Abstract: In a carbon-containing refractory composed of a refractory aggregate, a carbon based raw material, and a carbon bond connecting between the refractory aggregate or the carbon based raw material, transition metal-containing nanoparticles having particle diameters of 1,000 nm or less and containing a transition metal are contained in the above-described carbon bond while being dispersed. When the carbon-containing refractory is heat-treated, flexible structures of carbon fiber-shaped textures having diameters of 50 nm or less are formed in the inside of a carbon bond and, thereby, an increase in strength, a reduction in modulus of elasticity, and a reduction in thermal expansion coefficient are facilitated. Therefore, a carbon-containing refractory exhibiting high thermal shock resistance, high abrasion resistance, and high corrosion resistance are provided.

Abstract: Disclosed is a continuous casting nozzle, which comprises a layer formed to have high functions, such as high corrosion resistance and high anti-deposition capability, and disposed on the side of an inner bore thereof to serve as an inner bore-side layer, so as to enhance durability, wherein the continuous casting nozzle is capable of preventing expansion cracking of an outer periphery-side layer serving as a nozzle body thereof, due to a difference in thermal expansion between respective compositions of the inner bore-side layer and the outer periphery-side layer, while preventing peel-off of the inner bore-side layer during casting.

Abstract: A carbon-containing refractory is provided, which can improve the thermal shock resistance, the abrasion resistance, and the corrosion resistance without degrading the oxidation resistance. In a carbon-containing refractory composed of a refractory aggregate, a carbon based raw material, and a carbon bond connecting between the refractory aggregate or the carbon based raw material, transition metal-containing nanoparticles having particle diameters of 1,000 nm or less and containing a transition metal are contained in the above-described carbon bond while being dispersed. When the carbon-containing refractory is heat-treated, flexible structures of carbon fiber-shaped textures having diameters of 50 nm or less are formed in the inside of a carbon bond and, thereby, an increase in strength, a reduction in modulus of elasticity, and a reduction in thermal expansion coefficient are facilitated.