Abstract: A graft copolymer (B) produced by graft polymerization of a vinyl monomer mixture (m1) including an alkyl (meth)acrylate ester onto a copolymer (A), the copolymer (A) being a copolymer of an alkyl (meth)acrylate ester (Aa) and a (meth)acrylate ester (Ab) including an aromatic hydrocarbon group. A thermoplastic resin composition including the graft copolymer (B), a copolymer (C) that is the product of a polymerization reaction of a vinyl monomer mixture (m2) including an alkyl (meth)acrylate ester, and a molded article produced by molding the thermoplastic resin composition. Provided are the graft copolymer with which a thermoplastic resin composition excellent in terms of transparency, impact resistance, weather resistance, and flowability may be produced, a thermoplastic resin composition including the graft copolymer, and the molded article produced by molding the thermoplastic resin composition.

Abstract: A graft copolymer (B) produced by graft polymerization of a vinyl monomer mixture (m1) including an alkyl (meth)acrylate ester onto a copolymer (A), the copolymer (A) being a copolymer of an alkyl (meth)acrylate ester (Aa) and a (meth)acrylate ester (Ab) including an aromatic hydrocarbon group. A thermoplastic resin composition including the graft copolymer (B), a copolymer (C) that is the product of a polymerization reaction of a vinyl monomer mixture (m2) including an alkyl (meth)acrylate ester, and a molded article produced by molding the thermoplastic resin composition. Provided are the graft copolymer with which a thermoplastic resin composition excellent in terms of transparency, impact resistance, weather resistance, and flowability may be produced, a thermoplastic resin composition including the graft copolymer, and the molded article produced by molding the thermoplastic resin composition.

Abstract: According to the present invention, a polymer is provided capable of obtaining a graft polymer having a high graft ratio while having a low degree of crosslinking, a graft polymer having a high graft ratio, which is suitable as a material of a thermoplastic resin composition capable of obtaining a molded article excellent in impact resistance, surface appearance, and thermal stability, and a thermoplastic resin composition capable of obtaining a molded article excellent in impact resistance, surface appearance, and thermal stability. A polymer obtained by polymerizing a mixture containing an (Aa) component and an (Ab) component is used. The (Aa) component is an acrylic acid ester. The (Ab) component is a branched polyfunctional compound having two or more allyl groups, and all carbon-carbon double bonds contained in the polyfunctional compound are derived from the allyl groups.

Abstract: A thermoplastic resin composition of the present invention contains a graft copolymer (B) obtained by polymerizing a vinyl-based monomer component (m1) in the presence of a composite rubber polymer (A) formed from a polyorganosiloxane (Aa) and a poly(meth)acrylate ester (Ab), and a (meth)acrylate ester resin (C) obtained by polymerizing a vinyl-based monomer component (m2), wherein the amount of the polyorganosiloxane (Aa) relative to the total mass (100% by mass) of the composite rubber polymer (A) is from 1 to 20% by mass, the volume average particle size of the composite rubber polymer (A) is from 0.05 to 0.15 ?m, and relative to the total mass (100% by mass) of the vinyl-based monomer component (m2), the amount of the maleimide-based compound is from 1 to 30% by mass, and the amount of the aromatic vinyl compound is from 5.5 to 15% by mass.

Abstract: [Object] To provide lubricating thermoplastic resin compositions that can give formed articles exhibiting excellent lubricating properties and surface appearance and maintaining the lubricating properties permanently. [Solution] The lubricating thermoplastic resin composition includes an acid-modified copolymer (A) of a monomer mixture including an aromatic vinyl and a vinyl cyanide, the copolymer having a carboxyl group in the molecular chain, and a functionalized lubricant (B) having, in the molecule, a functional group (B1) capable of reacting with the carboxyl group and a lubricating segment (B2) having lubricating properties. The composition may further include a graft copolymer (C) and/or an additional thermoplastic resin (D) other than the acid-modified copolymer (A).

Abstract: This graft copolymer is obtainable by polymerization of a vinyl-based monomer mixture (m1) including an aromatic vinyl compound and a vinyl cyanide compound, in the presence of: an ethylene.?-olefin copolymer (A) which has a mass average molecular weight (Mw) of 17×104 to 35×104 and a distribution of molecular weight (Mw/Mn) of 1 to 3; or a cross-linked ethylene.?-olefin copolymer (C) obtainable by cross-linking treatment of the ethylene.?-olefin copolymer (A).

Abstract: A thermoplastic resin composition of the present invention contains a graft copolymer (B) obtained by polymerizing a vinyl-based monomer component (m1) in the presence of a composite rubber polymer (A) formed from a polyorganosiloxane (Aa) and a poly(meth)acrylate ester (Ab), and a (meth)acrylate ester resin (C) obtained by polymerizing a vinyl-based monomer component (m2), wherein the amount of the polyorganosiloxane (Aa) relative to the total mass (100% by mass) of the composite rubber polymer (A) is from 1 to 20% by mass, the volume average particle size of the composite rubber polymer (A) is from 0.05 to 0.15 ?m, and relative to the total mass (100% by mass) of the vinyl-based monomer component (m2), the amount of the maleimide-based compound is from 1 to 30% by mass, and the amount of the aromatic vinyl compound is from 5.5 to 15% by mass.

Abstract: This graft copolymer is obtainable by polymerization of a vinyl-based monomer mixture (m1) including an aromatic vinyl compound and a vinyl cyanide compound, in the presence of: an ethylene.?-olefin copolymer (A) which has a mass average molecular weight (Mw) of 17×104 to 35×104 and a distribution of molecular weight (Mw/Mn) of 1 to 3; or a cross-linked ethylene.?-olefin copolymer (C) obtainable by cross-linking treatment of the ethylene.?-olefin copolymer (A).

Abstract: [Object] To provide lubricating thermoplastic resin compositions that can give formed articles exhibiting excellent lubricating properties and surface appearance and maintaining the lubricating properties permanently. [Solution] The lubricating thermoplastic resin composition includes an acid-modified copolymer (A) of a monomer mixture including an aromatic vinyl and a vinyl cyanide, the copolymer having a carboxyl group in the molecular chain, and a functionalized lubricant (B) having, in the molecule, a functional group (B1) capable of reacting with the carboxyl group and a lubricating segment (B2) having lubricating properties. The composition may further include a graft copolymer (C) and/or an additional thermoplastic resin (D) other than the acid-modified copolymer (A).