Patents by Inventor Koji Fushimi
Koji Fushimi has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20230089029Abstract: Disclosed is a rare earth complex including: one or a plurality of rare earth ions; and a ligand forming a coordinate bond with the rare earth ions. At least a part of the rare earth ions are at least one kind selected from the group consisting of lutetium(III) ions, yttrium(III) ions, and gadolinium(III) ions. The ligand includes a residue obtained by removing one or more hydrogen atoms from a fluorescent condensed polycyclic aromatic compound.Type: ApplicationFiled: December 23, 2020Publication date: March 23, 2023Applicant: NATIONAL UNIVERSITY CORPORATION HOKKAIDO UNIVERSITYInventors: Yuichi KITAGAWA, Ayu NAITO, Yasuchika HASEGAWA, Koji FUSHIMI
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Patent number: 11499093Abstract: A rare earth complex including a rare earth ion and a ligand coordinated with the rare earth ion and having a condensed polycyclic aromatic group.Type: GrantFiled: February 22, 2018Date of Patent: November 15, 2022Assignee: NATIONAL UNIVERSITY CORPORATION HOKKAIDO UNIVERSITYInventors: Yuichi Kitagawa, Fumiya Suzue, Takayuki Nakanishi, Koji Fushimi, Yasuchika Hasegawa
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Publication number: 20220315613Abstract: Disclosed is a rare earth complex having a rare earth ion and a phosphine oxide ligand that is coordinated with the rare earth ion and is represented by the following formula (I): wherein R1, R2, R3, R4, R5, and R6 each independently represent an alkyl group which may have a substituent.Type: ApplicationFiled: April 23, 2020Publication date: October 6, 2022Applicant: NATIONAL UNIVERSITY CORPORATION HOKKAIDO UNIVERSITYInventors: Yuichi KITAGAWA, Kaori SHIMA, Satoshi WADA, Yasuchika HASEGAWA, Koji FUSHIMI
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Publication number: 20220089942Abstract: A rare earth compound including: one or a plurality of rare earth ions; and a ligand coordinated with the rare earth ion and having a condensed polycyclic aromatic group. At least part of the rare earth ions is a terbium(III) ion. The condensed polycyclic aromatic group is a residue formed by removing a hydrogen atom bonded to a condensed aromatic ring in formula (1) below from a condensed polycyclic aromatic compound represented by the following formula (1). Also disclosed is a luminescent body including the rare earth compound.Type: ApplicationFiled: December 13, 2019Publication date: March 24, 2022Applicant: NATIONAL UNIVERSITY CORPORATION HOKKAIDO UNIVERSITYInventors: Yuichi KITAGAWA, Fumiya SUZUE, Yasuchika HASEGAWA, Koji FUSHIMI
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Publication number: 20210269460Abstract: Disclosed is a rare-earth complex including a rare-earth ion, and a ligand coordinate-bonded to the rare-earth ion and having a condensed polycyclic aromatic group. The condensed polycyclic aromatic group is a residue formed by removing a hydrogen atom bonded to a condensed aromatic ring from a condensed polycyclic aromatic compound represented by the following Formula (I). In Formula (I), R1 and R2 represent hydrogen atoms or groups which are bonded to each other to form one aromatic ring or a condensed aromatic ring including two or more aromatic rings.Type: ApplicationFiled: July 4, 2019Publication date: September 2, 2021Applicant: NATIONAL UNIVERSITY CORPORATION HOKKAIDO UNIVERSITYInventors: Yuichi KITAGAWA, Marina KUMAGAI, Yasuchika HASEGAWA, Takayuki NAKANISHI, Koji FUSHIMI
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Publication number: 20210130378Abstract: A phosphine oxide compound represented by the following formula (I) and a rare earth complex containing the same are disclosed: wherein n represents an integer of 3 or more, Ar1 represents an n-valent aromatic group, L represents a divalent linker group, and Ar2 and Ar3 each independently represent a monovalent aromatic groups.Type: ApplicationFiled: February 21, 2018Publication date: May 6, 2021Applicant: NATIONAL UNIVERSITY CORPORATION HOKKAIDO UNIVERSITYInventors: Yasuchika HASEGAWA, Pedro paulo FERREIRA DA ROSA, Takayuki NAKANISHI, Yuichi KITAGAWA, Koji FUSHIMI
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Patent number: 10745614Abstract: Disclosed is a rare-earth complex polymer including trivalent rare-earth ions and a phosphine oxide bidentate ligand represented by the formula (1). One phosphine oxide bidentate ligand is coordinated to the two rare-earth ions, and crosslinks the same.Type: GrantFiled: April 26, 2017Date of Patent: August 18, 2020Assignee: NATIONAL UNIVERSITY CORPORATION HOKKAIDO UNIVERSITYInventors: Takayuki Nakanishi, Yuichi Hirai, Yasuchika Hasegawa, Yuichi Kitagawa, Koji Fushimi
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Publication number: 20200063030Abstract: A rare earth complex including a rare earth ion and a ligand coordinated with the rare earth ion and having a condensed polycyclic aromatic group.Type: ApplicationFiled: February 22, 2018Publication date: February 27, 2020Applicant: NATIONAL UNIVERSITY CORPORATION HOKKAIDO UNIVERSITYInventors: Yuichi KITAGAWA, Fumiya SUZUE, Takayuki NAKANISHI, Koji FUSHIMI, Yasuchika HASEGAWA
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Patent number: 10399999Abstract: Provided is an organic ligand capable of providing a complex that has a three-dimensional network structure due to rare-earth element ions. Also provided is a coordination polymer which includes this organic ligand, has a new function, and contains rare-earth element ions. Additionally, a process for producing the coordination polymer and a use of the coordination polymer are provided. In particular, provided is a coordination polymer having repeating units of formula (10): wherein each of the variable groups is as defined in the specification.Type: GrantFiled: February 26, 2016Date of Patent: September 3, 2019Assignee: National University Corporation Hokkaido UniversityInventors: Yasuchika Hasegawa, Ayako Nakajima, Takayuki Nakanishi, Yuichi Kitagawa, Koji Fushimi
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Patent number: 10329480Abstract: Provided are: a rare earth complex which has a novel structure, which exhibits compatibility with organic solvents and resins, and which exhibits excellent luminescent properties as a luminescent element; and a use thereof. This rare earth complex includes: a phosphine oxide compound represented by general formula (1); at least one rare earth ion selected from the group consisting of Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu; and a ligand compound. In the rare earth complex, the coordination numbers of the ligand compound and the phosphine oxide compound represented by general formula (1) to the rare earth ion are 8-10, and a plurality of the phosphine oxide compounds represented by general formula (1) and a plurality of the rare earth ions are provided with a crosslinked structure.Type: GrantFiled: July 4, 2014Date of Patent: June 25, 2019Assignee: National University Corporation Hokkaido UniversityInventors: Yasuchika Hasegawa, Shiori Tateno, Takayuki Nakanishi, Koji Fushimi
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Publication number: 20190119567Abstract: Disclosed is a rare-earth complex polymer including trivalent rare-earth ions and a phosphine oxide bidentate ligand represented by the formula (1). One phosphine oxide bidentate ligand is coordinated to the two rare-earth ions, and crosslinks the same.Type: ApplicationFiled: April 26, 2017Publication date: April 25, 2019Applicants: NATIONAL UNIVERSITY CORPORATION HOKKAIDO UNIVERSITY, Tokyo University of Science FoundationInventors: Takayuki NAKANISHI, Yuichi HIRAI, Yasuchika HASEGAWA, Yuichi KITAGAWA, Koji FUSHIMI
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Publication number: 20180334472Abstract: Provided is an organic ligand capable of providing a complex that has a three-dimensional network structure due to rare-earth element ions. Also provided is a coordination polymer which includes this organic ligand, has a new function, and contains rare-earth element ions. Additionally, a process for producing the coordination polymer and a use of the coordination polymer are provided. In particular, provided is a coordination polymer having repeating units of formula (10): wherein each of the variable groups is as defined in the specification.Type: ApplicationFiled: February 26, 2016Publication date: November 22, 2018Inventors: Yasuchika HASEGAWA, Ayako NAKAJIMA, Takayuki NAKANISHI, Yuichi KITAGAWA, Koji FUSHIMI
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Publication number: 20160160121Abstract: Provided are: a rare earth complex which has a novel structure, which exhibits compatibility with organic solvents and resins, and which exhibits excellent luminescent properties as a luminescent element; and a use thereof. This rare earth complex includes: a phosphine oxide compound represented by general formula (1); at least one rare earth ion selected from the group consisting of Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu; and a ligand compound. In the rare earth complex, the coordination numbers of the ligand compound and the phosphine oxide compound represented by general formula (1) to the rare earth ion are 8-10, and a plurality of the phosphine oxide compounds represented by general formula (1) and a plurality of the rare earth ions are provided with a crosslinked structure.Type: ApplicationFiled: July 4, 2014Publication date: June 9, 2016Inventors: Yasuchika HASEGAWA, Shiori TATENO, Takayuki NAKANISHI, Koji FUSHIMI
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Patent number: 9280002Abstract: The present invention relates to Eu (II) compound nanocrystals doped with transition metal ions. Such a constitution generates quantum size effects of an Eu (II) compound nanoparticle, while the transition metal ions can affect a magnetooptical property of the Eu (II) compound nanoparticle. Thus, the magnetooptical property can be improved.Type: GrantFiled: March 1, 2012Date of Patent: March 8, 2016Assignee: NATIONAL UNIVERSITY CORPORATION HOKKAIDO UNIVERSITYInventors: Yasuchika Hasegawa, Masashi Maeda, Mina Kumagai, Koji Fushimi
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Patent number: 9261718Abstract: The present invention is produced by a composite with an Eu (II) compound nanoparticle and a metal nanoparticle. Such production generates quantum size effects of the Eu (II) compound nanoparticle, while the surface plasmon of the metal nanoparticle can be used. Thus, the magnetooptical property can be improved. In addition, a thin film may be produced by a composite with an Eu (II) compound nanoparticle and a metal nanoparticle.Type: GrantFiled: March 1, 2012Date of Patent: February 16, 2016Assignee: National University Corporation Hokkaido UniversityInventors: Yasuchika Hasegawa, Akira Kawashima, Mina Kumagai, Koji Fushimi
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Patent number: 9051427Abstract: The present invention intends to provide a rare-earth complex polymer having a sufficient heat resistance to be blended in a plastic material and fabricated. A preferable embodiment of the rare-earth complex polymer comprises a plurality of both trivalent rare-earth ions and phosphine oxide multidentate ligands and a crosslinked structure formed by the phosphine oxide multidentate ligands being coordinated to a plurality of the rare-earth ions.Type: GrantFiled: May 1, 2012Date of Patent: June 9, 2015Assignee: NATIONAL UNIVERSITY CORPORATION HOKKAIDO UNIVERSITYInventors: Yasuchika Hasegawa, Kohei Miyata, Koji Fushimi, Masako Kato, Atsushi Kobayashi
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Publication number: 20140171600Abstract: The present invention intends to provide a rare-earth complex polymer having a sufficient heat resistance to be blended in a plastic material and fabricated. A preferable embodiment of the rare-earth complex polymer comprises a plurality of both trivalent rare-earth ions and phosphine oxide multidentate ligands and a crosslinked structure formed by the phosphine oxide multidentate ligands being coordinated to a plurality of the rare-earth ions.Type: ApplicationFiled: May 1, 2012Publication date: June 19, 2014Applicant: NATIONAL UNIVERSITY CORPORATION HOKKAIDO UNIVERSITYInventors: Yasuchika Hasegawa, Kohei Miyata, Koji Fushimi, Masako Kato, Atsushi Kobayashi
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Publication number: 20140071527Abstract: The present invention relates to Eu (II) compound nanocrystals doped with transition metal ions. Such a constitution generates quantum size effects of an Eu (II) compound nanoparticle, while the transition metal ions can affect a magnetooptical property of the Eu (II) compound nanoparticle. Thus, the magnetooptical property can be improved.Type: ApplicationFiled: March 1, 2012Publication date: March 13, 2014Applicant: NATIONAL UNIVERSITY CORPORATION HOKKAIDO UNIVERSITYInventors: Yasuchika Hasegawa, Masashi Maeda, Mina Kumagai, Koji Fushimi
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Publication number: 20140055855Abstract: The present invention is produced by a composite with an Eu (II) compound nanoparticle and a metal nanoparticle. Such production generates quantum size effects of the Eu (II) compound nanoparticle, while the surface plasmon of the metal nanoparticle can be used. Thus, the magnetooptical property can be improved. In addition, a thin film may be produced by a composite with an Eu (II) compound nanoparticle and a metal nanoparticle.Type: ApplicationFiled: March 1, 2012Publication date: February 27, 2014Applicant: National University Corporation Hokkaido UniversityInventors: Yasuchika Hasegawa, Akira Kawashima, Mina Kumagai, Koji Fushimi
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Patent number: 5398551Abstract: An ultrasonic testing method for detection of flaws in a ball-shaped material to be tested using an ultrasonic probe, wherein a test frequency f (MHz) of the probe and a radius of curvature r (mm) of a tip portion of the probe satisfy the relationship 50 mm.ltoreq.r.sqroot.f.ltoreq.60 mm, and wherein the radius of curvature r (mm) of the tip portion and the diameter D (mm) of an oscillator of the probe satisfy the relationship 0.35 mm.ltoreq.D/r.ltoreq.0.50 mm. The method enables detection of surface and internal flaws in materials, particularly ceramic ball hearings having a diameter ranging from several tens of millimeters down to 10 mm or below.Type: GrantFiled: June 9, 1994Date of Patent: March 21, 1995Assignee: NGK Insulators, Ltd.Inventors: Keiji Kawasaki, Koji Fushimi