Abstract: The present invention provides a positive electrode material for alkaline storage batteries which has high energy density and causes little capacity reduction even when a charge/discharge cycle is repeated at high temperatures. The positive electrode material for alkaline storage batteries of the present invention comprises nickel hydroxide particles and a layers of cobalt oxide coating the nickel hydroxide particles. A valence of cobalt of the cobalt oxide is larger than 3.0, and the cobalt oxide contains sodium ions or potassium ions inside the crystal and further fixes lithium hydroxide or lithium ions.

Abstract: A alkaline storage battery using positive electrodes comprising an active material containing nickel hydroxide particles and a rare earth element or a compound thereof containing or mixed with 0.1-100 ppm of Fe or an Fe compound based on the rare earth element or the compound thereof is provided.

Abstract: The present invention provides a positive electrode material for alkaline storage batteries which has high energy density and causes little capacity reduction even when a charge/discharge cycle is repeated at high temperatures. The positive electrode material for alkaline storage batteries of the present invention comprises nickel hydroxide particles and a layers of cobalt oxide coating the nickel hydroxide particles. A valence of cobalt of the cobalt oxide is greater than 3.0, and the cobalt oxide contains sodium ions or potassium ions inside the crystal and further fixes lithium hydroxide or lithium ions.

Abstract: An alkaline storage battery with improved cycle life and self-discharge characteristics is disclosed. The battery comprises a positive electrode, a negative electrode, a separator and an alkaline electrolyte. For the separator, a material of a woven or nonwoven fabric sheet or a porous film of polyolefine resin of which surfaces have been modified with a hydrophilic compound having a carboxyl group by graft-polymerization. The quantity of carbonates inside the battery is regulated to 150 mg/Ah battery capacity. The quantity of carbonates inside the battery can be regulated to a minimum by optimizing graft polymerization and subsequent washing conditions.

Abstract: Disclosed is a positive electrode material which provides an alkaline storage battery having high active material utilization, wherein good capacity recovery can be obtained by charging even after standing in the state of overdischarge or short circuit, and reduction in capacity scarcely arises. This active material comprises nickel hydroxide particles and a cobalt oxide. The cobalt oxide is a higher cobalt oxide containing as a main component .gamma.-cobalt oxyhydroxide, which belongs to any one crystal system of hexagonal, orthorhombic and monoclinic systems and has a layered structure, wherein a lattice spacing of the (003) plane is from 5.5 to 7.0 angstroms and an average valence of cobalt is higher than 3.0. Those which are prepared by coating the surface of nickel hydroxide particles with the higher cobalt oxide are preferable.

Abstract: The present invention provides a nickel/metal hydride storage battery using improved nickel hydroxide with an increased energy density as the active material. This invention is characterized in that the nickel hydroxide as the active material of the positive electrode constituting the battery indispensably contains as a solid solution at least one transition metal selected from the group consisting of Mn, Cr and Co in a proportion of 2 to 20 atomic % based on the amount of the nickel hydroxide in terms of metallic nickel, and that the crystal structure of the nickel hydroxide at charged state is a hexagonal or tetragonal system which has a diffraction peak of 2.theta. on (00l) plane of .beta.-NiOOH at an angle of approximately 15.degree. to 19.degree. in X-ray diffraction using CuK.alpha. as a source and has a regular array with a NaCl type structure.

Abstract: By using a thin film-formed positive electrode, and negative electrode and a film separator, the capacity density of the electrode plate can be improved and at the same time a nickel-hydrogen secondary battery with a higher capacity can be easily obtained; as a result a nickel-hydrogen secondary battery with a higher capacity density can be provided.

Abstract: Disclosed is an alkaline storage battery, in which the negative electrode is constituted by a hydrogen absorbing alloy capable of absorbing/desorbing hydrogen electrochemically, and a hydrophobic material is provided in the space between the surface of the negative electrode and the separator while a hydrophilic material is provided in the inside of the negative electrode, thereby properly secure both wetting property and surface hydrophobic property of the negative electrode against the alkaline electrolytic solution. Accordingly, a hydrogen gas generated in charging the battery can be absorbed by a vapor phase reaction in the hydrophobic portion in the surface of the negative electrode which is exposed to the vapor phase and can be absorbed electrochemically in the portion of the negative electrode which is wetted by the electrolytic solution, so that the inner pressure of the battery can be reduced to thereby make it possible to perform quick charging.

Abstract: Disclosed is an alkaline storage battery, in which the negative electrode is constituted by a hydrogen absorbing alloy capable of absorbing/desorbing hydrogen electrochemically, and a hydrophobic material is provided in the space between the surface of the negative electrode and the separator while a hydrophilic material is provided in the inside of the negative electrode, thereby properly secure both wetting property and surface hydrophobic property of the negative electrode against the alkaline electrolytic solution. Accordingly, a hydrogen gas generated in charging the battery can be absorbed by a vapor phase reaction in the hydrophobic portion in the surface of the negative electrode which is exposed to the vapor phase and can be absorbed electrochemically in the Portion of the negative electrode which is wetted by the electrolytic solution, so that the inner pressure of the battery can be reduced to thereby make it possible to perform quick charging.

Abstract: Disclosed is an improvement in a negative electrode of an alkaline storage battery, in which the negative electrode is constituted by a hydrogen absorbing alloy capable of absorbing/desorbing hydrogen electrochemically, and a hydrophobic material and a hydrophilic material are provided in a portion of the surface layer of the negative electrode and in the side of the negative electrode respectively so as to properly secure both the wetting property and hydrophobic property of the negative electrode against the alkaline electrolytic solution. Accordingly, a hydrogen can be absorbed electrochemically in the portion of the negative electrode which is wetted by the electrolytic solution and a hydrogen gas generated in charging the battery can be absorbed by a vapor phase reaction in the hydrophobic portion of the negative electrode which is exposed to the vapor phase so that the internal gas pressure can be reduced to thereby make it possible to perform rapid charging.

Abstract: Disclosed is an alkaline storage battery using a negative electrode formed of a hydrogen absorbing alloy capable of absorbing/desorbing hydrogen electrochemically. A three-dimensional structural matter having hydrophobic property is used as a supporter for supporting the hydrogen absorbing alloy of the negative electrode, so that hydrophobic property is given to the surface of the hydrogen absorbing alloy which is in contact with the support, whereby a hydrogen gas generated in a charging period is absorbed by powder of the alloy exposed at a gas phase portion to suppress the increase of the internal gas pressure of the battery.According to the present invention, it is possible to perform rapid charge in a short time because the increase of the internal gas pressure of the battery can be suppressed.