Abstract: The invention relates to a rechargeable electrochemical battery cell. Said cell comprises a negative electrode (5), an electrolyte (19), and a positive electrode, the negative electrode (5) having a an electronically conductive substrate (14), onto which an active mass (15) is electrolytically deposited during the charging of the cell. The aim of the invention is to significantly improve the operational safety of said cell. To achieve this, the cell in contact with the substrate (14)of the negative electrode (5) has a porous structure (16)formed by solid particles (17), which is configured and positioned in such a way that the active mass (15), which is deposited during the charging of the cell, penetrates from the surface of the substrate (14) into the pores (18) of the latter and is deposited again therein.

Abstract: A rechargeable electrochemical battery cell having a negative electrode (5), an electrolyte (19), and a positive electrode (4), the negative electrode (5) having an electronically conductive substrate (14), on which an active mass (15) is electrolytically deposited when the cell is charged. A significant improvement of the operating safety is achieved in that the cell has a porous structure (16) made of solid particles (17) in contact with the substrate (14) of the negative electrode (5), which porous structure is formed and positioned in such a manner that the active mass (15) deposited during charging of the cell penetrates from the surface of the substrate (14) into its pores (18) and is further deposited therein.

Abstract: Rechargeable electrochemical cell, with a negative electrode, which in charged state contains an active metal selected from the group of the alkaline metals, the alkaline-earth metals and the metals of the second subgroup of the periodic table of elements; an electrolyte solution based on sulfur dioxide; and a positive electrode containing the active metal, from where ions come out into the electrolyte solution during the charging process. A self discharge reaction takes place at the negative electrode, for which the sulfur dioxide of the an electrolyte solution reacts with the active metal of the negative electrode to form a poorly soluble compound. According to the invention, the electrochemical charge quantity of the sulfur dioxide in the cell, calculated with one faraday per mole sulfur dioxide, is smaller than the charge amount of the active metal which can be theoretically electrochemically accumulated in the positive electrode.

Abstract: Nonaqueous electrochemical cell (9) with a negative electrode (4), an electrolytic solution and a positive electrode (3). The operational safety is increased by the fact that the cell contains a salt (10) in solid state in the area of at least one of the two electrodes (3,4).

Abstract: A method and device for the detection of substances such as nitrotoluene, trinitrotoluene, dinitrotoluene, or derivatives, wherein a working electrode and an opposing electrode are contacted with the substance via a viscous electrolyte layer and a voltage is applied to the working electrode whose value is increased and decreased at least once with substantially equal beginning and end values within a predetermined time period, wherein the current strength is determined during this at least one measurement cycle in dependence on the applied voltage, is distinguished in that a plurality of measurement cycles are scanned, and differences of current values of sequential measurement cycles are determined and, in the event of the occurrence of a cathode current maximum, the associated voltage value is determined, held constant and the current strength extracted.

Abstract: A method for the detection of not easily volatized substances in particular of nitrotoluene, trinitrotoluene, dinitrotoluene, or derivatives of nitrotoluene as well as chemical warfare substances such as Clark, Lewisite, Lost, Sarin, Soman, Tabun or the like in soil, liquid and gases, wherein an electrode configuration, comprising at least a working electrode and an opposing electrode, is brought into contact with a substance under examination via an electrolyte and a voltage is applied to the working electrode whose value is increased and decreased at least once with substantially equal beginning and end values within a predetermined time period, wherein the current strength is determined during this at least one measurement cycle in dependence on the applied voltage, is distinguished in that a plurality of measurement cycles are scanned, and differences of current values of sequential measurement cycles are determined and, in the event of the occurrence of a cathode current maximum, the associated voltage v