Abstract: A chiller apparatus containing a composition comprising cis-1,1,1,4,4,4-hexafluoro-2-butene and trans-1,2-dichloroethylene.

Abstract: Disclosed is a method for producing heating in a cascade heat pump having a lower cascade stage and an upper cascade stage, said method comprising condensing a vapor working fluid comprising Z-1,1,1,4,4,4-hexafluoro-2-butene, in a condenser in the upper cascade stage, thereby producing a liquid working fluid; wherein the lower cascade stage contains a working fluid selected from the group consisting of CO2, N2O, E-HFO-1234ye, HFC-1243zf, HFC-125, HFC-143a, HFC-152a, HFC-161 and mixtures thereof; or mixtures thereof with HFC-134a, HFC-32, HFO-1234yf or trans-HFO-1234ze. Also disclosed is a cascade heat pump apparatus containing a working fluid comprising Z-1,1,1,4,4,4-hexafluoro-2-butene in an upper cascade stage and containing a working fluid selected from the group consisting of CO2, N2O, E-HFO-1234ye, HFC-1243zf, HFC-125, HFC-143a, HFC-152a, HFC-161 and mixtures thereof; or mixtures thereof with HFC-134a, HFC-32, HFO-1234yf or trans-HFO-1234ze.

Abstract: Azeotropic or azeotrope-like compositions are disclosed. The azeotropic or azeotrope-like compositions include mixtures of 2,3,3,4,4,4-hexafluoro-1-butene a second component, where the second component may be and 1,1,1,2,3,3-hexafluoropropane. Also disclosed is a process of preparing a thermoplastic or thermoset foam by using such azeotropic or azeotrope-like compositions as blowing agents. Also disclosed is a process of producing refrigeration by using such azeotropic or azeotrope-like compositions. Also disclosed is a process of using such azeotropic or azeotrope-like compositions as solvents. Also disclosed is a process of producing an aerosol product by using such azeotropic or azeotrope-like compositions. Also disclosed is a process of using such azeotropic or azeotrope-like compositions as heat transfer media. Also disclosed is a process of extinguishing or suppressing a fire by using such azeotropic or azeotrope-like compositions.

Abstract: In accordance with the present invention a composition is provided. The composition comprises Z-1,1,1,4,4,4-hexafluoro-2-butene (Z-HFO-1336mzz) and 2,2-dichloro-1,1,1-trifluoroethane (HCFC-123). Also in accordance with the present invention a method is provided for topping-off or replenishing a refrigerant charge. The method comprises adding a second refrigerant to a refrigeration, air conditioning, heat pump or power cycle system containing HCFC-123 as a first refrigerant, wherein said second refrigerant comprises Z-HFO-1336mzz and optionally HCFC-123, thus producing a refrigerant composition comprising the first refrigerant and the second refrigerant. Also in accordance with the present invention another method is provided. The method comprises replacing HCFC-123 in a refrigeration, air conditioning, heat pump or power cycle system with a refrigerant composition comprising Z-HFO-1336mzz and optionally HCFC-123.

Abstract: Disclosed herein are compositions containing: (A) a refrigerant component containing (1) at least one refrigerant having an OEL less than 400; and (2) a combination of refrigerants, each having an OEL greater than 400, containing (i) at least one compound selected from HFC-134a and HFC-134, and (ii) trans-HFO-1234ze, wherein the refrigerant component has an overall OEL of at least 400 and is non-flammable. The refrigerant mixtures are useful as components in compositions optionally also containing non-refrigerant components (e.g. lubricants), in methods to produce cooling, in methods for replacing refrigerant R-134a, and in refrigeration or air conditioning apparatus.

Abstract: Compositions are disclosed which contain a refrigerant component consisting essentially of at least one refrigerant having an OEL less than 400; and a combination of refrigerants, each having an OEL greater than 400, consisting essentially of HFC-134a; HFC-32; trans-HFO-1234ze; and optionally at least one refrigerant selected from the group consisting of HFC-134 and HFC-125; provided that HFC-134a is not greater than 26 weight percent of the refrigerant component and the total of HFC-134a and HFC-134 is not less than 20 weight percent of the refrigerant component; and optionally a non-refrigerant component; wherein the refrigerant component has an overall OEL of at least 400 and wherein components the refrigerant component is non-flammable. These compositions are useful in processes to produce refrigeration, in methods for replacing refrigerant R-404A or R-507A, and in refrigeration apparatus.

Abstract: A method is provided for converting heat from a heat source to mechanical energy. The method comprises heating a working fluid using heat supplied from the heat source; and expanding the heated working fluid to lower the pressure of the working fluid and generate mechanical energy as the pressure of the working fluid is lowered. The method is characterized by using a working fluid comprising HFC-245eb and optionally Z-HFO-1336mzz. A power cycle apparatus containing a working fluid to convert heat to mechanical energy is also provided. The apparatus is characterized by containing a working fluid comprising HFC-245eb and optionally Z-HFO-1336mzz. A working fluid comprising HFC-245eb and optionally Z-HFO-1336mzz is also provided. The working fluid (i) further comprises E-HFO-1336mzz, (ii) has a temperature above its critical temperature, or both (i) and (ii).

Abstract: Compositions are disclosed comprising: (a) 1,1,1,2,2-pentafluoropropane; (b) a compound selected from the group consisting of 2,3,3,3-tetrafluoropropene, E-1,3,3,3-tetrafluoropropene, and 1,1,1-trifluoropropene; and optionally (c) a compound selected from the group consisting of 1,1,1,2-tetrafluoroethane and difluoromethane. Such compositions are useful in methods to produce cooling, produce heat, transfer heat, form a foam, produce aerosol products, for recovering heat, and for replacing existing refrigerants. Additionally, these compositions are useful in refrigeration, air conditioning and heat pump apparatus.

Abstract: Disclosed herein is a chiller apparatus containing a composition comprising from about 6 to about 70 weight percent 2,3,3,3-tetrafluoropropene and from about 30 to about 94 weight percent 1,1,1,2-tetrafluoroethane. Also disclosed herein is a method for producing cooling in a chiller comprising (a) evaporating a liquid refrigerant comprising from about 6 to 70 weight percent 2,3,3,3-tetrafluoropropene and from about 30 to 94 weight percent 1,1,1,2-tetrafluoroethane in an evaporator having a heat transfer medium passing therethrough thereby producing a vapor refrigerant; and (b) compressing the vapor refrigerant in a compressor. Also disclosed herein is a method for replacing a refrigerant in a chiller designed for using HFC-134a or CFC-12 as refrigerant, comprising charging said chiller with a composition comprising a refrigerant consisting essentially of from about 6 to 70 weight percent 2,3,3,3-tetrafluoropropene and from about 30 to 94 weight percent 1,1,1,2-tetrafluoroethane.

Abstract: Disclosed are compositions of novel working fluids uniquely designed for higher cycle efficiencies leading to higher overall system efficiencies. In particular, these working fluids are useful in Organic Rankine Cycle systems for efficiently converting heat from any heat source into mechanical energy. The present invention also relates to novel processes for recovering heat from a heat source using ORC systems with a novel working fluid comprising at least about 20 weight percent cis-1,1,1,4,4,4-hexafluoro-2-butene (HFO-1336mzz-Z), trans-1,1,1,4,4,4-hexafluoro-2-butene (HFO-1336mzz-E), or mixtures thereof.

Abstract: Disclosed herein is a method for producing heating in a high temperature heat pump comprising condensing a vapor working fluid comprising Z-1,1,1,4,4,4-hexafluoro-2-butene, in a condenser, thereby producing a liquid working fluid. Also disclosed herein is a method of raising the maximum feasible condenser operating temperature in a high temperature heat pump apparatus comprising charging the high temperature heat pump with a working fluid comprising Z-1,1,1,4,4,4-hexafluoro-2-butene. Also disclosed herein is a composition comprising: (a) Z-1,1,1,4,4,4-hexafluoro-2-butene; (b) 2-chloropropane; and (c) at least one lubricant suitable for use at a temperature of at least about 150° C.; is wherein the 2-chloropropane is present in an amount effective to form an azeotrope or azeotrope-like combination with the Z-1,1,1,4,4,4-hexafluoro-2-butene. Also disclosed herein is a high temperature heat pump apparatus containing a working fluid comprising Z-1,1,1,4,4,4-hexafluoro-2-butene.

Abstract: Disclosed herein is a method for producing heating comprising condensing a vapor working fluid comprising (a) E-CF3CH?CHF and (b) at least one tetrafluoroethane of the formula C2H2F4, in a condenser, thereby producing a liquid working fluid; provided that the weight ratio of E-CF3CH?CHF to the total amount of E-CF3CH?CHF and C2H2F4 in the working fluid is from about 0.01 to 0.99. Also disclosed herein is a heat pump apparatus containing a working fluid comprising (a) E-CF3CH?CHF and (b) at least one tetrafluoroethane of the formula C2H2F4; provided that the weight ratio of E-CF3CH?CHF to the total amount of E-CF3CH?CHF and C2H2F4 in the working fluid is from about 0.01 to 0.99.

Abstract: Disclosed herein is a method for producing cooling comprising evaporating a liquid refrigerant comprising (a) E-CF3CH?CHF and (b) at least one tetrafluoroethane of the formula C2H2F4; provided that the weight ratio of E-CF3CH?CHF to the total amount of E-CF3CH?CHF and C2H2F4 is from about 0.05 to 0.99, in an evaporator, thereby producing a refrigerant vapor. Also disclosed herein is a method for replacing HCFC-124 or HFC-134a refrigerant in a chiller designed for said refrigerant comprising providing a replacement refrigerant composition comprising (a) E-CF3CH?CHF and (b) at least one tetrafluoroethane of the formula C2H2F4; provided that the weight ratio of E-CF3CH?CHF to the total amount of E-CF3CH?CHF and C2H2F4 is from about 0.05 to 0.99.

Abstract: Disclosed herein is a chiller apparatus containing a composition comprising from about 6 to about 70 weight percent 2,3,3,3-tetrafluoropropene and from about 30 to about 94 weight percent 1,1,1,2-tetrafluoroethane. Also disclosed herein are compositions comprising from about 58.0 to about 59.5 weight percent 2,3,3,3-tetrafluoropropene and from about 42.0 to about 40.5 weight percent 1,1,1,2-tetrafluoroethane. Also disclosed herein are compositions comprising from about 54.0 to about 56.0 weight percent 2,3,3,3-tetrafluoropropene and from about 46.0 to about 44.0 weight percent 1,1,1,2-tetrafluoroethane. Also disclosed herein is a composition comprising a refrigerant consisting essentially of from about 58.0 to about 59.5 weight percent 2,3,3,3-tetrafluoropropene and from about 42.0 to about 40.5 weight percent 1,1,1,2-tetrafluoroethane. Also disclosed herein is a composition comprising a refrigerant consisting essentially of from about 54.0 to about 56.

Abstract: An absorption cycle system utilizes an additional absorption circuit in conjunction with a traditional absorption circuit. The absorbent used in the additional absorption circuit could contain an ionic compound, or any absorbent with relatively low crystallization. Mixtures of such absorbent with water remain liquid at temperatures lower than the minimum feasible operating temperature of the traditional lithium bromide water absorbent solutions of the prior art.

Abstract: An absorption cycle system utilizes an additional absorption circuit in conjunction with a traditional absorption circuit. The absorbent used in the additional absorption circuit could contain an ionic compound, or any absorbent with relatively low crystallization. Mixtures of such absorbent with water remain liquid at temperatures lower than the minimum feasible operating temperature of the traditional lithium bromide water absorbent solutions of the prior art.

Abstract: The present invention relates to a cascade refrigeration system which circulates a refrigerant comprising a fluoroolefin therethrough. The cascade refrigeration system includes a low temperature refrigeration loop and a medium temperature refrigeration loop. The fluoroolefin circulates through either loop, or both. In a particular embodiment, the fluoroolefin circulates through the medium temperature loop. In a particular embodiment, where the cascade refrigeration system includes a first and a second cascade heat exchanger, and a secondary heat transfer loop which extends between the first and second cascade heat exchangers, either the first and/or second refrigerant may be, but need not necessarily be, a fluoroolefin.

Abstract: Disclosed herein is an air conditioning or refrigeration apparatus, and in particular, a chiller apparatus containing a composition comprising 1,1,1,4,4,4-hexafluoro-2-butene and 1,2-dichloroethylene, wherein the 1,1,1,4,4,4-hexafluoro-2-butene is cis isomer or primarily cis isomer and wherein the 1,2-dichloroethylene is trans isomer or primarily trans isomer. These chillers may be flooded evaporators or direct expansion evaporators, which utilize centrifugal compressors. Also disclosed herein are methods for producing cooling comprising evaporating a composition comprising cis-1,1,1,4,4,4-hexafluoro-2-butene and trans-1,2-dichloroethylene in the vicinity of a body to be cooled. Also disclosed herein are compositions comprising cis-1,1,1,4,4,4-hexafluoro-2-butene and trans-1,2-dichloroethylene, wherein the cis-1,1,1,4,4,4-hexafluoro-2-butene is present at 50 to about 60 weight percent.

Abstract: Disclosed herein is a chiller apparatus containing refrigerant characterized by said refrigerant being HFO-1336mzz that is trans isomer or primarily trans isomer. These chillers may be flooded evaporators or direct expansion evaporators, which utilize either centrifugal or screw compressors. Also disclosed herein are methods for producing cooling comprising evaporating trans-HFO-1336mzz in an evaporator in the vicinity of a body to be cooled, thereby producing cooling. Also disclosed herein is a method for replacing HFC-236fa or CFC-114 refrigerant in a chiller apparatus, said method comprising providing HFO-1336mzz to said chiller apparatus in place of the replaced refrigerant; wherein said HFO-1336mzz is trans isomer or primarily trans isomer.

Abstract: Disclosed herein are chiller apparatus containing cis-HFO-1336mzz. These chillers may be centrifugal chillers or positive displacment (e.g., screw) chillers and may comprise flooded evaporators or direct expansion evaporators. Also disclosed herein are methods for producing cooling comprising evaporating cis-HFO-1336mzz in the vicinity of a body to be cooled.