Abstract: Alkali-swellable rheology modifier comprising a core-shell polymer comprising a core polymer and a shell comprising at least one shell copolymer layer at least partially cross-linked and containing a mole percent of crosslinking agent greater than the mole percent of crosslinking agent in the core polymer, provided if the mole percent of crosslinking agent in the core polymer is zero, then either the core polymer is greater than 60 wt % of the core-shell polymer; the core polymer comprises at least one associative monomer; at least one shell copolymer layer copolymer comprises at least one associative monomer; and/or the at least one shell copolymer layer that is at least partially cross-linked comprises greater than 3 mole% crosslinking agent.

Abstract: A method of making a pyranine monomer composition comprises the step of reacting pyranine with a functionalizing agent that functionalizes the pyranine molecule with a polymerizable functional group to provide a composition of functionalized pyranine monomers, said functionalization reaction taking place in an aqueous reaction medium, and in the presence of a molar excess of said functionalizing agent, such that the functionalization reaction product is a monomer composition substantially free of unfunctionalized pyranine compound. The pyranine monomer compositions made by the method can be used to make fluorescent tagged water soluble polymer compositions that advantageously are substantially free of unpolymerized pyranine. The fluorescent tagged water soluble polymer compositions can be used in a method of inhibiting scale in industrial water systems.

Abstract: Disclosed are fluorescent water-soluble water treatment polymers suitable for use in scale inhibition or suppression of corrosion in industrial water systems, the water treatment polymers especially comprising fluorescent coumarin, fluorescein, rhodamine, and Nile blue derivative monomers. Also disclosed are methods of making the monomers, methods of making the polymers, methods of inhibiting scale in an industrial water system, methods of suppressing corrosion in an industrial water system, and methods of using the polymers in coagulation and flocculation, and in cleaning applications.

Abstract: Alkali-swellable rheology modifier comprising a core-shell polymer comprising a core polymer and a shell comprising at least one shell copolymer layer at least partially cross-linked and containing a mole percent of crosslinking agent greater than the mole percent of crosslinking agent in the core polymer, provided if the mole percent of crosslinking agent in the core polymer is zero, then either the core polymer is greater than 60 wt % of the core-shell polymer; the core polymer comprises at least one associative monomer; at least one shell copolymer layer copolymer comprises at least one associative monomer; and/or the at least one shell copolymer layer that is at least partially cross-linked comprises greater than 3 mole % crosslinking agent.

Abstract: A fluorescent water treatment polymer comprises at least one water soluble carboxylic acid monomer other than maleic acid, at least one sulfonated pyrene-containing fluorescent monomer, and at least one phosphino group wherein the phosphorous atom of the phosphino group is in the polymer backbone. Additional monomers can be present, with the proviso that if maleic acid is present it comprises no greater than 75 mol % of the polymer. Surprisingly, it has been found that when the phosphino group is present the polymers exhibit an unexpectedly strong fluorescent signal strength. The signal strength of the fluorescent monomer in the polymer is further enhanced when the polymer comprises no greater than 75 mol % maleic acid.

Abstract: A method of inhibiting carbonate scale in an industrial water system includes the steps of dosing the industrial water system with a water treatment polymer comprising at least 60 mol % of carboxylic acid monomer and a quaternized naphthalimide fluorescent monomer as disclosed herein, and then monitoring the fluorescence of the water system. If both maleic acid and phosphino moieties are included in the water treatment polymer, then the maleic acid is present as no greater than 70 mol % of the water treatment polymer. If the polymer contains a sulfonic acid monomer, the polymer is a fluorescence efficient polymer.

Abstract: Disclosed are fluorescent water-soluble water treatment polymers suitable for use in scale inhibition in industrial water systems, the water treatment polymers comprising non-quaternized fluorescent naphthalimide derivative monomers. Also disclosed are methods of making the monomers, methods of making the polymers, methods of inhibiting scale in an industrial water system, and methods of using the polymers in coagulation and flocculation, and in cleaning applications.

Abstract: A method of inhibiting scale in an industrial water system includes the steps of dosing the industrial water system with a water treatment polymer comprising at least 10 mol % of carboxylic acid monomer and a quaternized naphthalimide fluorescent monomer as disclosed herein, and then monitoring the fluorescence of the water system. The polymers are also useful for flocculation and coagulation in wastewater treatment.

Abstract: A method of inhibiting scale in an industrial water system includes the steps of dosing the industrial water system with a water treatment polymer comprising at least 10 mol % of carboxylic acid monomer and a quaternized naphthalimide fluorescent monomer as disclosed herein, and then monitoring the fluorescence of the water system. The polymers are also useful for flocculation and coagulation in wastewater treatment.

Abstract: A method of inhibiting scale in an industrial water system includes the steps of dosing the industrial water system with a water treatment polymer comprising at least 10 mol % of carboxylic acid monomer and a quaternized naphthalimide fluorescent monomer as disclosed herein, and then monitoring the fluorescence of the water system. The polymers are also useful for flocculation and coagulation in wastewater treatment.

Abstract: Alkali-swellable rheology modifier comprising a core-shell polymer comprising a core polymer and a shell comprising at least one shell copolymer layer at least partially cross-linked and containing a mole percent of crosslinking agent greater than the mole percent of crosslinking agent in the core polymer, provided if the mole percent of crosslinking agent in the core polymer is zero, then either the core polymer is greater than 60 wt % of the core-shell polymer; the core polymer comprises at least one associative monomer; at least one shell copolymer layer copolymer comprises at least one associative monomer; and/or the at least one shell copolymer layer that is at least partially cross-linked comprises greater than 3 mole % crosslinking agent.

Abstract: A method of inhibiting scale in an industrial water system includes the steps of dosing the industrial water system with a water treatment polymer comprising at least 10 mol % of carboxylic acid monomer and a quaternized naphthalimide fluorescent monomer as disclosed herein, and then monitoring the fluorescence of the water system. The polymers are also useful for flocculation and coagulation in wastewater treatment.

Abstract: A fluorescent water treatment polymer comprises at least one water soluble carboxylic acid monomer other than maleic acid, at least one sulfonated pyrene-containing fluorescent monomer, and at least one phosphino group wherein the phosphorous atom of the phosphino group is in the polymer backbone. Additional monomers can be present, with the proviso that if maleic acid is present it comprises no greater than 75 mol % of the polymer. Surprisingly, it has been found that when the phosphino group is present the polymers exhibit an unexpectedly strong fluorescent signal strength. The signal strength of the fluorescent monomer in the polymer is further enhanced when the polymer comprises no greater than 75 mol % maleic acid.

Abstract: A method of making a pyranine monomer composition comprises the step of reacting pyranine with a functionalizing agent that functionalizes the pyranine molecule with a polymerizable functional group to provide a composition of functionalized pyranine monomers, said functionalization reaction taking place in an aqueous reaction medium, and in the presence of a molar excess of said functionalizing agent, such that the functionalization reaction product is a monomer composition substantially free of unfunctionalized pyranine compound. The pyranine monomer compositions made by the method can be used to make fluorescent tagged water soluble polymer compositions that advantageously are substantially free of unpolymerized pyranine. The fluorescent tagged water soluble polymer compositions can be used in a method of inhibiting scale in industrial water systems.

Abstract: The present invention is directed to a cross-linked scale control agent particle comprising: a scale control agent and a cross-linker. The scale control agent is cross-linked by the cross-linker. The present invention is also directed to a cross-linked organic-based crystalline inhibitor particle comprising: an organic-based crystalline inhibitor and a cross-linker. The organic-based crystalline inhibitor is cross-linked by the cross-linker. The present invention is also directed to the use of cross-linkers which can also act as benefit agents and to the use of capping and extension agents which act as further benefit agents The present invention is further directed to a particle comprising more than one cross-linked active agents; the active agent may be a combination of a scale control agent and an organic-based crystalline inhibitor.

Abstract: A dried rheology modifier composition comprises a swellable emulsion polymer and a water soluble support polymer. In one embodiment the swellable emulsion polymer is polymerized in the presence of the water soluble support polymer. In one embodiment the swellable emulsion polymer is blended with the water soluble support polymer. The drying can be accomplished by spray drying, resulting in a non-tacky powder having good shelf life. The dried rheology modifiers can be subjected to a further heat treatment which can result in a rheology modifier that imparts a short flow characteristic to product formulations. The swellable emulsion polymer can be alkali swellable or acid swellable. The water soluble support polymer can be a polysaccharide or a derivative thereof, or a polyvinyl acetate or derivative thereof.

Abstract: Hybrid dendrite copolymer compositions include a hybrid dendrite copolymer including at least one ethylenically unsaturated first monomer, at least one second ethylenically unsaturated second monomer and a naturally derived hydroxyl containing chain transfer agent as an end group. The at least one first and second ethylenically unsaturated monomers are on separate side chains of the naturally derived hydroxyl containing chain transfer agent. Methods of preparing a hybrid dendrite copolymer are also included.

Abstract: Polysaccharide alkali swellable rheology modifiers include an emulsion polymer including at least one polysaccharide portion and at least one synthetic portion wherein the at least one synthetic portion is obtained from at least one anionic ethylenically unsaturated monomer, at least one nonionic ethylenically unsaturated monomer or a combination thereof, wherein at least one of the nonionic ethylenically unsaturated monomers is a hydrophobic ethylenically unsaturated monomer, as well as methods of making polysaccharide alkali swellable rheology modifiers.

Abstract: Polysaccharide alkali swellable rheology modifiers include an emulsion polymer including at least one polysaccharide portion and at least one synthetic portion wherein the at least one synthetic portion is obtained from at least one anionic ethylenically unsaturated monomer, at least one nonionic ethylenically unsaturated monomer or a combination thereof, wherein at least one of the nonionic ethylenically unsaturated monomers is a hydrophobic ethylenically unsaturated monomer, as well as methods of making polysaccharide alkali swellable rheology modifiers.

Abstract: Polysaccharide alkali swellable rheology modifiers include an emulsion polymer including at least one polysaccharide portion and at least one synthetic portion wherein the at least one synthetic portion is obtained from at least one anionic ethylenically unsaturated monomer, at least one nonionic ethylenically unsaturated monomer or a combination thereof; wherein at least one of the nonionic ethylenically unsaturated monomers is a hydrophobic ethylenically unsaturated monomer, as well as methods of making polysaccharide alkali swellable rheology modifiers.