Patents by Inventor Klaus Huemke
Klaus Huemke has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 5461091Abstract: A heat curable coating composition, particular for cathodic electrocoating, comprises(A) from 50 to 95% by weight of a chain or step growth polymerization product having functional groups and(B) from 50 to 5% by weight of a mixture of polymethylenepolyphenyl isocyanates which contains less than 25% of diphenylmethane diisocyanates.Type: GrantFiled: September 9, 1994Date of Patent: October 24, 1995Assignee: BASF AktiengesellschaftInventors: Gerhard Hoffmann, Dieter Faul, Klaus Huemke, John A. Gilbert
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Patent number: 5446084Abstract: Synthetic resins contain, as essential components,A) from 20 to 95% by weight of a crosslinkable binder selected from the group consisting of the polymers, polyadducts or polycondensates having reactive centers in the form of hydroxyl, thio, primary and/or secondary amino groups and/or hydrophilic centers in the form of ammonium, sulfonium and/or phosphonium groups andB) from 5 to 80% by weight of polymers consisting of a core and one or more shells and furthermoreC) from 0 to 10% by weight of one or more crosslinking agents andD) from 0 to 10% by weight of a pigment formulation consisting of one or more pigments and a resin having surfactant properties andE) from 0 to 10% by weight of additives and/or assistants.Type: GrantFiled: March 8, 1993Date of Patent: August 29, 1995Assignee: BASF Lacke+ Farben AGInventors: Klaus Huemke, Gerhard Hoffmann, Dieter Faul
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Patent number: 5401823Abstract: Binder systems suitable for electrocoating and consisting of a base resin A which carries groups which can be protonated with acids or cationic quaternary groups and, if desired, hydroxyl or thiol groups, a crosslinking component B which carries at least two blocked isocyanate groups per molecule and an organic iron compound C which is partially or completely soluble in water, as a catalyst for the thermal crosslinking of components A and B, and if desired, an additive D which increases the catalytic activity of C, are used to prepare dispersions which are used for electrocoating.Type: GrantFiled: March 8, 1993Date of Patent: March 28, 1995Assignee: BASF Lacke & Farben AGInventors: Klaus Huemke, Gerhard Hoffmann, Dieter Faul, Rainer Blum
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Patent number: 5389705Abstract: Novel polymers which are suitable as binders are obtainable by reacting(A) a base resin which has an average molecular weight M.sub.w of from 200 to 5,000 and contains on average from 1 to 3 epoxy or isocyanato groups as the reactive groups per moleculewith(B) a mixture of(B1) 5 to 50% by weight of polyisobutylene which is terminated with primary amino groups and has an average molecular weight M.sub.w of from 500 to 5,000 and(B2) 5-95% by weight of an amidoamine which carries primary amino groups and is obtainable by condensation of diprimary diamines of 2 to 20 carbon atoms with aliphatic C.sub.2 -C.sub.44 -dicarboxylic acids,the amounts being such that from 1 to 5 equivalents of primary amino groups of (B) are present per equivalent of reactive groups of (A).Type: GrantFiled: August 6, 1993Date of Patent: February 14, 1995Assignee: BASF Lacke + Farben AktiengesellschaftInventors: Klaus Huemke, Helmut Fobbe, Konrad Knoll
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Patent number: 5385977Abstract: Polymeric reaction products are obtained by reactingI) prepolymers obtained fromA) polyoxyalkylenes which have an average molecular weight M.sub.n of from 140 to 10,000 and contain on average from 1.5 to 3.0a.sub.1) primary or secondary amino groups ora.sub.2) epoxy groupsper molecule andB) polymers which are based on conjugated dienes, have an average molecular weight M.sub.n of from 250 to 50,000 and contain on average from 1.5 to 3.0b.sub.1) primary or secondary amino groups orb.sub.2) epoxy groupsper molecule, the components (a.sub.1) and (b.sub.2) or (a.sub.2) and (b.sub.1) being reacted with one another so that from at least an amino equivalent excess to 3 amino equivalents of component (a.sub.1) or (b.sub.1) are present per epoxide equivalent of component (a.sub.2) or (b.sub.2),withII) at least one compound which forms free radicals.Type: GrantFiled: March 31, 1994Date of Patent: January 31, 1995Assignee: BASF Lacke + Farben AGInventors: Dieter Faul, Gerhard Hoffmann, Klaus Huemke, Ulrich Heimann, John A. Gilbert
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Patent number: 5384386Abstract: Synthetic resins are based on products which are obtainable by reactingA) epoxy-carrying resins based ona.sub.1) polyhydric phenols anda.sub.2) at least one compound selected from the group consisting of.alpha..sub.1) polyoxyalkylenepolyols,.alpha..sub.2) polyoxyalkylenepolyepoxides,.alpha..sub.3) polyoxyalkylenepolyamines and.alpha..sub.4) polyhydric aliphatic alcohols and,if desired,a.sub.3) phenolic compounds which react monofunctionally toward epoxides,B) monocarboxylic acids of 5 to 30 carbon atoms,C) amines which contain at least one primary and one tertiary amino group andD) formaldehyde-donating compounds.Type: GrantFiled: March 8, 1994Date of Patent: January 24, 1995Assignee: BASF Lacke & Farben AGInventors: Klaus Huemke, Gerhard Hoffmann
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Patent number: 5356959Abstract: Epoxy resins obtainable by reactingA) a polyfunctional epoxide, which carries on average 1.5 to 2.5 epoxy groups per molecule and has an epoxide equivalent weight of from 100 to 2000, with based on 1 mol of epoxy groupsB) from 0.1 to 0.5 mol of an alkylphenol, the alkyl groups of which carry from 6 to 20 carbon atoms, andC) from 1 to 100 mmol of a polyoxyalkylenediol obtained from 1,2-propylene oxide, or of a copolymer obtained from 1,2-propylene oxide and other alkylene oxides, which has an average molecular weight of from 200 to 5000 and, on average, from 1 to 4 sulfonic acid groups bonded to methyl groups per molecule, and alsoD) from 0.2 to 0.3 mol of a diol, which isd1) a phenolic diol and/ord2) a polyoxyalkylenediol which has an average molecular weight of from 200 to 5000,with the proviso that the reaction product has an epoxide equivalent weight of from 1000 to 5000, can be converted to pigment resins suitable for electrodeposition coating and pigment pastes can then be prepared from said resins.Type: GrantFiled: July 27, 1993Date of Patent: October 18, 1994Assignee: BASF Lacke & Farben AktiengesellschaftInventors: Klaus Huemke, Christian Sinn
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Patent number: 5352525Abstract: Water-thinnable coating compositions useful in electrocoating compriseA. a mixture ofA.sub.1. 50-95% by weight of one or more oligomeric or polymeric polyaddition or polycondensation compounds which have on average a molecular weight of from 200 to 20,000 and contain per molecule at least two hydroxyl groups and at least two primary and/or secondary amino groups, andA.sub.2. 5-50% by weight of a crosslinker that is reactive toward component A.sub.1, andB. a mixture ofB.sub.1. 90-99.9% by weight of one or more radical-polymerizable compounds which have an average molecular weight of from 100 to 10,000 and contain per molecule at least two olefinic double bonds, andB.sub.2. 0.1-10% by weight of a free radical initiator having a decomposition temperature within the range 50-150.degree. C.,the ratio of mixture A to mixture B being from 10:1 to 1:10 and mixture A being substantially chemically inert toward mixture B.Type: GrantFiled: February 25, 1993Date of Patent: October 4, 1994Assignee: BASF Lacke + Farben AGInventors: Klaus Huemke, Dieter Faul, Ulrich Heimann
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Patent number: 5350636Abstract: A synthetic resin contains, as essential components,A) a crosslinkable binder selected from the group consisting of the polymers, polyadducts or polycondensates having reactive centers in the form of hydroxyl, thio or primary or secondary amino groups andB) a crosslinking agent based on at least one polyoxyalkylene polyisocyanate andC) a crosslinking agent which differs from (B) and is based on.gamma..sub.1) a polyfunctional isocyanate which differs from (B) or.gamma..sub.2) an organic compound which reacts at elevated temperatures with free amino groups of component (A) with amide formation or.gamma..sub.3) an organic compound which reacts at elevated temperatures with hydroxyl groups of component (A) with transesterification or.gamma..sub.4) a phenolic Mannich base ora mixture of two or more crosslinking agents (.gamma..sub.1) to (.gamma..sub.4).Type: GrantFiled: November 20, 1992Date of Patent: September 27, 1994Assignee: BASF Lacke+Farben AktiengesellschaftInventors: Klaus Huemke, Dieter Faul, Gerhard Hoffmann
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Patent number: 5336722Abstract: Polymeric reaction products are obtained by reactingI) prepolymers obtained fromA) polyoxyalkylenes which have an average molecular weight M.sub.n of from 140 to 10,000 and contain on average from 1.5 to 3.0a.sub.1) primary or secondary amino groups ora.sub.2) epoxy groups per molecule andB) polymers which are based on conjugated dienes, have an average molecular weight M.sub.n of from 250 to 50,000 and contain on average from 1.5 to 3.0b.sub.1) primary or secondary amino groups orb.sub.2) epoxy groups per molecule, the components (a.sub.1) and ( b.sub.2) or (a.sub.2) and (b.sub.1) being reacted with one another so that from at least an amino equivalent excess to 3 amino equivalents of component (a.sub.1) or (b.sub.1) are present per epoxide equivalent of component (a.sub.2) or (b.sub.2), withII) at least one compound which forms free radicals.Type: GrantFiled: November 20, 1992Date of Patent: August 9, 1994Assignee: BASF Lacke+Farben AktiengesellschaftInventors: Dieter Faul, Gerhard Hoffmann, Klaus Huemke, Ulrich Heimann, John A. Gilbert
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Patent number: 5283269Abstract: Epoxy resins with urethane groups, containing on average per molecule from 0.5 to 5 groups of the formula I ##STR1## where the substituents R.sup.1 and R.sup.2 are C.sub.1 -C.sub.8 -alkyl groups, which may also be linked together to form five- or six-membered rings, which may contain an oxygen atom, or are each phenyl, are useful in electrocoating.Type: GrantFiled: January 14, 1993Date of Patent: February 1, 1994Assignee: BASF Lacke + Farben AktiengesellschaftInventors: Klaus Huemke, Dirk Lawrenz, Ulrich Heimann
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Patent number: 5274011Abstract: Cationic resins are obtainable by reaction ofA) a carboxyl-containing copolymer containing as comonomersa) 35-100 mol % of butadiene,b) 0-45 mol % of acrylonitrile, andc) 0-20 mol % of further comonomers, which has an average molecular weight of 500-50,000 and carries on average from 1.5 to 4 carboxyl groups per molecule, andB) a condensation product ofd) a polybasic aliphatic C.sub.10 -C.sub.100 -carboxylic acid, ande) an amine which is polyfunctional in respect of primary and secondary amino groups,the amount of e) having been determined in such a way that, arithmetically, there are from 1.05 to 4 amino groups for every carboxyl group of d),with the proviso that the amount of B) is chosen in such a way that there are from 1.05 to 4 mol of amino groups per mole of the carboxyl groups present in A).Type: GrantFiled: October 22, 1992Date of Patent: December 28, 1993Assignee: BASF Lacke+Farben AktiengesellschaftInventors: Dieter Faul, Gerhard Hoffmann, Klaus Huemke, Ulrich Heimann
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Patent number: 5258460Abstract: Polymeric reaction products useful as additions to electrocoating baths are obtainable fromA. a polyoxyalkylene which has an average molecular weight M.sub.n of from 140 to 10,000 and contains on average from 1.5 to 3.0 primary and/or secondary amino groups andB. a polymer which is based on a conjugated diene, has an average molecular weight M.sub.n of from 250 to 50,000, contains on average from 1.5 to 3.0 epoxy groups per molecule and is obtainable by reacting a hydroxyl- or carboxyl-containing polymer with a glycidyl compound.Type: GrantFiled: March 25, 1992Date of Patent: November 2, 1993Assignee: BASF Lacke+ Farben AktiengesellschaftInventors: Dieter Faul, Gerhard Hoffmann, Klaus Huemke, Ulrich Heimann, John A. Gilbert
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Patent number: 5212309Abstract: Chemiluminescenct 3-aminobenzene-1,2,4,5-tetracarboxylic dihydrazides.Type: GrantFiled: February 3, 1992Date of Patent: May 18, 1993Assignee: BASF AktiengesellschaftInventors: Ernst Schefczik, Klaus Huemke
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Patent number: 5188716Abstract: A heat-curable coating composition for cathodic electrocoating which becomes water-thinnable on protonation with an acid contains(A) 50-95% by weight of a polycondensation or polyaddition product having an average molecular weight of from 500 to 20,000 and containing primary and/or secondary hydroxyl groups and primary, secondary and/or tertiary amino groups, and(B) 5-50% by weight of a crosslinking agent obtainable by reactinga) an aliphatic polyhydroxy compound andb) an aromatic polyhydroxy compound withc) an aliphatic and/or cycloaliphatic polyisocyanate andd) a blocking agent.Type: GrantFiled: February 8, 1990Date of Patent: February 23, 1993Assignee: BASF Lack + Farben AktiengesellschaftInventors: Thomas Schwerzel, Hans Schupp, Klaus Huemke, Dieter Faul, Ulrich Heimann
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Patent number: 5177125Abstract: A two-phase cathodic electrocoat is obtainable by coating an electrically conducting substrate with a mixture containingA) an aqueous cationic dispersion of a polycondensation or polyaddition product,B) an aqueous cationic dispersion of a polycondensation or polyaddition product having a glass transition temperature of from -80.degree. to 20.degree. C., the polymers of dispersions (A) and (B) being mutually incompatible, and C) optionally a crosslinking agent, a pigment paste, auxiliaries and/or additives, and then baking.Type: GrantFiled: August 14, 1991Date of Patent: January 5, 1993Assignee: BASF Lacke & Farben AktiengeselllschaftInventors: Thomas Schwerzel, Hans Schupp, Klaus Huemke, Ulrich Heimann
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Patent number: 5096555Abstract: A heat-curable, cathodically depositable aqueous electrocoating composition contains(A) from 50 to 95% by weight of a polymerization or polycondensation or polyaddition product which has an average molecular weight of from 200 to 20,000 and primary and/or secondary hydroxyl groups and primary, secondary and/or tertiary amino groups and is water-thinnable on protonation with an acid, and(B) from 5 to 50% by weight of a water-thinnable crosslinking agent having cationic groups or groups which are convertible into cationic groups by protonation with an acid.Type: GrantFiled: January 25, 1990Date of Patent: March 17, 1992Assignee: BASF AktiengesellschaftInventors: Hans Schupp, Thomas Schwerzel, Klaus Huemke, Dieter Faul