Abstract: The invention relates to the field of radio-ecological monitoring, in particular to a method for measuring the content of radionuclides in components of the environment. The technical result is enhancement of the sensitivity of liquid scintillation analysis of radionuclides with low activity in the presence of radionuclides with high activity. Selection and preparation of a sample for measurements are carried out, the spectrum of the sample is measured and recorded, the measured spectrum Pi is grouped, model spectrum Mi=&Sgr;cj Mij, wherein cj designates relative contributions of base spectra of radionuclides in the model spectrum, is created on the basis of a library of base spectra of radionuclides Mij, where i is the No.