Patents by Inventor Klaus Mühlbach

Klaus Mühlbach has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20230406968
    Abstract: A process for the preparation of polyisobutene derivatives involves bringing an oxygen-containing gas in contact with polyisobutene, in the presence of a photosensitizer, and irradiating the reaction mixture. The polyisobutene derivatives are useful, for example, in hydrocarbon mixtures or hydrocarbon-containing oils.
    Type: Application
    Filed: November 9, 2021
    Publication date: December 21, 2023
    Applicant: BASF SE
    Inventors: Bernd Schaefer, Klaus Muehlbach, Paul Lederhose, Wolfgang Grabarse, Andreas Minke, Thorsten Schoeppe
  • Publication number: 20230365726
    Abstract: A novel process can be used for preparing high-reactivity isobutene homo- or copolymers, by polymerizing isobutene or an isobutene-containing monomer mixture in the presence of a polymerization catalyst.
    Type: Application
    Filed: July 27, 2021
    Publication date: November 16, 2023
    Applicant: BASF SE
    Inventors: Paul Lederhose, Klaus Muehlbach, Sergei V. Kostjuk, Irina V. Vasilenko, Ivan A. Berezianko
  • Patent number: 11634654
    Abstract: An olefin-carboxylic acid copolymer, containing at least one free carboxylic acid side group, or a nitrogen compound quaternized with epoxide in the presence of an olefin-carboxylic acid copolymer, containing at least one free carboxylic acid side group, can be used as a fuel additive or lubricant additive. Processes can be used for preparing additives of this kind and fuels and lubricants additized therewith, such as a detergent additive. These additives, fuels, and lubricants can be used for reduction or prevention of deposits in injection systems of direct injection diesel engines, especially in common rail injection systems; for reduction of fuel consumption of direct injection diesel engines, especially of diesel engines with common rail injection systems; and for minimization of power loss in direct injection diesel engines, especially in diesel engines with common rail injection systems. The additives can also be used for gasoline fuels, especially for operation of DISI engines.
    Type: Grant
    Filed: March 25, 2021
    Date of Patent: April 25, 2023
    Assignee: BASF SE
    Inventors: Maxim Peretolchin, Harald Böhnke, Wolfgang Grabarse, Ludwig Völkel, Markus Hansch, Günter Oetter, Aaron Flores-Figueroa, Klaus Mühlbach, Ivette Garcia Castro
  • Patent number: 11629206
    Abstract: The present invention relates to a novel process for preparing high-reactivity isobutene homo- or copolymers with a content of terminal vinylidene double bonds per polyisobutene chain end of at least 80 mol %. The present invention further relates to novel isobutene polymers.
    Type: Grant
    Filed: March 26, 2021
    Date of Patent: April 18, 2023
    Assignee: BASF SE
    Inventors: Rosa Corberan Roc, Klaus Muehlbach, Thomas Wettling, Sergei V. Kostjuk, Irina Vasilenko, Dmitryi Shiman
  • Patent number: 11359034
    Abstract: The present invention relates to a novel process for preparing high-reactivity isobutene homo- or copolymers with a content of terminal vinylidene double bonds per polyisobutene chain end of at least 70 mol %. The present invention further relates to novel isobutene polymers.
    Type: Grant
    Filed: August 7, 2018
    Date of Patent: June 14, 2022
    Assignee: BASF SE
    Inventors: Rosa Corberan Roc, Klaus Muehlbach, Thomas Wettling, Sergei V. Kostjuk, Irina Vasilenko, Dmitryi Shiman
  • Patent number: 11306161
    Abstract: A process for preparing isobutene homo- or copolymer derivatives by (i) polymerizing isobutene or an isobutene-comprising monomer mixture in the presence of an iron halide-donor complex, an aluminum trihalide-donor complex, or an alkylaluminum halide-donor complex, (ii) reacting a resulting high-reactivity isobutene polymer with a compound which introduces a low molecular weight polar group or a substructure thereof, and (iii) in the case of reaction with a substructure, further reacting to complete the formation of the low molecular weight polar group. The homo- or copolymer derivatives include a radical of a hydrophobic polyisobutene polymer having a number-average molecular weight of 110 to 250 000 and low molecular weight polar groups including amino functions, nitro groups, hydroxyl groups, mercaptan groups, carboxylic acid or carboxylic acid derivative functions, sulfonic acid or sulfonic acid derivative functions, aldehyde functions and/or silyl groups.
    Type: Grant
    Filed: June 30, 2020
    Date of Patent: April 19, 2022
    Assignee: BASF SE
    Inventors: Hannah Maria Koenig, Klaus Muehlbach, Helmut Mach, Ulrich Eichenauer
  • Publication number: 20220049028
    Abstract: The present invention is directed to the use of a quaternized derivative of polyisobutylene as stabiliser in inverse emulsions like inverse emulsions used for a reverse-phase emulsion polymerisation process, e.g. for the polymerisation of acrylamide and ethylenically unsaturated cationic monomers. Such emulsions are e.g. used as flocculant for waste water treatment. The present invention is further directed to inverse emulsions comprising a quaternized derivative of polyisobutylene. The inverse emulsions have sufficiently low viscosity and sufficiently high shear stability. The present invention is further directed to an inverse emulsion polymerisation process, wherein the inverse emulsion comprises a quaternized derivative of polyisobutylene.
    Type: Application
    Filed: December 6, 2019
    Publication date: February 17, 2022
    Applicants: SOLENIS TECHNOLOGIES CAYMAN, L.P., SOLENIS TECHNOLOGIES CAYMAN, L.P.
    Inventors: Herbert HOMMER, Gregor HERTH, Klaus MUEHLBACH, Jochen WAGNER, Rosa CORBERAN ROC
  • Patent number: 11168273
    Abstract: The present invention relates to the use of an olefin-carboxylic acid copolymer, wherein the copolymer comprises at least one free carboxylic acid side group, or of a nitrogen compound quaternized with epoxide in the presence of an olefin-carboxylic acid copolymer, wherein the copolymer comprises at least one free carboxylic acid side group, as a fuel additive or lubricant additive; to processes for preparing additives of this kind, and to fuels and lubricants additized therewith; such as, more particularly, as a detergent additive; for reduction or prevention of deposits in the injection systems of direct injection diesel engines, especially in common rail injection systems, for reduction of the fuel consumption of direct injection diesel engines, especially of diesel engines with common rail injection systems, and for minimization of power loss in direct injection diesel engines, especially in diesel engines with common rail injection systems; and as an additive for gasoline fuels, especially for operation
    Type: Grant
    Filed: December 4, 2014
    Date of Patent: November 9, 2021
    Assignee: BASF SE
    Inventors: Maxim Peretolchin, Harald Böhnke, Wolfgang Grabarse, Ludwig Völkel, Markus Hansch, Günter Oetter, Aaron Flores-Figueroa, Klaus Mühlbach, Ivette Garcia Castro
  • Publication number: 20210253752
    Abstract: The present invention relates to a novel process for preparing high-reactivity isobutene homo- or copolymers with a content of terminal vinylidene double bonds per polyisobutene chain end of at least 80 mol %. The present invention further relates to novel isobutene polymers.
    Type: Application
    Filed: March 26, 2021
    Publication date: August 19, 2021
    Applicant: BASF SE
    Inventors: Rosa Corberan Roc, Klaus Muehlbach, Thomas Wettling, Sergei V. Kostjuk, Irina Vasilenko, Dmitryi Shiman
  • Patent number: 11085001
    Abstract: Novel uses of copolymers for removing and/or reducing the level of deposits in the fuel system and/or injection system of direct injection diesel and/or gasoline engines are provided. What is provided is the use of particular copolymers as fuel additive or lubricant additive; to processes for preparation of such additives, and fuels and lubricants added therewith, such as, more particularly, as a detergent additive; to use of these copolymers for reducing the level of or preventing deposits in the fuel systems and especially the injection systems of direct injection diesel engines, especially in common rail injection systems, for reducing the fuel consumption of direct injection diesel engines, especially of diesel engines with common rail injection systems, and for minimizing power loss in direct injection diesel engines, especially in diesel engines with common rail injection systems; and as an additive for gasoline fuels, especially for operation of DISI engines.
    Type: Grant
    Filed: July 12, 2016
    Date of Patent: August 10, 2021
    Assignee: BASF SE
    Inventors: Ivette Garcia Castro, Maxim Peretolchin, Jochen Mezger, Klaus Muehlbach
  • Publication number: 20210222080
    Abstract: An olefin-carboxylic acid copolymer, containing at least one free carboxylic acid side group, or a nitrogen compound quaternized with epoxide in the presence of an olefin-carboxylic acid copolymer, containing at least one free carboxylic acid side group, can be used as a fuel additive or lubricant additive. Processes can be used for preparing additives of this kind and fuels and lubricants additized therewith, such as a detergent additive. These additives, fuels, and lubricants can be used for reduction or prevention of deposits in injection systems of direct injection diesel engines, especially in common rail injection systems; for reduction of fuel consumption of direct injection diesel engines, especially of diesel engines with common rail injection systems; and for minimization of power loss in direct injection diesel engines, especially in diesel engines with common rail injection systems. The additives can also be used for gasoline fuels, especially for operation of DISI engines.
    Type: Application
    Filed: March 25, 2021
    Publication date: July 22, 2021
    Applicant: BASF SE
    Inventors: Maxim Peretolchin, Harald Böhnke, Wolfgang Grabarse, Ludwig Völkel, Markus Hansch, Günter Oetter, Aaron Flores-Figueroa, Klaus Mühlbach, Ivette Garcia Castro
  • Publication number: 20210214635
    Abstract: An olefin-carboxylic acid copolymer, containing at least one free carboxylic acid side group, or a nitrogen compound quaternized with epoxide in the presence of an olefin-carboxylic acid copolymer, containing at least one free carboxylic acid side group, can be used as a fuel additive or lubricant additive. Processes can be used for preparing additives of this kind and fuels and lubricants additized therewith, such as a detergent additive. These additives, fuels, and lubricants can be used for reduction or prevention of deposits in injection systems of direct injection diesel engines, especially in common rail injection systems: for reduction of fuel consumption of direct injection diesel engines, especially of diesel engines with common rail injection systems; and for minimization of power loss in direct injection diesel engines, especially in diesel engines with common rail injection systems. The additives can also be used for gasoline fuels, especially for operation of DISI engines.
    Type: Application
    Filed: March 25, 2021
    Publication date: July 15, 2021
    Applicant: BASF SE
    Inventors: Maxim Peretolchin, Harald Böhnke, Wolfgang Grabarse, Ludwig Völkel, Markus Hansch, Günter Oetter, Aaron Flores-Figueroa, Klaus Mühlbach, Ivette Garcia Castro
  • Patent number: 10975175
    Abstract: The present invention relates to a novel process for preparing high-reactivity isobutene homo- or copolymers with a content of terminal vinylidene double bonds per polyisobutene chain end of at least 70 mol %. The present invention further relates to novel isobutene polymers.
    Type: Grant
    Filed: July 14, 2017
    Date of Patent: April 13, 2021
    Assignee: BASF SE
    Inventors: Rosa Corberan Roc, Klaus Muehlbach, Thomas Wettling, Sergei V. Kostjuk, Irina Vasilenko, Dmitryi Shiman, Ivan Berazianka
  • Patent number: 10975180
    Abstract: The present invention relates to a process for preparing high-reactivity isobutene homo- or copolymers with a content of terminal vinylidene double bonds per polyisobutene chain end of at least 70 mol %, which comprises polymerizing isobutene or an isobutene-comprising monomer mixture in the presence of an aluminum trihalide-donor complex effective as a polymerization catalyst or an alkylaluminum halide-donor complex effective as a polymerization catalyst, wherein the aluminum trihalide or alkylaluminum halide is treated with at least one inorganic hydrate.
    Type: Grant
    Filed: February 13, 2017
    Date of Patent: April 13, 2021
    Assignee: BASF SE
    Inventors: Rosa Corberan Roc, Klaus Muehlbach, Thomas Wettling, Sergei V. Kostjuk, Irina Vasilenko, Dmitryi Shiman
  • Patent number: 10968294
    Abstract: The present invention relates to a process for preparing high-reactivity isobutene homo- or copolymers with a content of terminal vinylidene double bonds per homo- or copolymer chain end of at least 70 mol % which comprises polymerizing isobutene or an isobutene-comprising monomer mixture in the presence of an aluminum trihalide-donor complex effective as a polymerization catalyst or of an alkylaluminum halide-donor complex, said complex comprising, as the donor, a mixture of at least two organic compounds with at least one ether function each.
    Type: Grant
    Filed: February 13, 2017
    Date of Patent: April 6, 2021
    Assignee: BASF SE
    Inventors: Rosa Corberan Roc, Klaus Muehlbach, Thomas Wettling, Sergei V. Kostjuk, Irina Vasilenko, Dmitryi Shiman
  • Publication number: 20200325253
    Abstract: A process for preparing isobutene homo- or copolymer derivatives by (i) polymerizing isobutene or an isobutene-comprising monomer mixture in the presence of an iron halide-donor complex, an aluminum trihalide-donor complex, or an alkylaluminum halide-donor complex, (ii) reacting a resulting high-reactivity isobutene polymer with a compound which introduces a low molecular weight polar group or a substructure thereof, and (iii) in the case of reaction with a substructure, further reacting to complete the formation of the low molecular weight polar group. The homo- or copolymer derivatives include a radical of a hydrophobic polyisobutene polymer having a number-average molecular weight of 110 to 250 000 and low molecular weight polar groups including amino functions, nitro groups, hydroxyl groups, mercaptan groups, carboxylic acid or carboxylic acid derivative functions, sulfonic acid or sulfonic acid derivative functions, aldehyde functions and/or silyl groups.
    Type: Application
    Filed: June 30, 2020
    Publication date: October 15, 2020
    Applicant: BASF SE
    Inventors: Hannah Maria KOENIG, Klaus MUEHLBACH, Helmut MACH, Ulrich EICHENAUER
  • Publication number: 20200317832
    Abstract: The present invention relates to a process for preparing high- reactivity isobutene homo- or copolymers with a content of terminal vinylidene double bonds per polyisobutene chain end of at least 70 mol %, which comprises polymerizing isobutene or an isobutene-comprising monomer mixture in the presence of an aluminum trihalide-donor complex effective as a polymerization catalyst or an alkylaluminum halide-donor complex effective as a polymerization catalyst, wherein the aluminum trihalide or alkylaluminum halide is treated with at least one inorganic hydrate.
    Type: Application
    Filed: February 13, 2017
    Publication date: October 8, 2020
    Applicant: BASF SE
    Inventors: Rosa CORBERAN ROC, Klaus MUEHLBACH, Thomas WETTLING, Sergei V. KOSTJUK, Irina VASILENKO
  • Patent number: 10745496
    Abstract: A process for preparing isobutene homo- or copolymer derivatives by (i) polymerizing isobutene or an isobutene-comprising monomer mixture in the presence of an iron halide-donor complex, an aluminum trihalide-donor complex, or an alkylaluminum halide-donor complex, (ii) reacting a resulting high-reactivity isobutene polymer with a compound which introduces a low molecular weight polar group or a substructure thereof, and (iii) in the case of reaction with a substructure, further reacting to complete the formation of the low molecular weight polar group. The homo- or copolymer derivatives include a radical of a hydrophobic polyisobutene polymer having a number-average molecular weight of 110 to 250 000 and low molecular weight polar groups including amino functions, nitro groups, hydroxyl groups, mercaptan groups, carboxylic acid or carboxylic acid derivative functions, sulfonic acid or sulfonic acid derivative functions, aldehyde functions and/or silyl groups.
    Type: Grant
    Filed: February 18, 2016
    Date of Patent: August 18, 2020
    Assignee: BASF SE
    Inventors: Hannah Maria Koenig, Klaus Muehlbach, Helmut Mach, Ulrich Eichenauer
  • Publication number: 20200207887
    Abstract: The present invention relates to a novel process for preparing high-reactivity isobutene homo- or copolymers with a content of terminal vinylidene double bonds per polyisobutene chain end of at least 70 mol %. The present invention further relates to novel isobutene polymers.
    Type: Application
    Filed: August 7, 2018
    Publication date: July 2, 2020
    Applicant: BASF SE
    Inventors: Rosa CORBERAN ROC, Klaus MUEHLBACH, Thomas WETTLING, Sergei V. KOST JUK, Irina VASILENKO, Dmitryi SHIMAN
  • Publication number: 20190284313
    Abstract: The present invention relates to a novel process for preparing high-reactivity isobutene homo- or copolymers with a content of terminal vinylidene double bonds per polyisobutene chain end of at least 70 mol %. The present invention further relates to novel isobutene polymers.
    Type: Application
    Filed: July 14, 2017
    Publication date: September 19, 2019
    Applicant: BASF SE
    Inventors: Rosa CORBERAN ROC, Klaus MUEHLBACH, Thomas WETTLING, Sergei V. KOSTJUK, Irina VASILENKO, Dmitryi SHIMAN, Ivan BERAZIANKA