Abstract: A plastic article is provided wherein a plastic substrate is coated with multiple resin layers including a primer layer comprising a polymer having a UV-absorptive functional group incorporated therein and a weather resistant hardcoat layer comprising a reaction product of alkoxysilyl-containing benzophenone and/or a hydrolyzate thereof.

Abstract: Disclosed is a method for repairing a damaged area of a silicone hard-coat layer on an automotive resin glazing substrate by applying an intermediate coating composition (I) to the damaged area and applying a topcoat coating composition (II) to the intermediate coating composition. The intermediate coating composition (I) contains (A) a reactive siloxane compound and (B) silica. The topcoat coating composition (II) contains (C) an alkoxysilane having a UV-absorbing functional group, (D) a multifunctional alkoxysilane, (E) a reactive siloxane compound, (F) colloidal silica, and (G) phosphoric acid. The method forms a coating having the same appearance and physical properties as the underlying silicone hard-coat layer.

Abstract: A refinish coating system comprising (I) an intermediate coating composition and (II) a topcoat coating composition is useful for repairing a damage area of a silicone hard coat layer on an automotive resin glazing substrate. The intermediate coating composition (I) comprises (A) a reactive siloxane compound and (B) silica. The topcoat coating composition (II) comprises (C) an alkoxysilane having a UV-absorbing functional group, (D) a multifunctional alkoxysilane, (E) a reactive siloxane compound, (F) colloidal silica, and (G) phosphoric acid. The system forms a coating having the same appearance and physical properties as the underlying silicone hard coat layer.

Abstract: A plastic article is provided wherein a plastic substrate is coated with multiple resin layers including a primer layer comprising a polymer having a UV-absorptive functional group incorporated therein and a weather resistant hardcoat layer comprising a reaction product of alkoxysilyl-containing benzophenone and/or a hydrolyzate thereof.

Abstract: A curable composition comprises (A) an organic/inorganic composite in which a hydrolyzable silyl group and/or SiOH group-containing polysiloxane is bonded to a vinyl polymer through a Si—C bond, and (B) an organic UV absorber having a molecular weight of at least 500 and a weight retentivity of at least 95% when held at 150° C. for 24 hours in an open state. The curable composition is coated and cured to an article, whereby the article is endowed with satisfactory weathering resistance while minimizing coloration or degradation.

Abstract: A curable composition comprises (A) a vinyl polymer having hydrolyzable silyl groups and/or SiOH groups and organic UV absorbing groups bonded to side chains, (B) an organic UV absorber having a molecular weight of at least 500 and a weight retentivity of at least 95% when held at 150° C. for 24 hours in an open state, and (C) an organosilicon compound containing a nitrogen atom and an alkoxysilyl group in the molecule. The curable composition is coated and cured to an article, whereby the article is endowed with satisfactory weathering resistance while minimizing coloration or degradation.

Abstract: A curable composition comprises (A) an organic/inorganic composite in which a hydrolyzable silyl group and/or SiOH group-containing polysiloxane is bonded to a vinyl polymer through a Si—C bond, and (B) an organic UV absorber having a molecular weight of at least 500 and a weight retentivity of at least 95% when held at 150° C. for 24 hours in an open state. The curable composition is coated and cured to an article, whereby the article is endowed with satisfactory weathering resistance while minimizing coloration or degradation.