried and, In another embodiment, the strip is first coated with at least one paint-like polymer containing coating without prior application of an anticorrosive coating.

Abstract: Gas-selective electrodes in liquid analyzing devices have a characteristic K with a linear portion L and a non-linear portion NL. In the non-linear portion NL, the characteristic can only be estimated so that these determinations of the concentration are rather inexact. According to the present method, the electrode is rinsed with an acid and the zero point voltage at the electrode is determined during the rinsing. Using the zero point voltage UN thus quickly obtained, the non-linear portion NL of the characteristic K can be determined with high precision so that even low concentrations c can be determined with great accuracy.

Abstract: Feed devices for liquid samples serve to convey liquid samples, for example to convey a liquid sample from waste water in a waste water treatment plant so as to monitor the treatment process. Known feed devices feed continuously at relatively low speeds. Films may accrete in the feed line that hinder the feeding and may react with the liquid sample. Therefore, the feed line must be cleaned frequently. In view of this, it is the object of the invention to improve the handling and the maintenance of a feed device for liquid samples. According to the invention, this object is solved by the fact that the feed pump (16) feeds in a pulse-like manner and the feed pump (16) as well as the feed line (18) are configured such that the expansion volume of the feed line (18) during the feed pulse is at most 50% of the pulse volume. Thereby, the feed line is cleaned and kept free of accretions.

Abstract: The invention relates to a method for applying phosphate coatings to metallic surfaces by wetting with an aqueous, acidic phosphating solution and subsequent drying of the phosphating solution, usually without subsequent rinsing, in which the phosphating solution contains

Abstract: The invention relates to a method for coating metallic surfaces by a manganese-zinc phosphatizing process, using an aqueous phosphatizing solution, in which nickel is deliberately not added. Said method is characterized in that the zinc:manganese weight ratio of the phosphatizing solution is maintained in the region of between 0.05:1 and 0.99:1 and that the phosphatizing solution has the following contents: between 0.05 and 5 g/l zinc, between 0.075 and 5.2 g/l manganese and between 0.008 and 0.050 g/l copper and/or hexafluoride complexes of titanium, hafnium and/or zirconium totalling between 0.002 and 0.5 g/l, calculated as F6. The invention also relates to the use of the metal parts coated in this manner.

Abstract: A metal surface is coated with a phosphate coating by wetting the surface with an aqueous acidic phosphatizing solution containing from 1.2 to less than 10 g/l zinc ions; from 0.2 to 2.

Abstract: The invention relates to a method for coating a metallic strip. The strip or optionally, the strip sections produced from said strip in the subsequent process, is/are first coated with at least one anticorrosion layer—according to an alternative form of embodiment, this can be left out—and then with at least one layer of a paint-like coating containing polymers. After being coated with at least one anticorrosion layer or after being coated with at least one layer of a paint-like coating, the strip is divided into strip sections. The coated strip sections are then formed, joined and/or coated with at least one (other) paint-like coating and/or paint coating.

Abstract: The invention relates to a method for coating a metallic surface with a composition. This method is characterised in that the composition contains the following in addition to water: a) at least one organic film former containing at least one polymer which is soluble in water or is dispersed in water; b) a quantity of cations and/or hexafluoro complexes of cations selected from the group comprising titanium, zirconium, hafnium, silicon, aluminium and boron; and c) at least one inorganic compound in particle form with an average particle diameter of 0.005 to 0.2 &mgr;m, measured with a scanning electron microscope. The clean metallic surface is brought into contact with the aqueous composition and a film containing particles is formed on the metallic surface. This film is then dried, the dry film having a layer thickness of 0.01 to 10 &mgr;m. The invention also relates to a corresponding aqueous composition.

Abstract: The invention relates to a method for coating a metallic strip. The strip or optionally, the strip sections produced from said strip in the subsequent process, is/are coated first with at least one anticorrosion layer and then with at least one layer of a paint-like coating containing polymers and/or with at least one paint coating. After being coated with at least one anticorrosion layer or after being coated with at least one layer of a paint-like coating and/or with at least one paint coating, the strip is divided into strip sections. The coated strip sections are then formed, joined and/or coated with at least one (other) paint-like coating and/or paint coating.

Abstract: The invention relates to a method for coating a metal strip for use in the automotive, aircraft or aerospace industry. The strip or the strip sections produced on the basis thereof in a later step is/are first coated with at least one anticorrosive coating and then with at least one coating of a paint-like polymer-containing coating. The strip, once coated with at least one anticorrosive coating or once coated with at least one coat of a paint-like coating, is divided up in strip sections. Said coated strip sections are then formed, joined and/or coated with at least one (further) paint-like coating and/or coat of paint. The paint-like coating is achieved by coating the surface with an aqueous dispersion that contains, in addition to water, at least one UV-crosslinkable water-soluble and/or water-dispersible resin, at least one wax as the forming additive, at least one photoinitiator, and at least one corrosion inhibitor.

Abstract: In a method for the pretreatment of work pieces having a surface made of aluminium or aluminium alloys, for non-cutting shaping and/or the connection by welding or gluing to work pieces as well as for a subsequent permanent corrosion-preventing treatment, the work pieces are subjected to a three-stage treatment by a) rinsing with an aqueous, acidic solution containing a mineral acid, b) rinsing with water, c) bringing them into contact with an aqueous, acidic solution which is chromium-free and polymer-free and contains Ti and Zr as complex fluorides in a weight ratio of Ti:Zr of 2:1 to 1:2, in such a way that, after the subsequent drying off, a layer weight of 2 to 15 mg/m2 (calculated as Ti/Zr metal) results, wherein depending on the type of application, solutions having different concentrations and different pH values are used.

Abstract: A method is disclosed for applying phosphate coatings to surfaces of zinc, iron, aluminum, and the alloys thereof by wetting with a phosphatizing solution containing divalent cations and phosphate to form a liquid film, and subsequently drying on the liquid film wherein the metal surfaces are wetted with a phosphatizing solution, which is free from elements of sub-groups 5 and 6 of the Periodic Table, said phosphatizing solution containing:0.5 to 8 g/l nickel;2 to 20 g/l manganese;18 to 170 g/l of phosphate (calculated as P.sub.2 O.sub.5);and has an acid number of 0.4 to 0.8, such that after drying on, a phosphate layer having a weight per unit area of 0.3 to 3.0 g/m.sup.2, is obtained, where in the case of phosphatizing surfaces of iron, aluminum or the alloys thereof, the phosphatizing solution necessarily contains 0.5 to 5 g/l of zinc, and in the case of phosphatizing surfaces of zinc or zinc alloys the phosphatizing solution either contains zinc or is free from zinc.

Abstract: The process forms a phosphate coating on a steel strip or sheet having a galvanized or alloy galvanized side and a steel side so that the phosphate coating is only present on the galvanized or alloy galvanized side. This process includes contacting the galvanized or alloy galvanized side of the steel strip or sheet with a phosphatizing solution for 4 to 20 seconds at a temperature of from 45.degree. C. to 80.degree. C. The phosphatizing solution has an S value of from 0.08 to 0.30 and contains 0.5 to 5 g/l zinc, 3 to 20 g/l P.sub.2 O.sub.5, 0.020 to 0.2 g/l nitrite, 3 to 30 g/l nitrate and 0.2 to 2.5 g/l complexing agent for iron. Chelate forming substances, such as tartaric acid, citric acid, ethylenediamine-tetraacetic acid, nitrilotriacetic acid and/or oxalic acid, may be used as the complexing agent for iron. The phosphatizing solutions may also contain other bivalent cations, particularly manganese and/or nickel cations.