Patents by Inventor Krassimir Garbev

Krassimir Garbev has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 9751771
    Abstract: A process for preparing dicalcium silicate includes providing a starting material comprising calcium carbonate (CaCO3) and silicon dioxide (SiO2), wherein a molar ratio of calcium:silicon (C:S) is from 1.5:1 to 2.5:1. At least one of an inorganic alkali metal salt and an alkaline earth metal salt is added as a mineralizing agent to the starting material in an amount of from 0.5 wt.-% to 20 wt.-%, based on a total weight of the starting material. The starting material is reacted with the mineralizing agent in a gas atmosphere having a CO2 partial pressure of from 0.05 MPa to 0.2 MPa at a temperature of from 900° C. to 1100° C. so as to obtain a dicalcium silicate product. The dicalcium silicate product comprises a content of an unreacted starting material of <5 wt.-% and a total carbon content of <1.5 wt.-%, each based on a weight of the dicalcium silicate product.
    Type: Grant
    Filed: July 24, 2013
    Date of Patent: September 5, 2017
    Assignee: KARLSRUHER INSTITUT FUER TECHNOLOGIE
    Inventors: Hans Hunsinger, Guenter Beuchle, Peter Stemmermann, Uwe Schweike, Karolina Giziewicz, Krassimir Garbev
  • Publication number: 20150158733
    Abstract: A process for preparing dicalcium silicate includes providing a starting material comprising calcium carbonate (CaCO3) and silicon dioxide (SiO2), wherein a molar ratio of calcium:silicon (C:S) is from 1.5:1 to 2.5:1. At least one of an inorganic alkali metal salt and an alkaline earth metal salt is added as a mineralizing agent to the starting material in an amount of from 0.5 wt.-% to 20 wt.-%, based on a total weight of the starting material. The starting material is reacted with the mineralizing agent in a gas atmosphere having a CO2 partial pressure of from 0.05 MPa to 0.2 MPa at a temperature of from 900° C. to 1100° C. so as to obtain a dicalcium silicate product. The dicalcium silicate product comprises a content of an unreacted starting material of <5 wt.-% and a total carbon content of <1.5 wt.-%, each based on a weight of the dicalcium silicate product.
    Type: Application
    Filed: July 24, 2013
    Publication date: June 11, 2015
    Applicant: KARLSRUHER INSTITUT FUER TECHNOLOGIE
    Inventors: Hans Hunsinger, Guenter Beuchle, Peter Stemmermann, Uwe Schweike, Karolina Warzycha, Krassimir Garbev
  • Patent number: 8382892
    Abstract: The invention relates to a monophase amorphous hydraulic binder containing silicon, calcium and oxygen atoms in an arrangement comprising silicate building units having an average connectedness of at least Q1, with none or a part of the calcium atoms being substituted for by a metal atom M[6]x+ sixfold or higher-coordinated with oxygen and/or none or no more than 45 atomic percent of the silicon atoms being substituted for by a metal atom M[4]y+ tetrahedrally coordinated with oxygen, the molar ratio of [CaO+(x/2)·(M[6]x+Ox/2)]:[SiO2+M[4]y+Oy/2] having a value of 0.2 to 1.5, and the binder having less than 3.5% by weight of water, as well as a mixture containing this binder.
    Type: Grant
    Filed: July 16, 2008
    Date of Patent: February 26, 2013
    Assignee: Karlsruher Institut fuer Technologie
    Inventors: Guenter Beuchle, Peter Stemmermann, Uwe Schweike, Krassimir Garbev
  • Patent number: 8226764
    Abstract: The invention relates to a monophase hydraulic binder containing silicon, calcium, oxygen and hydrogen atoms in an arrangement comprising silicate building units having an average connectedness of higher than Q1.5 and silanol groups, with none or a part of the calcium atoms being substituted for by a metal atom M[6]x+ sixfold or higher-coordinated with oxygen and/or none or a part of the silicon atoms being substituted for by a metal atom M[4]y+ tetrahedrally coordinated with oxygen, the molar ratio of [CaO+(x/2)·(M[6]x+Ox/2)]: [SiO2+M[4]y+Oy/2] having a value of 0.2 to 2.0, and the binder having an H2O content of 3.5% by weight to 20% by weight, as well as a mixture containing this binder.
    Type: Grant
    Filed: July 16, 2008
    Date of Patent: July 24, 2012
    Assignee: Karlsruher Institut fuer Technologie
    Inventors: Guenter Beuchle, Peter Stemmermann, Uwe Schweike, Krassimir Garbev
  • Patent number: 8226763
    Abstract: The invention relates to a monophase hydraulic binder containing silicon, calcium, oxygen and hydrogen atoms in an arrangement comprising silicate building units having an average connectedness of no more than Q1.5 and silanol groups, with none or a part of the calcium atoms being substituted for by a metal atom M[6]x+ sixfold or higher-coordinated with oxygen and/or none or a part of the silicon atoms being substituted for by a metal atom M[4]y+ tetrahedrally coordinated with oxygen, the molar ratio of [CaO+(x/2)·(M[6]x+Ox/2)]:[SiO2+M[4]y+Oy/2] having a value of 0.75 to 2.75, and the binder containing an H2O content of 3.5% by weight to 20% by weight, as well as a mixture containing this binder.
    Type: Grant
    Filed: July 16, 2008
    Date of Patent: July 24, 2012
    Assignee: Karlsruher Institut Fuer Technologie
    Inventors: Guenter Beuchle, Peter Stemmermann, Uwe Schweike, Krassimir Garbev
  • Publication number: 20110041737
    Abstract: The invention relates to a monophase amorphous hydraulic binder containing silicon, calcium and oxygen atoms in an arrangement comprising silicate building units having an average connectedness of at least Q1, with none or a part of the calcium atoms being substituted for by a metal atom M[6]x+ sixfold or higher-coordinated with oxygen and/or none or no more than 45 atomic percent of the silicon atoms being substituted for by a metal atom M[4]y+ tetrahedrally coordinated with oxygen, the molar ratio of [CaO+(x/2)·(M[6]x+Ox/2)]:[SiO2+M[4]y+Oy/2] having a value of 0.2 to 1.5, and the binder having less than 3.5% by weight of water, as well as a mixture containing this binder.
    Type: Application
    Filed: July 16, 2008
    Publication date: February 24, 2011
    Inventors: Guenter Beuchle, Peter Stemmermann, Uwe Schweike, Krassimir Garbev
  • Patent number: 7807078
    Abstract: A method for producing components including preparing an aqueous suspension of solids including calcium oxide CaO and silicon dioxide SiO2 with a molar ratio of Ca:Si that is between 0.5:1.0 and 2.5:1.0. Nanocrystalline C—S—H phases are produced by grinding the aqueous suspension and keeping its temperature at or below 100° C. The aqueous phase is separated out from the suspension to form a residue containing the nanocrystalline C—S—H phases. The residued is removed and a powdery product is made by drying the residue. A mold is filled with the powdery product and pressure is applied to form the component. The component is removed from the mold.
    Type: Grant
    Filed: March 24, 2006
    Date of Patent: October 5, 2010
    Assignee: Forschungszentrum Karlsruhe GmbH
    Inventors: Peter Stemmermann, Krassimir Garbev, Guenter Beuchle, Uwe Schweike
  • Publication number: 20100206199
    Abstract: The invention relates to a monophase hydraulic binder containing silicon, calcium, oxygen and hydrogen atoms in an arrangement comprising silicate building units having an average connectedness of higher than Q1.5 and silanol groups, with none or a part of the calcium atoms being substituted for by a metal atom M[6]x+ sixfold or higher-coordinated with oxygen and/or none or a part of the silicon atoms being substituted for by a metal atom M[4]Yy+ tetrahedrally coordinated with oxygen, the molar ratio of [CaO+(x/2) (M[6]x+Ox/2)]: [SiO2+M[4]y+Oy/2] having a value of 0.2 to 2.0, and the binder having an H2O content of 3.5% by weight to 20% by weight, as well as a mixture containing this binder.
    Type: Application
    Filed: July 16, 2008
    Publication date: August 19, 2010
    Inventors: Guenter Beuchle, Peter Stemmermann, Uwe Schweike, Krassimir Garbev
  • Publication number: 20100186634
    Abstract: The invention relates to a monophase hydraulic binder containing silicon, calcium, oxygen and hydrogen atoms in an arrangement comprising silicate building units having an average connectedness of no more than Q1.5 and silanol groups, with none or a part of the calcium atoms being substituted for by a metal atom M[6]x+ sixfold or higher-coordinated with oxygen and/or none or a part of the silicon atoms being substituted for by a metal atom M[4]y+ tetrahedrally coordinated with oxygen, the molar ratio of [CaO+(x/2)·(M[6]x+Ox/2)]:[SiO2+M[4]y+Oy/2] having a value of 0.75 to 2.75, and the binder containing an H2O content of 3.5% by weight to 20% by weight, as well as a mixture containing this binder.
    Type: Application
    Filed: July 16, 2008
    Publication date: July 29, 2010
    Inventors: Guenter Beuchle, Peter Stemmermann, Uwe Schweike, Krassimir Garbev
  • Publication number: 20080093774
    Abstract: A method for producing components including preparing an aqueous suspension of solids including calcium oxide CaO and silicon dioxide SiO2 with a molar ratio of Ca:Si that is between 0.5:1.0 and 2.5:1.0. Nanocrystalline C—S—H phases are produced by grinding the aqueous suspension and keeping its temperature at or below 100° C. The aqueous phase is separated out from the suspension to form a residue containing the nanocrystalline C—S—H phases. The residued is removed and a powdery product is made by drying the residue. A mold is filled with the powdery product and pressure is applied to form the component. The component is removed from the mold.
    Type: Application
    Filed: March 24, 2006
    Publication date: April 24, 2008
    Applicant: Forschungszentrum Karlsruhe GmbH
    Inventors: Peter Stemmermann, Krassimir Garbev, Guenter Beuchle, Uwe Schweike