Patents by Inventor Klaus Grychtol

Klaus Grychtol has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5529872
    Abstract: An electrostatic toner contains a polymeric binder and as charge stabilizer a 1:2 chromium, iron, cobalt or zirconium complex of azo dyes of the formula D--N.dbd.N--K, where D is derived from a diazo component D--NH.sub.2 selected from the group consisting of 2-amino-4-nitrophenol, 2-amino-5-nitrophenol, 2-amino-phenol-4-sulfonamide, anthranilic acid and picramic acid and K is derived from a coupling component K--H selected from the group consisting of .beta.-naphthol, acetoacetanilide and 1-phenyl-3-methylpyrazol-5-one.
    Type: Grant
    Filed: February 17, 1995
    Date of Patent: June 25, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Klaus Grychtol, Karin H. Beck, Rainer Dyllick-Brenzinger
  • Patent number: 4979962
    Abstract: Natural and synthetic polyamides are dyed with the betaines of 1:1 chromium complexes of sulfo-containing azo or azomethine dyes from an aqueous liquor.
    Type: Grant
    Filed: May 26, 1989
    Date of Patent: December 25, 1990
    Assignee: BASF Aktiengesellschaft
    Inventors: Klaus Grychtol, Manfred Daubitz
  • Patent number: 4804386
    Abstract: A chromium complex dye of the formula ##STR1## and salts thereof are used for dyeing polyamides or leather.
    Type: Grant
    Filed: February 2, 1988
    Date of Patent: February 14, 1989
    Assignee: BASF Aktiengesellschaft
    Inventor: Klaus Grychtol
  • Patent number: 4720568
    Abstract: Compounds of the general formula IA--B--A (I)where A is a radical of the formula ##STR1## and B is a bridge member of the formula ##STR2## and where R.sup.1 and R.sup.2 independently of one another are unsubstituted or hydroxy-, C.sub.1 -C.sub.4 -alkoxy-, cyano-, C.sub.1 -C.sub.4 -alkoxycarbonyl-, di-C.sub.1 -C.sub.4 -alkylamino-, chlorine- or bromine-substituted C.sub.1 -C.sub.4 -alkyl, cyclohexyl, benzyl, phenylethyl or phenyl, orR.sup.1 and R.sup.2 together with the nitrogen are morpholino, pyrrolidino, piperidino or N-methylpiperazino,R.sup.3 is hydrogen, chlorine, bromine, methyl, ethyl, methoxy, ethoxy or nitro,R.sup.4 and R.sup.5 independently of one another are hydrogen, C.sub.1 -C.sub.4 -alkyl or benzyl,X is oxygen or imino andalkylene is of 2 to 6 carbon atoms and is linear or branched.The compounds of the formula I are particularly suitable for coloring paper pulps.
    Type: Grant
    Filed: February 7, 1986
    Date of Patent: January 19, 1988
    Assignee: BASF Aktiengesellschaft
    Inventors: Manfred Eisert, Klaus Grychtol
  • Patent number: 4663441
    Abstract: Compounds of the formula I ##STR1## where K.sup..sym. is a cation, R is methyl or is phenyl which is unsubstituted or substituted by chlorine, bromine, methyl, methoxy or ethoxy, R.sup.1 is hydrogen, chlorine, bromine or nitro, R.sup.2 is hydrogen, chlorine, bromine, nitro, sulfamyl or hydroxysulfonyl, X and Y are each --O-- or --COO--, Z is --O-- or --NH--, D is a radical of a diazo component of the aniline or naphthylamine series and K is a radical of a coupling component, are very useful for dyeing natural and synthetic polyamide textile fibers and leather.
    Type: Grant
    Filed: September 16, 1985
    Date of Patent: May 5, 1987
    Assignee: BASF Aktiengesellschaft
    Inventor: Klaus Grychtol
  • Patent number: 4597912
    Abstract: A compound of the formula: ##STR1## wherein R.sup.1 and R.sup.2 independently of one another are unsubstituted or hydroxy substituted, C.sub.1 -C.sub.4 alkoxy substituted, cyano substituted, C.sub.1 -C.sub.4 alkoxycarbonyl substituted, di-C.sub.1 -C.sub.4 alkylamino substituted, (CH.sub.3)(C.sub.6 H.sub.5 CH.sub.2)NC.sub.2 H.sub.4 substituted, chlorine substituted or bromine substituted C.sub.1 -C.sub.4 -alkyl, cyclohexyl, benzyl, phenylethyl or phenyl, R.sup.1 and R.sup.2 together with the nitrogen are morpholino, pyrrolidino, piperidino or N-methylpiperazino;R.sup.3 is hydrogen, chlorine, bromine, methyl, ethyl, methoxy, ethoxy or nitro;R.sup.4 and R.sup.5 independently of one another are hydrogen, C.sub.1 -C.sub.4 -alkyl or benzyl; X is oxygen or imino; A.sup.
    Type: Grant
    Filed: May 17, 1985
    Date of Patent: July 1, 1986
    Assignee: BASF Aktiengesellschaft
    Inventors: Manfred Eisert, Klaus Grychtol
  • Patent number: 4560744
    Abstract: Compounds which in the form of the free acids correspond to the formula ##STR1## where A is a radical of a diazo component or of an amine,B is a radical of a coupling component or of an aldehyde,R.sup.1 is chlorine or bromine,R.sup.2 is methoxy or ethoxy,X is .dbd.N-- or .dbd.CH--,Y is --O-- or --COO-- andZ is --O-- or --NH--,are dyes which are very suitable for dyeing nylons and natural polyamides.
    Type: Grant
    Filed: March 6, 1981
    Date of Patent: December 24, 1985
    Assignee: BASF Aktiengesellschaft
    Inventors: Hans Baumann, Klaus Grychtol
  • Patent number: 4537955
    Abstract: An unsymmetrical 1:2 chromium complex of a monoazo dyestuff and a disazo dyestuff which is non-fiber reactive and is free of sulfonamido and amino groups and which, in the form of the free acid has the formula: ##STR1## wherein A' is the radical of a 1-hydroxy-2-aminobenzene which is monosubstituted or disubstituted by chlorine, nitro, or sulfo, B' is a naphth-2-ol, resorcinol, p-(C.sub.1 -C.sub.6 -alkyl)-phenol, 1-phenol-3-methylpyrazol-5-one or acetoacetanilide radical, and the phenol group in the last two mentioned compounds can be substituted by C.sub.1 -C.sub.4 -alkyl C.sub.1 -C.sub.4 -alkoxy, chlorine or sulfo, K' is an unsubstituted or sulfo-substituted naphth-1-ol or naphth-2-ol radical, phenol which is substituted in the p-positioned by C.sub.1 -C.sub.6 -alkyl, an unsubstituted or sulfo-substituted 2-naphthylanime, and 1-phenol-3-methylpyrazol-5-one or an acetoactanilide radical, and the phenol group in the last two mentioned compounds can be substituted by C.sub.1 -C.sub.
    Type: Grant
    Filed: March 1, 1983
    Date of Patent: August 27, 1985
    Assignee: BASF Aktiengesellschaft
    Inventors: Klaus Grychtol, Hans Baumann
  • Patent number: 4489002
    Abstract: Compounds of the general formula I ##STR1## where E is --CH.dbd. or --N.dbd., K is the radical of an amine or of a coupling component of the benzene, naphthalene, pyrazole, pyridine, pyrimidine, quinoline or isoquinoline series, or the radical of a 1,3-dicarbonyl compound which can be coupled, X is --O-- or --COO--, Y is --O--, --COO-- or --NH--, Z.sup.1 and Z.sup.2 independently of one another are unsubstituted or substituted alkyl or cycloalkyl, and one of them may furthermore be unsubstituted or substituted aryl, or Z.sup.1 and Z.sup.2 together with the nitrogen atom are a heterocyclic radical, and Z is unsubstituted or substituted C.sub.2 - or C.sub.3 -alkylene, from 1 to 4 sulfonic acid groups can be present and the rings A and B can be further substituted or can carry a fused benzene ring.The compounds of the present invention are suitable for dyeing or printing natural or synthetic N-containing materials, i.e., wool, leather or polyamide or polyurethane fibers, as wells as for coloring inks.
    Type: Grant
    Filed: June 4, 1982
    Date of Patent: December 18, 1984
    Assignee: BASF Aktiengesellschaft
    Inventors: Hans Baumann, Klaus Grychtol
  • Patent number: 4474695
    Abstract: Mixtures of two or more cobalt 1:2 complexes of azo dyes of the formula I ##STR1## where R is ##STR2## where R.sup.1 is hydrogen, C.sub.1 -C.sub.18 -alkyl, or hydroxyalkyl or alkoxyalkyl which may be interrupted by oxygen, and X and Y are hydrogen, fluorine, chlorine, bromine, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy.The mixtures according to the invention are particularly useful for dyeing leather.
    Type: Grant
    Filed: December 2, 1981
    Date of Patent: October 2, 1984
    Assignee: BASF Aktiengesellschaft
    Inventors: Klaus Grychtol, Dietrich Lach
  • Patent number: 4424153
    Abstract: 1:2 Chromium complexes of arylazo-azamethines of the general formula ##STR1## where A is a naphthalene or benzene radical which may be monosubstituted or polysubstituted by alkyl, alkoxy or halogen.
    Type: Grant
    Filed: August 24, 1981
    Date of Patent: January 3, 1984
    Assignee: BASF Aktiengesellschaft
    Inventors: Hans Baumann, Klaus Grychtol
  • Patent number: 4397651
    Abstract: Polymeric dyes of the general formula I ##STR1## where A is the radical of a methylene-active compound, which may or may not be quaternized,B.sup.1 and B.sup.2 are bridge members which may or may not be quaternized or B.sup.2 may be a direct bond,n is number >1,p is the number of positive charges,R is hydrogen, chlorine, bromine, hydroxyl, C.sub.1 -C.sub.8 -alkyl, nitro, C.sub.1 -C.sub.8 -alkoxy, C.sub.1 -C.sub.8 -alkoxycarbonyl, cyano, hydroxycarbonyl, unsubstituted or substituted carbamyl or unsubstituted or substituted amino,R.sup.1 is hydrogen, chlorine, hydroxyl, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy orR and R.sup.1 together are an unsubstituted or substituted fused ring, or R and R.sup.1 together with B.sup.2 are a heterocyclic radical andA.sup..crclbar. is an anion.
    Type: Grant
    Filed: August 10, 1981
    Date of Patent: August 9, 1983
    Assignee: BASF Aktiengesellschaft
    Inventors: Hans-Juergen Degen, Klaus Grychtol
  • Patent number: 4353833
    Abstract: Compounds of the general formula I ##STR1## where the radicals A, A.sup.1 and B are identical or different andA is unsubstituted or substituted benzene or heteroaromatic,A.sup.1, if n=1, is unsubstituted or substituted heteroaromatic or is aryl which is unsubstituted or substituted by alkyl, aryl, cycloalkyl, chlorine, bromine, hydroxyl, alkoxy, aryloxy, nitro, hydroxycarbonyl, alkoxycarbonyl, or aminocarbonyl, and, if n>1, A.sup.1 may also be aryl substituted by unsubstituted or substituted amino,B is a bridge member of the formula ##STR2## B.sup.1 is a bridge member which may or may not be quaternized, R.sup.1 and R.sup.2 are hydrogen, unsubstituted or substituted alkyl, cycloalkyl, aryl, alkoxy or amino,n is an integer equal to or greater than 1 andX.sup..theta. is an anion.The compounds according to the invention are preferably used for coloring paper pulp.
    Type: Grant
    Filed: November 12, 1980
    Date of Patent: October 12, 1982
    Assignee: BASF Aktiengesellschaft
    Inventors: Horst Bruder, Hans-Juergen Degen, Franz Feichtmayr, Klaus Grychtol, Udo Mayer
  • Patent number: 4323362
    Abstract: Compounds of the general formulaA.sup.1 .dbd.CH--B--CH.dbd.A.sup.2where A.sup.1 and A.sup.2 are the radical of a quaternized methylene-active compound and B is a bridge member.The compounds according to the invention are very suitable for coloring ligneous and lignin-free paper stock.
    Type: Grant
    Filed: January 14, 1981
    Date of Patent: April 6, 1982
    Assignee: BASF Aktiengesellschaft
    Inventors: Hans-Juergen Degen, Klaus Grychtol
  • Patent number: 4280964
    Abstract: Basic dyes of the general formulaA-B-A Iwherethe substituents A independently of one another are a radical of the formula ##STR1## and B is a bridge member,and in the formula for AR.sup.1 and R.sup.2 independently of one another are C.sub.1 -C.sub.4 -alkyl which is unsubstituted or substituted by hydroxyl, C.sub.1 -C.sub.4 -alkoxy, cyano, C.sub.1 -C.sub.4 -alkoxycarbonyl, di-C.sub.1 -C.sub.4 -alkylamino, benzyl-(C.sub.1 -C.sub.4 -alkyl)-amino, chlorine or bromine, or are cyclohexyl, benzyl, phenylethyl or phenyl, orR.sup.1 and R.sup.2 together with the nitrogen are pyrrolidino, piperidino, morpholino or N-methylpiperazino,R.sup.3 is hydrogen, chlorine, bromine, methyl, ethyl, methoxy, ethoxy or nitro,X is oxygen, imino or C.sub.1 -C.sub.4 -alkylimino andalkylene is of 2 to 6 carbon atoms and is straight or branched.The novel dyes are mainly used for dyeing paper pulps.
    Type: Grant
    Filed: June 6, 1979
    Date of Patent: July 28, 1981
    Assignee: BASF Aktiengesellschaft
    Inventor: Klaus Grychtol
  • Patent number: 4264494
    Abstract: Metal complex compounds which in the form of the free acids correspond to the formula I ##STR1## where A is an aliphatic, carbocyclic or heterocyclic radical,E is an aliphatic or carbocyclic radical,B is a cyano, acyl, substituted sulfonyl, carboxylic acid ester or carboxamide radical, orB and E together with the carbon atoms by which they are linked may be an alicyclic or heterocyclic radical,F is an aliphatic, carbocylic or heterocyclic radical,L is --O--, --COO--, ##STR2## n is 1, 2, 3 or 4, Y is .dbd.CH-- or .dbd.N-- andZ is ##STR3## or the radical of a coupling component, alkyl being of 1 to 4 carbon atoms, andR is hydrogen or unsubstituted or substituted alkyl, cycloalkyl, aryl or acyl and R.sup.1 and R.sup.2 are substituents conventionally present in dyes.The compounds of the formula I give fast dyeings on natural polyamides and synthetic nylons.
    Type: Grant
    Filed: August 2, 1978
    Date of Patent: April 28, 1981
    Assignee: BASF Aktiengesellschaft
    Inventors: Klaus Grychtol, Hans Baumann
  • Patent number: 4256458
    Abstract: Methine dyes of the general formula ##STR1## where the groups A are identical or different aryl or hetaryl, A.sup..crclbar. is an anion, R is hydrogen, methyl or ethyl and X is a bridge member, and the methine groups are in the .alpha.- or .gamma.-position. The compounds are preferably used for dyeing paper.
    Type: Grant
    Filed: June 21, 1979
    Date of Patent: March 17, 1981
    Assignee: BASF Aktiengesellschaft
    Inventors: Hans-Juergen Degen, Franz Feichtmayr, Klaus Grychtol
  • Patent number: 4223144
    Abstract: Compounds of the general formula I ##STR1## where B is a bridge member,the radicals R independently of one another are hydrogen or substituted or unsubstituted alkyl, or two radicals R together with the nitrogen are a heterocyclic saturated 5-membered or 6-membered ring,the radicals R.sup.1 independently of one another are hydrogen or C.sub.1 -C.sub.4 -alkyl,the radicals R.sup.2 independently of one another are hydrogen, C.sub.1 -C.sub.4 -alkyl or halogen,the radicals R.sup.3 independently of one another are hydrogen or substituted or unsubstituted alkyl or together are an alkylene group, and X.crclbar. is an anion. The compounds of the formula I are particularly suitable for dyeing paper.
    Type: Grant
    Filed: September 5, 1978
    Date of Patent: September 16, 1980
    Assignee: BASF Aktiengesellschaft
    Inventors: Hellmut Kast, Klaus Grychtol, Franz Feichtmayr
  • Patent number: 4212644
    Abstract: Paper dyed with compounds of the general formula I ##STR1## where R.sup.1 is unsubstituted or substituted alkyl, T is hydrogen or alkyl, A.sup..theta. is an anion, n is 1, 2 or 3 and X is an aminoaryl radical which may or may not possess further substituents, and where the benzene nucleus a may be substituted by alkyl, hydroxy, alkoxy, chlorine, bromine, amino, alkylamino, dialkylamino, alkanoylamino or nitro. The compounds of the formula I dye paper in brilliant yellow shades. They are also suitable for dyeing materials containing anionic groups.
    Type: Grant
    Filed: July 25, 1978
    Date of Patent: July 15, 1980
    Assignee: BASF Aktiengesellschaft
    Inventors: Hans-Juergen Degen, Klaus Grychtol
  • Patent number: 3971821
    Abstract: Aminobenzaldehyde compounds and a process for their production by the reaction of an aniline with a formamide in the presence of an acid halide with or without a following reaction with a nitrogen compound. The products are starting materials for the production of optical brighteners, dyes, plant protection agents and medicaments.
    Type: Grant
    Filed: December 9, 1974
    Date of Patent: July 27, 1976
    Assignee: BASF Aktiengesellschaft
    Inventors: Hans Baumann, Klaus Grychtol, Andreas Oberlinner