Abstract: The present invention is intended to improve a SOx reduction rate which is a ratio of an amount of SOx reduction with respect to an amount of SOx occlusion in SOx poisoning recovery processing. In the present invention, in the SOx poisoning recovery processing in which the SOx occluded in an NOx storage reduction catalyst is reduced by decreasing the air fuel ratio of an exhaust gas flowing into the NOx storage reduction catalyst to a predetermined air fuel ratio in a repeated manner, the length of a period in which the air fuel ratio of an exhaust gas flowing into the NOx storage reduction catalyst is decreased is made longer in a relatively early time during the processing than in a relatively late time during the processing.

Abstract: The present invention provides a porous composite oxide comprising an aggregate of secondary particles in the form of aggregates of primary particles of a composite oxide containing two or more types of metal elements, and having mesopores having a pore diameter of 2-100 nm between the secondary particles; wherein, the percentage of the mesopores between the secondary particles having a diameter of 10 nm or more is 10% or more of the total mesopore volume after firing for 5 hours at 600° C. in an oxygen atmosphere.

Abstract: When a search character string is input via a key input section and a handwriting input section, if a spelling is input, a character is input directly by a key input operation or a recognized character is input by a handwriting input operation. If pinyin is input to input a Chinese character, not only are alphabetic characters input by a key input operation, but also the four tones area input by touching a four-tone input screen displayed on the handwriting input section. Accordingly, not only can ordinary characters be input as usual, of course, but also Chinese-specific four tones can be input easily by a touch operation at the handwriting input section even when a pinyin character is input.

Abstract: An internal combustion engine in an engine exhaust passage of which a hydrocarbon feed valve and an exhaust purification catalyst are arranged. On the exhaust purification catalyst, platinum Pt is carried and a basic layer is formed. A concentration of hydrocarbons flowing into the exhaust purification catalyst is made to vibrate within a predetermined range of amplitude of 200 ppm or more and within a predetermined range of period of 5 seconds or less whereby NOx which is contained in the exhaust gas is reduced in the exhaust purification catalyst.

Abstract: Inside an engine exhaust passage, in order from the upstream side, a hydrocarbon feed valve, oxidation catalyst, and exhaust purification catalyst are arranged. A first NOx purification method which lowers the air-fuel ratio of the exhaust gas flowing into the exhaust purification catalyst by a predetermined period while maintaining it lean so as to remove NOx without causing NOx to be stored in the form of nitrates and a second NOx purification method which switches the air-fuel ratio of the exhaust gas flowing into the exhaust purification catalyst from lean to rich by a period longer than the above period so as to remove NOx are selectively used in accordance with an operating state of the engine.

Abstract: A metal or metal compound able to trap a sulfur component in exhaust gas is arranged in a flow passage of exhaust gas in an internal combustion engine. When the amount of sulfur component trapped in the metal or metal compound increases over the passage of time, a property of the metal or metal compound which changes along with the increase in the amount of trapped sulfur component is measured and the sulfur component in the gas is detected from the measured property.

Abstract: Inside of an engine exhaust passage, a hydrocarbon feed valve (15) and an exhaust purification catalyst (13) are arranged. On the exhaust purification catalyst (13), platinum Pt (51) is carried and a basic layer (53) is formed. The concentration of hydrocarbons which flows into the exhaust purification catalyst (13) is made to vibrate within a predetermined range of amplitude and within a predetermined range of period, whereby the NOx which is contained in the exhaust gas is reduced by the exhaust purification catalyst (13). A clogging degree detecting means is provided for detecting a degree of clogging of a nozzle opening of the hydrocarbon feed valve (15). The NOx purification rate is estimated from the degree of clogging of the nozzle opening of the hydrocarbon feed valve (15) which is detected.

Abstract: A metal compound (50) able to trap a sulfur component in exhaust gas is arranged in a flow path of the exhaust gas, a property of the metal compound (50) changing along with an increase of the amount of sulfur component trapped at the metal compound (50) is measured, and the cumulative value of the amount of SOX actually contained in the exhaust gas is calculated from the measured property. On the other hand, the assumed cumulative value of the amount of SOX, assumed to be contained in the exhaust gas when assuming that fuel or oil of a sulfur concentration assumed in advance is used, is calculated. It is judged if fuel or oil with a high sulfur concentration is being used from the actual cumulative value of the amount of SOX and the assumed cumulative value of the amount of SOX.

Abstract: An internal combustion engine in which a front end catalyst (12) and rear end catalyst (14) comprising NOx storing catalysts are arranged in an engine exhaust passage. When these catalysts (12, 14) should recover from SOx poisoning, SOx poisoning recovery proceeding is performed in which the temperatures of the corresponding catalysts (12, 14) are raised to the SOx release temperature and the air-fuel ratio of the exhaust gas flowing into the corresponding catalysts (12, 14) is made rich. In this case, the frequency of performing the SOx poisoning recovery proceeding of the rear end catalyst (14) is made higher than the frequency of performing the SOx poisoning recovery proceeding of the front end catalyst (12).

Abstract: A post-treatment system comprised of an SOx trapping catalyst (11), a particulate filter (13) carrying an NOx storing and reducing catalyst, and an NOx storing and reducing catalyst (15) and a fuel feed valve (17) for feeding fuel for post processing to the post-treatment system are arranged in an engine exhaust passage. Each time an operating period of the engine passes a certain period, values of operating parameters of the engine and the method of feeding the post-treatment use fuel are reset so that the total amount of consumption of the combustion use fuel and post-treatment use fuel becomes smallest while maintaining the amounts of the harmful components discharged into the atmosphere at below the regulatory values.

Abstract: An internal combustion engine wherein an SOx trap catalyst (12), an NOx storage catalyst (14), and a fuel addition valve (15) are arranged in an engine exhaust passage. When making the air-fuel ratio of the exhaust gas flowing into the NOx storage catalyst (14) the stoichiometric air-fuel ratio or rich so as to make the NOx storage catalyst (14) release NOx, additional fuel is supplied into the combustion chamber (2) and fuel is added from the fuel addition valve (15). At this time, the amount of additional fuel to the combustion chamber (2) is controlled so that the air-fuel ratio of the exhaust gas exhausted from the combustion chamber (2) becomes the smallest in the range where the SOx trap catalyst (12) does not release SOx.

Abstract: An exhaust purification system of an internal combustion engine includes an NOX storage reduction catalyst device which is arranged in an engine exhaust passage. The NO storage reduction catalyst device stores SOX simultaneously with NOX. When the stored SOX amount exceeds a predetermined allowable amount, the SOX is made to be released by SOX release control which raises the temperature of the NOX catalyst device to the SOX releasable temperature, then makes the air-fuel ratio of the exhaust gas which flows into the NOX catalyst device the stoichiometric air-fuel ratio or rich. The NOX catalyst device has a residual SOX storage amount which finally remains even if performing SOX release control depending on the temperature of the NOX catalyst device when performing SOX release control. The system uses the residual SOX storage amount of the current SOX release control as the basis to calculate the SOX release speed at each timing in the current SOX release control.

Abstract: When performing temperature elevation control at a first exhaust purification device, a second exhaust purification device is prevented from being raised in temperature to a set temperature or more.

Abstract: An SOX trap catalyst (11) in which at least one of an alkali metal and alkali earth metal is carried diffused is arranged in an exhaust passage of an internal combustion engine. By holding the temperature of the SOX trap catalyst (11) during engine operation at the temperature where a nitrate of the at least one of the alkali metal and alkali earth metal becomes the melted state, a nitrate movement and coagulation action where the nitrate in the SOX trap catalyst (11) moves to and coagulates at the surface of the SOX trap catalyst (11) is promoted. Due to this nitrate movement and coagulation action, SOX is removed while restoring the SOX trap rate.

Abstract: In an internal combustion engine, an SOx sensor (16) having a sensor part (53, 60) trapping the SOx contained in the exhaust gas and able to detect the amount of SOx trapped at the sensor part (53, 60) from a change of property of the sensor part (53, 60) is arranged in the engine exhaust passage upstream of the NOx storing catalyst (14). When estimating the amount of SOx stored in the NOx storing catalyst (14) from the amount of SOx trapped at the sensor part (53, 60), deviation of the estimated value of the amount of stored SOx arising due to the difference between the SOx trapping rate of the sensor part (53, 60) and the SOx trapping rate of the NOx storing catalyst (14) is corrected.

Abstract: A control system of an internal combustion engine which arranges in an engine exhaust passage an exhaust turbine of an exhaust driven type supercharger, arranges in the exhaust passage downstream of the exhaust turbine an exhaust purification catalyst connects the exhaust passage between the exhaust purification catalyst and the exhaust turbine with the exhaust passage upstream of the exhaust turbine by a bypass passage, arranges in the bypass passage a storing agent which stores a specific ingredient in the exhaust, and is provided with an exhaust gas flow switching device which selectively switches the exhaust gas flow between a flow which flows through the exhaust turbine into the exhaust purification catalyst and a flow which flows through the bypass passage into the exhaust purification catalyst.

Abstract: In an internal combustion engine, an NOx selective reducing catalyst is arranged inside an engine exhaust passage, an oxidation catalyst is arranged upstream of the NOx selective reducing catalyst, and an NOx adsorption catalyst is arranged upstream of the oxidation catalyst. The NOx adsorption catalyst has a property of releasing NOx when the temperature rises and a property of trapping the SOx contained in the exhaust gas. The inflow of SOx into the oxidation catalyst is suppressed by the NOx adsorption catalyst to prevent the NO released from the NOx adsorption catalyst being oxidized to NO2 at the oxidation catalyst from being obstructed by SOx.

Abstract: Engine air-fuel ratio controlling means is provided to control an exhaust air-fuel ratio that is the ratio between the air contained in the exhaust gas discharged from the engine and the fuel element contained in the same exhaust gas and acting as a reducing agent at a NOx catalyst by controlling the air-fuel ratio of the gas combusted in the engine. Fuel adding means is provided upstream of the NOx catalyst in an exhaust passage to add fuel into the exhaust gas. During the SOx poisoning recovery control, when developing a state enabling SOx reduction reactions, the exhaust gas air-fuel ratio of the exhaust gas discharged from the engine and the amount of fuel added from the fuel adding means are controlled to minimize the sum of the amount of fuel injected in the engine and the amount of fuel added from the fuel adding means.

Abstract: In an internal combustion engine, a sulfur detection sample gas is generated in a sample gas generation chamber by fuel of an amount smaller than the amount of fuel fed to a combustion chamber and proportional to the amount of fuel fed to the combustion chamber. An SOx sensor having a sensor part trapping the sulfur contained in the sample gas and capable of detecting the amount of sulfur trapped in the sensor part from the property changes of the sensor part is provided. The amount of SOx that flows into the catalyst is estimated from the output value-of this SOx sensor.

Abstract: An internal combustion engine wherein an SOX trap catalyst (11) able to trap SOX contained in exhaust gas is arranged in an engine exhaust passage upstream of an NOX storing catalyst (12). When the air-fuel ratio of the exhaust gas flowing into the SOX trap catalyst (11) is switched from lean to rich to make the NOX storing catalyst (12) release the NOX, if the temperature of the SOX trap catalyst (11) is the SOX release lower limit temperature or more, rich processing making the air-fuel ratio of the exhaust gas flowing into the SOX trap catalyst (11) rich for making the NOX storing catalyst (12) release NOX is prohibited.