Patents by Inventor Koji Kawaai

Koji Kawaai has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 6019911
    Abstract: Disclosed is a polycyclic compound represented by the following formula (I):R.sup.1 --X.sup.1 --[A.sup.1 --X.sup.2 ]--[A.sup.2 --X.sup.3 ]--R.sup.2 (I)wherein R.sup.1 is a (halogenated) alkyl group of 6 to 16 carbon atoms, X.sup.1 is --O-- group or a single bond, A.sup.1 is a biphenylene group, a phenylene group or the like, A.sup.2 is 1-fluoro-3,4-dihydronaphthalene or the like, X.sup.2 and X.sup.3 are each --COO--, a single bond or the like, and R.sup.2 is an optically active group of 4 to 20 carbon atoms which has at least one asymmetric carbon atom. Also disclosed are a liquid crystal material consisting of the polycyclic compound, a liquid crystal composition comprising the liquid crystal material, and a liquid crystal element. This novel polycyclic compound is optically active and capable of being in a smectic phase in a wide temperature range including room temperature. The polycyclic compound can be used as a ferroelectric liquid crystal material or an antiferroelectric liquid crystal material.
    Type: Grant
    Filed: September 26, 1997
    Date of Patent: February 1, 2000
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Chiho Hirano, Toyotaro Maruyama, Hiroaki Tan, Koji Kawaai, Shigekazu Matsui, Yasuhiko Suzuki, Tsuneaki Koike
  • Patent number: 5936053
    Abstract: A propylene polymer is excellent in rigidity, heat resistance, surface hardness, glossiness, transparency and impact resistance. A propylene copolymer (wherein the amount of monomer units derived from an .alpha.-olefin other than propylene is not more than 5% by mol) is excellent in transparency, rigidity, surface hardness, heat resistance, heat-sealing property, anti-blocking property, anti-bleedout property and impact strength. A propylene copolymer (wherein the amount of monomer units derived from an .alpha.-olefin other than propylene is not less than 5% by mol) is excellent in transparency, environmental aging property, and effective in improving heat-sealing property at low temperature and impact strength. A propylene elastomer is excellent in heat resistance, impact absorbing capacity, transparency, heat-sealing properties and anti-blocking properties.
    Type: Grant
    Filed: June 6, 1997
    Date of Patent: August 10, 1999
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Daisuke Fukuoka, Takashi Tashiro, Koji Kawaai, Takashi Ueda, Yoshihisa Kiso, Akira Mizuno, Masaaki Kawasaki, Masaaki Itoh, Mikio Hashimoto
  • Patent number: 5859272
    Abstract: Disclosed is a novel transition metal compound represented by the following formula: ##STR1## wherein M is a transition metal, X is halogen or the like, R.sup.1 is a hydrocarbon group or the like, R.sup.2 is an aryl group substituted with a halogenated hydrocarbon group, and Y is a divalent silicon-containing group or the like.Also disclosed are an olefin polymerization catalyst component comprising the transition metal compound, an olefin polymerization catalyst comprising the olefin polymerization catalyst component, and a process for olefin polymerization using the olefin polymerization catalyst.An olefin polymerization catalyst component having high polymerization activity can be formed from the transition metal compound. By the use of the olefin polymerization catalyst or the process for olefin polymerization, polyolefins having a high melting point and a high molecular weight can be prepared with high polymerization activity.
    Type: Grant
    Filed: January 24, 1997
    Date of Patent: January 12, 1999
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Junichi Imuta, Daisuke Fukuoka, Masayasu Yoshida, Junji Saito, Terunori Fujita, Takashi Tashiro, Koji Kawaai, Takashi Ueda, Yoshihisa Kiso
  • Patent number: 5723640
    Abstract: The novel transition metal compound of the invention is represented by the following formula (I): ##STR1## wherein M is a transition metal; R.sup.1 is a hydrocarbon group of 2 to 6 carbon atoms, R.sup.2 is an aryl group of 6 to 16 carbon atoms; X.sup.1 and X.sup.2 are each a halogen atom or the like; and Y is a divalent hydrocarbon group, a divalent silicon-containing group or the like. An olefin polymerization catalyst component of the present invention comprises the aforementioned transition metal compound.
    Type: Grant
    Filed: March 26, 1996
    Date of Patent: March 3, 1998
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Daisuke Fukuoka, Takashi Tashiro, Koji Kawaai, Junji Saito, Takashi Ueda, Yoshihisa Kiso, Junichi Imuta, Terunori Fujita, Masatoshi Nitabaru, Masayasu Yoshida
  • Patent number: 5710223
    Abstract: A process for polymerizing propylene utilizes a metallocene catalyst component of the formula (I) ##STR1## wherein M is a transition metal, R.sup.1 is a C.sub.2-6 hydrocarbon, R.sup.2 is a C.sub.6-16 aryl group, X.sup.1 and X.sup.2 are each a halogen atom and Y is a divalent hydrocarbon or a divalent silicon-containing group. Propylene polymers produced thereby have such properties that the triad tacticity of propylene units is high, the proportion of inversely inserted units based on the 2,1-insertion of propylene monomer is in a specific range and the intrinsic viscosity (.eta.), as measured in decahydronaphthalene at 135.degree. C., is in a specific range.
    Type: Grant
    Filed: September 25, 1996
    Date of Patent: January 20, 1998
    Assignee: Mitsui Petrochemical Industries Ltd.
    Inventors: Daisuke Fukuoka, Takashi Tashiro, Koji Kawaai, Junji Saito, Takashi Ueda, Yoshihisa Kiso, Junichi Imuta, Terunori Fujita, Masatoshi Nitabaru, Masayasu Yoshida
  • Patent number: 5705584
    Abstract: The novel propylene homopolymer and copolymer produced by using a catalyst which is represented by the following formula (I): ##STR1## wherein M is a transition metal; R.sup.1 is a hydrocarbon group of 2 to 6 carbon atoms, R.sup.2 is an aryl group of 6 to 16 carbon atoms; X.sup.1 and X.sup.2 are each a halogen atom or the like; and Y is a divalent hydrocarbon group, a divalent silicon-containing group or the like.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: January 6, 1998
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Daisuke Fukuoka, Takashi Tashiro, Koji Kawaai, Takashi Ueda, Yoshihisa Kiso, Akira Mizuno, Masaaki Kawasaki, Masaaki Itoh, Mikio Hashimoto
  • Patent number: 5658997
    Abstract: The novel transition metal compound of the invention is represented by the following formula (I): ##STR1## wherein M is a transition metal; R.sup.1 is a hydrocarbon group of 2 to 6 carbon atoms, R.sup.2 is an aryl group of 6 to 16 carbon atoms; X.sup.1 and X.sup.2 are each a halogen atom or the like; and Y is a divalent hydrocarbon group, a divalent silicon-containing group or the like. An olefin polymerization catalyst component of the present invention comprises the aforementioned transition metal compound. An olefin polymerization catalyst of the present invention comprises the aforementioned olefin polymerization catalyst component. The propylene homopolymer, the propylene copolymer and the propylene elastomer according to the present invention have such properties that the triad tacticity of propylene units chain is high, a proportion of the inversely units based on the 2,1-insertion of propylene monomer is in the specific range, and the intrinsic viscosity [.eta.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: August 19, 1997
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Daisuke Fukuoka, Takashi Tashiro, Koji Kawaai, Junji Saito, Takashi Ueda, Yoshihisa Kiso, Junichi Imuta, Terunori Fujita, Masatoshi Nitabaru, Masayasu Yoshida
  • Patent number: 5629254
    Abstract: The novel transition metal catalyst of the invention is represented by the following formula (I): ##STR1## wherein M is a zirconium or hafnium; R.sup.1 is a hydrocarbon group of 2 to 6 carbon atoms, R.sup.2 is an aryl group of 6 to 16 carbon atoms; X.sup.1 and X.sup.2 are each a halogen atom; and Y is a divalent hydrocarbon group, a divalent silicon-containing group.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: May 13, 1997
    Assignee: Mitsui Petrochemical Industries Co., Ltd.
    Inventors: Daisuke Fukuoka, Takashi Tashiro, Koji Kawaai, Junji Saito, Takashi Ueda, Yoshihisa Kiso, Junichi Imuta, Terunori Fujita, Masatoshi Nitabaru, Masayasu Yoshida
  • Patent number: 5616663
    Abstract: Disclosed is a novel transition metal compound represented by the following formula: ##STR1## wherein M is a transition metal, X is halogen or the like, R.sup.1 is a hydrocarbon group or the like, R.sup.2 is an aryl group substituted with a halogenated hydrocarbon group, and Y is a divalent silicon-containing group or the like.Also disclosed are an olefin polymerization catalyst component comprising the transition metal compound, an olefin polymerization catalyst comprising the olefin polymerization catalyst component, and a process for olefin polymerization using the olefin polymerization catalyst.An olefin polymerization catalyst component having high polymerization activity can be formed from the transition metal compound. By the use of the olefin polymerization catalyst or the process for olefin polymerization, polyolefins having a high melting point and a high molecular weight can be prepared with high polymerization activity.
    Type: Grant
    Filed: November 10, 1994
    Date of Patent: April 1, 1997
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Junichi Imuta, Daisuke Fukuoka, Masayasu Yoshida, Junji Saito, Terunori Fujita, Takashi Tashiro, Koji Kawaai, Takashi Ueda, Yoshihisa Kiso
  • Patent number: 5360921
    Abstract: Disclosed is a process for preparing a cyclopentadienyl group-containing silicon compound or a cyclopentadienyl group-containing germanium compound, comprising reacting (i) a lithium, sodium or potassium salt of a cyclopentadiene derivative with (ii) a silicon halide compound or a germanium halide compound in the presence of a cyanide or a thiocyanate. The cyanide or the thiocyanate is preferably a copper salt. According to the process of the invention, a cyclopentadienyl group-containing silicon compound or a cyclopentadienyl group-containing germanium compound, which is very useful for the preparation of a metallocene complex catalyst component, can be prepared in a high yield for a short period of time.
    Type: Grant
    Filed: March 11, 1994
    Date of Patent: November 1, 1994
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Yoshihisa Kiso, Koji Kawaai, Masatoshi Nitabaru