Abstract: An object of the present invention is to provide sulfide solid electrolyte glass ceramics that have a high ionic conductivity and an enhanced water resistance, and is also to provide a method of producing the sulfide solid electrolyte glass ceramics. Sulfide solid electrolyte glass ceramics that have peaks at 20.2° and 23.6° in an X-ray diffractometry (XRD) using the CuK? line, a crystallite diameter of 30 nm or more, and a P2S64? phosphorus proportion obtained by a solid 31P-NMR spectroscopy of 4.5% by mol or less, and a method of producing the sulfide solid electrolyte glass ceramics are provided.

Abstract: A sulfide solid electrolyte that contains lithium, phosphorus, sulfur, chlorine and bromine, wherein in powder X-ray diffraction analysis using CuK? rays, it has a diffraction peak A at 2?=25.2±0.5 deg and a diffraction peak B at 2?=29.7±0.5 deg, the diffraction peak A and the diffraction peak B satisfy the following formula (A), and a molar ratio of the chlorine to the phosphorus “c (Cl/P)” and a molar ratio of the bromine to the phosphorus “d (Br/P)” satisfies the following formula (1): 1.2<c+d<1.9??(1) 0.845<SA/SB<1.200??(A) where SA is an area of the diffraction peak A and SB is an area of the diffraction peak B.

Abstract: A sulfide solid electrolyte may include lithium, phosphorus and sulfur, and the sulfide solid electrolyte may have a diffraction peak A at 2?=25.2±0.5 deg and a diffraction peak B at 29.7±0.5 deg in powder X-ray diffraction using CuK? rays, and a crystallite diameter in a range of from 5 to 20 nm.

Abstract: A sulfide solid electrolyte containing the following (A) and (B): (A) a sulfide solid electrolyte having an argyrodite-type crystal structure; and (B) a sulfide solid electrolyte having a crystal structure different from the argyrodite-type crystal structure of the above-mentioned (A).

Abstract: A sulfide solid electrolyte that contains lithium, phosphorus, sulfur, chlorine and bromine, wherein in powder X-ray diffraction analysis using CuK? rays, it has a diffraction peak A at 2?=25.2±0.5 deg and a diffraction peak B at 2?=29.7±0.5 deg, the diffraction peak A and the diffraction peak B satisfy the following formula (A), and a molar ratio of the chlorine to the phosphorus “c (Cl/P)” and a molar ratio of the bromine to the phosphorus “d (Br/P)” satisfies the following formula (1): 1.2<c+d<1.9??(1) 0.845<SA/SB<1.200??(A) where SA is an area of the diffraction peak A and SB is an area of the diffraction peak B.

Abstract: Provided is a sulfide solid electrolyte containing lithium, phosphorus, sulfur and chlorine, in which a molar ratio of the chlorine to the phosphorus, c (Cl/P), is greater than 1.0 and 1.9 or less, the sulfide solid electrolyte includes an argyrodite-type crystal structure, and a lattice constant of the argyrodite-type crystal structure is 9.820 ? or less.

Abstract: Provided is a sulfide solid electrolyte containing lithium, phosphorus, sulfur and chlorine, in which a molar ratio of the chlorine to the phosphorus, c (Cl/P), is greater than 1.0 and 1.9 or less, the sulfide solid electrolyte includes an argyrodite-type crystal structure, and a lattice constant of the argyrodite-type crystal structure is 9.820 ? or less.

Abstract: A sulfide solid electrolyte comprising lithium, phosphorus and sulfur, wherein the sulfide solid electrolyte has a diffraction peak A at 2?=25.2±0.5 deg and a diffraction peak B at 29.7±0.5 deg in powder X-ray diffraction using CuK? rays, an area ratio of a peak derived from PS43? glass to the total area of peaks derived from glass observed in solid 31P-NMR measurement is 90% or more and 100% or less, and an area ratio of peaks derived from glass to the total area of all peaks at 60 to 120 ppm observed in solid 31P-NMR measurement is 1% or more and 45% or less.

Abstract: A sulfide solid electrolyte particles comprising lithium, phosphorus and sulfur, having a volume-based average particle size measured by laser diffraction particle size distribution measurement of 0.1 ?m to 10 ?m, having a diffraction peak having 2? of 29.0 to 31.0 deg in powder X-ray diffraction measurement using CuK? ray, and an intensity ratio (Ib/Ip) of a peak intensity Ib at a high angle-side low part of the diffraction peak to a peak intensity Ip of the diffraction peak is less than 0.09.

Abstract: A sulfide solid electrolyte may include lithium, phosphorus and sulfur, and the sulfide solid electrolyte may have a diffraction peak A at 2?=25.2±0.5 deg and a diffraction peak B at 29.7±0.5 deg in powder X-ray diffraction using CuK? rays, and a crystallite diameter in a range of from 5 to 20 nm.

Abstract: A sulfide solid electrolyte that contains lithium, phosphorus, sulfur, chlorine and bromine, wherein in powder X-ray diffraction analysis using CuK? rays, it has a diffraction peak A at 2?=25.2±0.5 deg and a diffraction peak B at 2?=29.7±0.5 deg, the diffraction peak A and the diffraction peak B satisfy the following formula (A), and a molar ratio of the chlorine to the phosphorus “c (Cl/P)” and a molar ratio of the bromine to the phosphorus “d (Br/P)” satisfies the following formula (1): 1.2<c+d<1.9??(1) 0.845<SA/SB<1.200??(A) where SA is an area of the diffraction peak A and SB is an area of the diffraction peak B.

Abstract: It is an object of the invention to provide sulfide solid electrolytes having good processability at the time of manufacturing a battery and high ionic conductivity. The present invention relates to a sulfide solid electrolyte containing lithium, phosphorus and sulfur, having a diffraction peak A at 2?=25.2±0.5 deg and a diffraction peak B at 29.7±0.5 deg in powder X-ray diffraction using CuK? rays, and the half-value width of at least one peak obtained by separating the peaks observed in a range of 60 to 120 ppm in solid-state 31P-NMR measurements is 500 to 800 Hz.

Abstract: A sulfide solid electrolyte that contains lithium, phosphorus, sulfur, chlorine and bromine, wherein in powder X-ray diffraction analysis using CuK? rays, it has a diffraction peak A at 2?=25.2±0.5 deg and a diffraction peek B at 2?=29.7±0.5 deg, the diffraction peak A and the diffraction peak B satisfy the following formula (A), and a molar ratio of the chlorine to the phosphorus “c (Cl/P)” and a molar ratio of the bromine to the phosphorus “d (Br/P)” satisfies the following formula (1): 1.2<c+d<1.9??(1) 0.845<SA/SB<1.200??(A) where SA is an area of the diffraction peak A and SB is an area of the diffraction peak B.

Abstract: A sulfide solid electrolyte containing lithium, phosphorus, sulfur; and one or more of elements X selected from the group consisting of halogen elements and chalcogen elements excluding sulfur, wherein the sulfide solid electrolyte includes an argyrodite-type crystal structure, and wherein a molar ratio of the lithium to the phosphorus, a (Li/P), a molar ratio of the sulfur to the phosphorus, b (S/P), and a molar ratio of the element X to the phosphorus, c (X/P), satisfy formulas (1) to (3): 5.0?a?7.1 (1) 1.0<a?b?1.5 (2) 6.5?a+c<7.1 (3) wherein b>0 and c>0 are satisfied.

Abstract: A sulfide solid electrolyte that contains lithium, phosphorus, sulfur, chlorine and bromine, wherein in powder X-ray diffraction analysis using CuK? rays, it has a diffraction peak A at 2?=25.2±0.5 deg and a diffraction peek B at 2?=29.7±0.5 deg, the diffraction peak A and the diffraction peak B satisfy the following formula (A), and a molar ratio of the chlorine to the phosphorus “c (Cl/P)” and a molar ratio of the bromine to the phosphorus “d (Br/P)” satisfies the following formula (1): 1.2<c+d<1.9??(1) 0.845<SA/SB<1.200??(A) where SA is an area of the diffraction peak A and SB is an area of the diffraction peak B.

Abstract: A sulfide solid electrolyte that contains lithium, phosphorus, sulfur, chlorine and bromine, wherein in powder X-ray diffraction analysis using CuK? rays, it has a diffraction peak A at 2?=25.2±0.5 deg and a diffraction peak B at 2?=29.7±0.5 deg, the diffraction peak A and the diffraction peak B satisfy the following formula (A), and a molar ratio of the chlorine to the phosphorus “c (Cl/P)” and a molar ratio of the bromine to the phosphorus “d (Br/P)” satisfies the following formula (1): 1.2<c+d<1.9??(1) 0.845<SA/SB<1.200??(A) where SA is an area of the diffraction peak A and SB is an area of the diffraction peak B.

Abstract: Aimed at providing a sulfide solid electrolyte comprising an argyrodite type crystal structure, having a high ionic conductivity due to presence of a large amount of a halogen element and is capable of suppressing agglomeration at the time of production. Provided is a sulfide solid electrolyte comprising lithium, phosphorus, sulfur and one or more elements X selected from halogen elements, wherein the sulfide solid electrolyte comprises an argyrodite type crystal structure, and wherein a molar ratio of the lithium to the phosphorus “a (Li/P)”, a molar ratio of the sulfur to the phosphorus “b (S/P)” and a molar ratio of the element X to the phosphorus “c (X/P)” satisfy the following formulas (1) to (3): 5.0?a<7.3??(1) 0.70?a?b<1.0??(2) 7.0<a+c?7.3??(3) provided that b>0 and c>0.

Abstract: A sulfide solid electmlyte containing the following (A) and (B): (A) a sulfide solid electrolyte having an argyrodite-type crystal structure; and (B) a sulfide solid electrolyte having a crystal structure different from the argyrodite-type crystal structure of the above-mentioned (A).

Abstract: A sulfide solid electrolyte comprising lithium, phosphorus and sulfur, wherein the sulfide solid electrolyte has a diffraction peak A at 2?=25.2±0.5 deg and a diffraction peak B at 29.7±0.5 deg in powder X-ray diffraction using CuK? rays, an area ratio of a peak derived from PS43? glass to the total area of peaks derived from glass observed in solid 31P-NMR measurement is 90% or more and 100% or less, and an area ratio of peaks derived from glass to the total area of all peaks at 60 to 120 ppm observed in solid 31P-NMR measurement is 1% or more and 45% or less.

Abstract: It is an object of the invention to provide sulfide solid electrolytes having good processability at the time of manufacturing a battery and high ionic conductivity. The present invention relates to a sulfide solid electrolyte containing lithium, phosphorus and sulfur, having a diffraction peak A at 2?=25.2±0.5 deg and a diffraction peak B at 29.7±0.5 deg in powder X-ray diffraction using CuK? rays, and the half-value width of at least one peak obtained by separating the peaks observed in a range of 60 to 120 ppm in solid-state 31P-NMR measurements is 500 to 800 Hz.