Abstract: A thermal treatment apparatus includes a treatment tank including a treatment chamber to perform thermal treatment on toner particles; a toner particle supply unit configured to supply toner particles into the treatment chamber; and a hot air supply unit including a supply port to supply hot air into the treatment chamber. The supply port of the hot air supply unit is disposed on a ceiling of the treatment chamber. The treatment tank further includes: a columnar member that is vertically disposed at the center inside of the treatment chamber; and a protruded member that is disposed at an upper end of the columnar member and has an approximately conical shape protruding toward the ceiling. The columnar member has a cylindrical shape and a radius of curvature RCP (mm) of an upper end edge in a vertical cross-section thereof is 5<RCP<75.

Abstract: Provided is a toner that expresses all of low-temperature fixability, transferability, and scratch resistance at high levels. The toner is a toner including a toner particle containing a binder resin, a wax, and an inorganic fine particle, wherein when an outflow start temperature measured with the toner is represented by T1 (° C.), the inorganic fine particle always has a thermal expansion coefficient of ?0.1×10?6 (/K) or less in a temperature range of from 30° C. or more to T1° C. or less, the thermal expansion coefficient being determined by X-ray diffraction and wherein a content of the wax is 3.0 mass % or more and 20.0 mass % or less with respect to a mass of the toner particle.

Abstract: A toner comprising a toner particle comprising a binder resin including a polyester resin, and a polyolefin resin having a sulfonic acid group, wherein the polyolefin resin having a sulfonic acid group is a polymer in which a vinyl polymer is bonded to a polyolefin, a content ratio of a monomer unit containing a sulfonic acid group in the vinyl polymer is from 1.0 mass % to 20.0 mass %, in a FT-IR spectrum obtained through measurement of a large particle size toner and a small particle size toner resulting from dividing, on a number basis, the toner into two substantially equal parts, a ratio of an intensity of a maximum absorption peak in a range from 1130 cm?1 to 1170 cm?1 with respect to an intensity of a maximum absorption peak in a range from 1713 cm?1 to 1723 cm?1 exhibits a specific relationship.

Abstract: A toner including a toner particle comprising a binder resin and a crystalline polyester, wherein the binder resin contains a polyester having a structure represented by the following formula (1): in formula (1), Rs each independently represent hydrogen, a methyl group, or a phenyl group; A represents a polyester segment; B represents a polyester segment or any functional group selected from the group consisting of —R1OH, —R1COOH, and —R1NH2 wherein R1 represents a single bond or a C1-4 alkylene group; and the average repeat number n is 10 to 80.

Abstract: A toner containing a toner particle that contains a binder resin including a polyester resin, and a polyolefin resin having —COOM that is a neutralized carboxy group with a monovalent metal ion M, wherein the polyolefin resin having —COOM is a polymer in which a vinyl polymer is bonded to a polyolefin, a content of a monomer unit containing —COOM in the polyolefin resin having —COOM is 1 to 20 mass %, and in a FT-IR spectrum obtained through measurement of a large particle size-side particle group and a small particle size-side particle group obtained by dividing the toner into two substantially equal parts, on a number basis, a ratio of the intensity of a maximum absorption peak in a range from 1545 cm?1 to 1555 cm?1 with respect to the intensity of a maximum absorption peak in a range from 1713 cm?1 to 1723 cm?1 exhibits a specific relationship.

Abstract: A magnetic toner comprising a toner particle comprising a binder resin and magnetic iron oxide particles, wherein a content of the magnetic iron oxide particles in the magnetic toner is 30 to 45 mass %, the magnetic iron oxide particles contain (i) spherical magnetic iron oxide particles and (ii) at least one selected from the group consisting of hexahedral magnetic iron oxide particles and octahedral magnetic iron oxide particles, and a content of the spherical magnetic iron oxide particles in the magnetic iron oxide particles is 1.0 to 9.0% by number.

Abstract: A toner includes toner particles containing a binder resin, a colorant, and inorganic fine particles, in which in a depth profile of an element distribution in a depth region from the outermost surface of a particle to a depth of 500 nm the depth profile being obtained by an element analysis performed by X-ray photoelectron spectroscopy using the toner as a sample, two or more minimum points of a concentration of a carbon element in the depth region exist, a concentration of an inorganic element becomes a maximum value at a depth position corresponding to each of the minimum points, and the inorganic element is an element derived from the inorganic fine particle.

Abstract: A toner comprising a toner particle comprising a binder resin including a polyester resin, and a polyolefin resin having a sulfonic acid group, wherein the polyolefin resin having a sulfonic acid group is a polymer in which a vinyl polymer is bonded to a polyolefin, a content ratio of a monomer unit containing a sulfonic acid group in the vinyl polymer is from 1.0 mass % to 20.0 mass %, in a FT-IR spectrum obtained through measurement of a large particle size toner and a small particle size toner resulting from dividing, on a number basis, the toner into two substantially equal parts, a ratio of an intensity of a maximum absorption peak in a range from 1130 cm?1 to 1170 cm?1 with respect to an intensity of a maximum absorption peak in a range from 1713 cm?1 to 1723 cm?1 exhibits a specific relationship.

Abstract: A toner comprising a toner particle containing a binder resin and a polymer A, wherein the binder resin contains a polyester resin having a specific structure, the polymer A has a first monomer unit derived from a specific (meth)acrylic acid ester and a second monomer unit different from the first monomer unit, a content ratio of the first monomer unit in the polymer A is 5.0 mol % to 60.0 mol % while a content ratio of the second monomer unit in the polymer A is 20.0 mol % to 95.0 mol %, and the SP value of the first monomer unit, the SP value of the second monomer unit, and the SP value of a silicone segment contained in the specific structure satisfy a specific relationship.

Abstract: A toner including a toner particle comprising a binder resin and a crystalline polyester, wherein the binder resin contains a polyester having a structure represented by the following formula (1): in formula (1), Rs each independently represent hydrogen, a methyl group, or a phenyl group; A represents a polyester segment; B represents a polyester segment or any functional group selected from the group consisting of —R1OH, —R1COOH, and —R1NH2 wherein R1 represents a single bond or a C1-4 alkylene group; and the average repeat number n is 10 to 80.

Abstract: A toner containing a toner particle that contains a binder resin including a polyester resin, and a polyolefin resin having —COOM that is a neutralized carboxy group with a monovalent metal ion M, wherein the polyolefin resin having —COOM is a polymer in which a vinyl polymer is bonded to a polyolefin, a content of a monomer unit containing —COOM in the polyolefin resin having —COOM is 1 to 20 mass %, and in a FT-IR spectrum obtained through measurement of a large particle size-side particle group and a small particle size-side particle group obtained by dividing the toner into two substantially equal parts, on a number basis, a ratio of the intensity of a maximum absorption peak in a range from 1545 cm?1 to 1555 cm?1 with respect to the intensity of a maximum absorption peak in a range from 1713 cm?1 to 1723 cm?1 exhibits a specific relationship.

Abstract: A toner that is suppressed from deteriorating owing to its long-term use and can maintain high transferability. The toner includes: a toner particle containing an amorphous polyester serving as a binder resin and a polymer A; and inorganic fine particles, wherein the polymer A includes a graft copolymer of a polyolefin and a vinyl-based polymer unit having a carboxylate anion group, and a metal ion having a valence of 2 or more.

Abstract: A toner includes a toner particle containing a binder resin and a silica fine particle A on a surface of the toner particle, wherein D50 on a number basis of the toner is 3.0 to 6.0 the silica fine particle A is a particle having a particle diameter of 80 to 500 nm, the particle diameter being confirmable by observing the toner with a SEM, and when the average coverage with the silica fine particle A determined by image analysis of a particle group of a small particle diameter side of the toner with a SEM is set to Ss and the average coverage with the silica fine particle A determined by image analysis of a particle group of a large particle diameter side of the toner with a scanning electron microscope is set to S1, Ss is 20 to 70 area %, Ss and S1 satisfy S1/Ss?0.80.

Abstract: A toner comprising a toner particle including a binder resin and a crystalline polyester resin, wherein the binder resin is an amorphous polyester resin having a linear alkyl group at a molecular chain terminal; the crystalline polyester resin is a polycondensate of a diol and a dicarboxylic acid; the number of carbon atoms CaPES of the linear alkyl group, the number of carbon atoms COH of the diol, and the number of carbon atoms CAc of the dicarboxylic acid, excluding carbon that belongs to carboxyl groups, satisfy the following relationships; and a glass transition temperature of the toner as measured by a differential scanning calorimeter is from 40.0° C. to 55.0° C. 8?CaPES?20??(1) CAc/COH?3.5 and 0?|CAc?CaPES|?3??(2) COH/CAc?3.

Abstract: A toner that is suppressed from deteriorating owing to its long-term use and can maintain high transferability. The toner includes: a toner particle containing an amorphous polyester serving as a binder resin and a polymer A; and inorganic fine particles, wherein the polymer A includes a graft copolymer of a polyolefin and a vinyl-based polymer unit having a carboxylate anion group, and a metal ion having a valence of 2 or more.

Abstract: A toner comprising a toner particle including a binder resin and a crystalline polyester resin, wherein the binder resin is an amorphous polyester resin having a linear alkyl group at a molecular chain terminal; the crystalline polyester resin is a polycondensate of a diol and a dicarboxylic acid; the number of carbon atoms CaPES of the linear alkyl group, the number of carbon atoms COH of the diol, and the number of carbon atoms CAc of the dicarboxylic acid, excluding carbon that belongs to carboxyl groups, satisfy the following relationships; and a glass transition temperature of the toner as measured by a differential scanning calorimeter is from 40.0° C. to 55.0° C. 8?CaPES?20??(1) CAc/COH?3.5 and 0?|CAc?CaPES|?3??(2) COH/CAc?3.

Abstract: Provided is a magenta toner having a magenta toner particle containing a binder resin, a colorant, a wax, a wax dispersant, and a crystalline polyester, wherein the wax dispersant is a graft polymer in which a styrene acrylic resin is grafted to a hydrocarbon compound, and the styrene acrylic resin has a monomer unit having a saturated alicyclic group, the colorant contains C.I. Pigment Red 32, and when observing a cross-section of the magenta toner particle using a transmission electron microscope (TEM), crystals of the crystalline polyester are dispersed in the cross-section, and the number average value of maximum lengths of the crystals is 50 nm or less.

Abstract: Provided is a magenta toner having a magenta toner particle containing a binder resin, a colorant, a wax, a wax dispersant, and a crystalline polyester, wherein the wax dispersant is a graft polymer in which a styrene acrylic resin is grafted to a hydrocarbon compound, and the styrene acrylic resin has a monomer unit having a saturated alicyclic group, the colorant contains C.I. Pigment Red 32, and when observing a cross-section of the magenta toner particle using a transmission electron microscope (TEM), crystals of the crystalline polyester are dispersed in the cross-section, and the number average value of maximum lengths of the crystals is 50 nm or less.

Abstract: A toner is provided, which is obtained by heat treating a toner particle containing a crystalline polyester resin, an amorphous polyester resin, a hydrocarbon wax and a wax dispersant, wherein the crystalline polyester resin is a hybrid resin having crystalline polyester segments and amorphous vinyl segments, and a mass ratio of crystalline polyester segments and amorphous vinyl segments in the crystalline polyester resin (crystalline segments/amorphous segments) is 70/30 to 98/2.

Abstract: A toner production method including: a melt-kneading step of melt-kneading a resin composition including a binder resin, a colorant, a wax, and a wax dispersant to obtain a melt-kneaded product; and a pulverizing step of pulverizing the melt-kneaded product. Where the temperature of the melt-kneaded product at the end of the melt-kneading step is Tk (° C.), and the softening point of the wax dispersant is Tm (° C.), the relationship of ?18?[Tk?Tm]?10 is satisfied. The wax dispersant is a polymer in which a styrene acrylic polymer is graft-polymerized to a polyolefin. The styrene acrylic polymer has a monomer unit derived from ?-methylstyrene and a monomer unit derived from a cycloalkyl (meth)acrylate.