Patents by Inventor Konstantinos Patsidis
Konstantinos Patsidis has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 7230128Abstract: Fluorenyl-containing metallocenes are disclosed along with methods for making the metallocenes. Also disclosed are methods for using the metallocenes as polymerization catalysts. In addition, polymers resulting from such polymerizations are disclosed.Type: GrantFiled: May 10, 2002Date of Patent: June 12, 2007Assignee: Phillips Potroleum CompanyInventors: Helmut G. Alt, Syriac J. Palackal, Konstantinos Patsidis, M. Bruce Welch, Rolf L. Geerts, Eric T. Hsieh, Max P. McDaniel, Gil R. Hawley, Paul D. Smith
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Publication number: 20060122344Abstract: Fluorenyl-containing metallocenes are disclosed along with methods for making the metallocenes. Also disclosed are methods for using the metallocenes as polymerization catalysts. In addition, polymers resulting from such polymerizations are disclosed.Type: ApplicationFiled: May 10, 2002Publication date: June 8, 2006Applicant: Phillips Petroleum CompanyInventors: HELMUT ALT, SYRIAC PALACKAL, KONSTANTINOS PATSIDIS, M. WELCH, ROLF GEERTS, ERIC HSIEH, MAX MCDANIEL, GIL HAWLEY, PAUL SMITH
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Patent number: 6420579Abstract: Bridged and unbridged fluorenyl-containing metallocenes of the formula R″x(FlRn)(CpRm)MQk wherein Fl is a fluorenyl radical, Cp is a cyclopentadienyl, indenyl, tetrahydroindenyl, or fluorenyl radical, each R is an organo radical, R″ is a structural bridge linking (FlRn) and (CpRm), M is a metal selected from the group consisting of IVB, VB, and VIB metals, each Q is selected from the group consisting of hydrocarbyl or hydrocarbyloxy radicals and halogen, x is 1 or 0, k is an integer sufficient to fill out the remaining valences of M, n is in the range of 0 to 7, and m is 0 to 7, further characterized by the fact that if (CpRm) is unsubstituted fluorenyl and metallocene is an unbridged metallocene, then n is 1 to 7 and if R″ is 1,1-dimethylmethylene and (CpRm) is unsubstituted cyclopentadienyl or 3-methylcyclopentadienyl, then n is 1 to 7.Type: GrantFiled: December 9, 1994Date of Patent: July 16, 2002Assignee: Phillips Petroleum CompanyInventors: Helmut G. Alt, Syriac J. Palackal, Konstantinos Patsidis, M. Bruce Welch, Rolf L. Geerts, Eric T. Hsieh, Max P. McDaniel, Gil R. Hawley, Paul D. Smith
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Patent number: 6403734Abstract: Bridged fluorenyl-containing metallocenes of metals of Groups 4-6 and their use in forming homopolymers of alpha olefins or polymers of ethylene and optionally minor amounts of alpha olefins, wherein in each case at least one of the cyclic groups of the bridged ligand is a fluorenyl and the other is selected from indenyl, tetrahydroindenyl, fluorenyl, and in the case of the polymerization of ethylene optionally cyclopentadienyl.Type: GrantFiled: November 23, 1998Date of Patent: June 11, 2002Assignee: Phillips Petroleum CompanyInventors: Helmut G. Alt, Syriac J. Palackal, Konstantinos Patsidis, M. Bruce Welch, Rolf L. Geerts, Eric T. Hsieh, Max P. McDaniel, Gil R. Hawley, Paul D. Smith
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Patent number: 6162936Abstract: Fluorenyl-containing metallocenes are disclosed along with methods for making the metallocenes. Also disclosed are methods for using the metallocenes as polymerization catalysts. In addition, polymers resulting from such polymerizations are disclosed.Type: GrantFiled: May 28, 1998Date of Patent: December 19, 2000Assignee: Phillips Petroleum CompanyInventors: Helmut G. Alt, Syriac J. Palackal, Konstantinos Patsidis, M. Bruce Welch, Rolf L. Geerts, Eric T. Hsieh, Max P. McDaniel, Gil R. Hawley, Paul D. Smith
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Patent number: 5637744Abstract: Group IVB metal metallocenes of bis(1-methyl fluorenyl) diphenyl silane and bis(1-methyl fluorenyl) dimethyl tin are disclosed, plus their use in the production of polyolefins, including isotactic polypropylene.Type: GrantFiled: June 1, 1995Date of Patent: June 10, 1997Assignee: Phillips Petroleum CompanyInventors: Helmut G. Alt, Konstantinos Patsidis, M. Bruce Welch, Peter P. Chu
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Patent number: 5631335Abstract: Group IVB metal metallocenes of bis(1-methyl fluorenyl) diphenyl silane and bis(1-methyl fluorenyl) dimethyl tin are disclosed, plus their use in the production of polyolefins, including isotactic polypropylene.Type: GrantFiled: June 7, 1993Date of Patent: May 20, 1997Assignee: Phillips Petroleum CompanyInventors: Helmut G. Alt, Konstantinos Patsidis, M. Bruce Welch, Peter P. Chu
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Patent number: 5627247Abstract: Unbridged fluorenyl containing metallocenes are disclosed along with methods for making the metallocenes. Also disclosed are methods for using the metallocenes as polymerization catalysts. In addition, polymers resulting from such polymerizations are disclosed.Type: GrantFiled: March 22, 1995Date of Patent: May 6, 1997Assignee: Phillips Petroleum CompanyInventors: Helmut G. Alt, Gil R. Hawley, Paul D. Smith, Syriac J. Palackal, Michael Schmid, M. Bruce Welch, Konstantinos Patsidis, Rolf L. Geerts, Eric T. Hsieh, Max P. McDaniel
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Patent number: 5627118Abstract: Fluorenyl-containing silyl bridged metallocenes, the process of using such metallocenes to polymerize olefins, and the resulting unusual syndiotactic polypropylene are disclosed.Type: GrantFiled: December 9, 1994Date of Patent: May 6, 1997Assignee: Phillips Petroleum CompanyInventors: Syriac J. Palackal, Helmut G. Alt, Konstantinos Patsidis, Tara G. Hill, Gil R. Hawley, Peter P. Chu, M. Bruce Welch, Rolf L. Geerts
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Patent number: 5616752Abstract: A method is provided for forming a supported cyclopentadiene-type compound comprising contacting a cyclopentadiene-type compound containing an active halogen with an inorganic support having surface hydroxyl group. Also there is provided a method of preparing a supported metallocene comprising reacting the supported cyclopentadiene-type compound with a transition metal compound under suitable conditions. There is also provided a process for producing bridged cyclopentadiene-type ligands having a bridge having branch that has a terminal vinyl group. Also metallocenes of these ligands are provided. Still further there is provided a process for producing bridged cyclopentadiene-type ligands having a bridge having a branch that has a terminal active halogen. The resulting new ligands and supported metallocenes produced therefrom are also provided.Type: GrantFiled: June 5, 1995Date of Patent: April 1, 1997Assignee: Phillips Petroleum CompanyInventors: Konstantinos Patsidis, Bernd Peifer, Helmut G. Alt, Rolf L. Geerts, Darryl R. Fahey, M. Bruce Welch, Syriac J. Palackal, Harold R. Deck
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Patent number: 5610247Abstract: 9-substituted fluorenyl-containing metallocenes and their use in the polymerization of olefins is disclosed. In addition, novel 9-cyclohexylfluorenyl or 9-phenylfluorenyl compounds are disclosed. Also methods for preparing such 9-substituted fluorenyl compounds are presented.Type: GrantFiled: March 23, 1995Date of Patent: March 11, 1997Assignee: Phillips Petroleum CompanyInventors: Helmut G. Alt, Syriac J. Palackal, Konstantinos Patsidis, M. Bruce Welch, Rolf L. Geerts, Eric T. Hsieh, Max P. McDaniel, Gil R. Hawley, Paul D. Smith, Jay Janzen, Michael Schmid
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Patent number: 5565592Abstract: A method is provided for forming a supported cyclopentadiene-type compound comprising contacting a cyclopentadiene-type compound containing an active halogen with an inorganic support having surface hydroxyl group. Also there is provided a method of preparing a supported metallocene comprising reacting the supported cyclopentadiene-type compound with a transition metal compound under suitable conditions. There is also provided a process for producing bridged cyclopentadiene-type ligands having a bridge having branch that has a terminal vinyl group. Also metallocenes of these ligands are provided. Still further there is provided a process for producing bridged cyclopentadiene-type ligands having a bridge having a branch that has a terminal active halogen. The resulting new ligands and supported metallocenes produced therefrom are also provided.Type: GrantFiled: March 10, 1995Date of Patent: October 15, 1996Assignee: Phillips Petroleum CompanyInventors: Konstantinos Patsidis, Bernd Peifer, Syriac J. Palackal, Helmut G. Alt, M. Bruce Welch, Rolf L. Geerts, Darryl R. Fahey, Harold R. Deck
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Patent number: 5541351Abstract: Processes are disclosed for preparing compounds of the formula Z--R--Z where each Z can be selected from cyclopentadienyl type radicals such as substituted or unsubstituted cyclopentadienyl, indenyl, fluorenyl or tetrahydroindenyl or where one Z is Cl, Br, or I by reacting specific Z precursors with a dihaloalkylene compound. Also new cyclopentadienyl-type compounds are disclosed.Type: GrantFiled: August 15, 1994Date of Patent: July 30, 1996Assignee: Phillips Petroleum CompanyInventors: Konstantinos Patsidis, Syriac J. Palackal, Helmut G. Alt
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Patent number: 5466766Abstract: A method is provided for forming a supported cyclopentadiene-type compound comprising contacting a cyclopentadiene-type compound containing an active halogen with an inorganic support having surface hydroxyl group. Also there is provided a method of preparing a supported metallocene comprising reacting the supported cyclopentadiene-type compound with a transition metal compound under suitable conditions. There is also provided a process for producing bridged cyclopentadiene-type ligands having a bridge having branch that has a terminal vinyl group. Also metallocenes of these ligands are provided. Still further there is provided a process for producing bridged cyclopentadiene-type ligands having a bridge having a branch that has a terminal active halogen. The resulting new ligands and supported metallocenes produced therefrom are also provided.Type: GrantFiled: November 17, 1993Date of Patent: November 14, 1995Assignee: Phillips Petroleum CompanyInventors: Konstantinos Patsidis, Bernd Peifer, Syriac J. Palackal, Helmut G. Alt, M. Bruce Welch, Rolf L. Geerts, Darryl R. Fahey, Harold R. Deck
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Patent number: 5459218Abstract: Fluorenyl-containing silyl bridged metallocenes, the process of using such metallocenes to polymerize olefins, and the resulting unusual syndiotactic polypropylene are disclosed.Type: GrantFiled: December 9, 1994Date of Patent: October 17, 1995Assignee: Phillips Petroleum CompanyInventors: Syriac J. Palackal, Helmut G. Alt, Konstantinos Patsidis, Tara G. Hill, Gil R. Hawley, Peter P. Chu, M. Bruce Welch, Rolf L. Geerts
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Patent number: 5436305Abstract: Fluorenyl-containing metallocenes are disclosed along with methods for making the metallocenes. Also disclosed are methods for using the metallocenes as polymerization catalysts. In addition, polymers resulting from such polymerizations are disclosed.Type: GrantFiled: July 23, 1991Date of Patent: July 25, 1995Assignee: Phillips Petroleum CompanyInventors: Helmut G. Alt, Syriac J. Palackal, Konstantinos Patsidis, M. Bruce Welch, Rolf L. Geerts, Eric T. Hsieh, Max P. McDaniel, Gil R. Hawley, Paul D. Smith
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Patent number: 5406013Abstract: Processes are disclosed for preparing compounds of the formula Z--R--Z where each Z can be selected from cyclopentadienyl type radicals such as substituted or unsubstituted cyclopentadienyl, indenyl, fluorenyl or tetrahydroindenyl or where one Z is Cl, Br, or I by reacting specific Z precursors with a dihaloalkylene compound. Also new cyclopentadienyl-type compounds are disclosed.Type: GrantFiled: January 11, 1993Date of Patent: April 11, 1995Assignee: Phillips Petroleum CompanyInventors: Konstantinos Patsidis, Syriac J. Palackal, Helmut G. Alt
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Patent number: 5401817Abstract: Fluorenyl-containing silyl bridged metallocenes, the process of using such metallocenes to polymerize olefins, and the resulting unusual syndiotactic polypropylene are disclosed.Type: GrantFiled: May 20, 1993Date of Patent: March 28, 1995Assignee: Phillips Petroleum CompanyInventors: Syriac J. Palackal, Helmut G. Alt, Konstantinos Patsidis, Tara G. Hill, Gil R. Hawley, Peter P. Chu, M. Bruce Welch, Rolf L. Geerts
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Patent number: 5399636Abstract: A composition is provided comprising a metallocene having the formula of: ##STR1## wherein each Z can be the same or different hydrocarbyl radical selected from the group consisting of cyclopentadienyl, indenyl, tetrahydroindenyl, fluorenyl, and mixtures thereof; each X can be the same or different and is selected from the group consisting of hydrogen, fluorine, chlorine, bromine, iodine, R, OR, NR.sub.2, PR.sub.2, or OQ, or mixtures thereof wherein the R is a C.sub.1 -C.sub.20 hydrocarbyl radical and Q is an inorganic moiety selected from the group consisting of silica, alumina, clay, phosphated alumina, and mixtures thereof; each Y can be the same or different and is an alkyl group, hydrogen, fluorine, chlorine, bromine, iodine, or mixtures thereof; E is selected from C, Sn, Si, Ge, B, Al, N, or P; M is a metal selected from Ti, Zr, Hf, Sc, Y, V, or La; m is a number sufficient to fill out the valences of metal M; and n is 1 or 2.Type: GrantFiled: June 11, 1993Date of Patent: March 21, 1995Assignee: Phillips Petroleum CompanyInventors: Helmut G. Alt, Konstantinos Patsidis, M. Bruce Welch, Rolf L. Geerts, Bernd Peifer, Syriac J. Palackal
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Patent number: 5393911Abstract: New fluorenyl silane compounds and method for their production are disclosed. The fluorenyl compounds have the formula ##STR1## wherein Z is a substituted or unsubstituted fluorenyl radical and Z' is a substituted or unsubstituted cyclopentadienyl-type radical or a halogen.Type: GrantFiled: November 30, 1992Date of Patent: February 28, 1995Assignee: Phillips Petroleum CompanyInventors: Konstantinos Patsidis, Syriac J. Palackal, Helmut G. Alt