Abstract: Presented herein are articles and methods relating to manufactured superhydrophobic, superoleophobic, and/or supermetallophobic surfaces with macro-scale features (macro features) configured to induce controlled asymmetry in a liquid film produced by impinging phase (e.g., impinging droplet(s)) onto the surface, thereby further reducing the contact time between an impinging liquid and the surface.

Abstract: Described herein are methods for transporting and/or harvesting gas from bubbles, as well as associated articles and systems. In some embodiments, transporting and/or harvesting the gas from the bubbles can reduce or prevent the amount of foam that is present within a system. According to certain embodiments, a conduit comprising a porous wall portion can be at least partially submerged into a foam and/or a bubble-containing liquid. The porous wall portion of the conduit can be configured and/or arranged, according to certain embodiments, such that the porous wall portion provides a fluidic pathway through which gas from the bubbles within the liquid may be channeled to a gaseous environment in the interior portion of the conduit. The gas may be transported, according to certain embodiments, along the interior portion of the conduit into an external gaseous environment and/or harvested from the interior portion of the conduit.

Abstract: Foam mitigation using a variety of articles, systems, and methods is generally described. According to certain embodiments, surfaces with certain wetting properties can be used to reduce or eliminate the formation of foam from bubble-containing liquids. In some embodiments, a surface with certain wetting properties is configured and/or arranged within bubble-containing liquids such that the surface provides a gaseous fluidic pathway through which gas from the bubbles within the liquid may be channeled to a gaseous environment outside the liquid.

Abstract: Upon light irradiation, a dye sensitized photoactive surfaces can undergo hydrophobic to hydrophilic conversion in both in air and oil environments.

Abstract: Polymers comprising fluorinated side chains that can be used for water resistance coatings on substrates and are deposited by initiated chemical vapor deposition are generally described.

Abstract: Meshes capable of droplet fragmentation are generally described. Inventive articles, systems, and uses thereof are also described.

Abstract: Methods related to forming reaction products on surfaces are generally provided. Some methods comprise applying first and second polyelectrolytes in first and second polyelectrolyte carrier fluids to a surface. The first and second polyelectrolytes may be different, and the first and second carrier fluids may be the same or different. Some methods comprise forming a mixture of the first and second polyelectrolytes in a mixture carrier fluid that comprises the first and/or second carrier fluids. The first and second polyelectrolyte may be removed from the mixture carrier fluid to form a reaction product on the surface. In some embodiments, the mixture carrier fluid comprises a salt with a molecular weight of less than or equal to 1 kg/mol at a concentration within the mixture carrier fluid of from 0.01 M to 0.5 M. In some embodiments, the mixture carrier fluid has a turbidity of greater than or equal to 10 NTU and a viscosity of less than or equal to 1 Pa*s.

Abstract: Methods related to depositing oil on surfaces and methods related to contacting surfaces at least partially covered by oil with droplets are generally provided.

Abstract: Hierarchical porous membranes suitable for use in oil/water separation processes are provided. The membranes described herein are particularly well suited for separating trace amounts of water (e.g., no greater than 3 wt % water content, no greater than 1 wt % water content, or 50-1000 ppm water) from oil. The membranes have a wide range of applications, including deep seep oil exploration, oil purification, and oil spill cleanup.

Abstract: Methods described herein provide a way to reduce or eliminate drag and adhesion of a substance flowing over a surface by creating a vapor cushion via evaporation of a phase-changing material of or on the surface or encapsulated within textures of the surface. The vapor cushion causes the flowing substance to be suspended over the surface, greatly reducing friction, drag, and adhesion between the flowing substance and the surface. The temperature of the flowing substance is above the sublimation point and/or melting point of the phase-changing material. The phase-changing material undergoes a phase change (evaporation or sublimation) upon contact with the flowing substance due to local heat transfer from the flowing substance to the material, generating a vapor cushion between the solid or liquid material and the flowing substance.

Abstract: This invention relates generally to an article that includes a non-wetting surface having a dynamic contact angle of at least about 90°. The surface is patterned with macro-scale features configured to induce controlled asymmetry in a liquid film produced by impingement of a droplet onto the surface, thereby reducing time of contact between the droplet and the surface.

Abstract: Embodiments discussed herein relate to systems and methods for separating two or more phases of an emulsion or other mixture. The methods include providing the mixture with a net and unipolar charge (e.g., such that adjacent droplets therein acquire net and unipolar charges), thereby enhancing coalescence of like-phase droplets therein and producing, or enhancing the production of, two or more consolidated phases; and collecting the two or more consolidated phases.

Abstract: This invention relates generally to articles, devices, and methods for gas hydrate mitigation in deep-sea drilling applications. In certain embodiments, hydrate-phobic surfaces are provided that ensure passive enhancement of flow assurance and prevention of catastrophic failures in deep-sea oil and gas operations.

Abstract: Presented herein are articles and methods relating to manufactured superhydrophobic, superoleophobic, and/or supermetallophobic surfaces with macro-scale features (macro features) configured to induce controlled asymmetry in a liquid film produced by impinging phase (e.g., impinging droplet(s)) onto the surface, thereby further reducing the contact time between an impinging liquid and the surface.

Abstract: This invention relates generally to articles, devices, and methods for inhibiting or preventing the formation of scale during various industrial processes. In certain embodiments, a vessel is provided for use in an industrial process, the vessel having a textured, liquid-impregnated surface in contact with a mineral solution, wherein the liquid-impregnated surface comprises a matrix of features spaced sufficiently close to stably contain an impregnating liquid lubricant therebetween or therewithin, wherein the impregnating lubricant has a low surface energy density, and wherein the spreading coefficient Sos(w) of the impregnating lubricant (subscript ‘o’) on the substrate (subscript ‘s’) in the presence of the salt solution (subscript ‘w’) is greater than zero, such that the impregnating lubricant fully submerges the textured substrate.

Abstract: A method for precise control of movement of a motive phase on a lubricant-impregnated surface includes providing a lubricant-impregnated surface, introducing the motive phase onto the lubricant-impregnated surface, and exposing the droplets to an electric and/or magnetic field to induce controlled movement of the droplets on the surface. The lubricant-impregnated surface includes a matrix of solid features spaced sufficiently close to stably contain the impregnating lubricant therebetween or therewithin. The motive phase is immiscible or scarcely miscible with the impregnating lubricant.

Abstract: Hierarchical porous membranes suitable for use in oil/water separation processes are provided. The membranes described herein are particularly well suited for separating trace amounts of water (e.g., no greater than 3 wt % water content, no greater than 1 wt % water content, or 50-1000 ppm water) from oil in droplets less than 1 um in size. The membranes have a wide range of applications, including deep seep oil exploration, oil purification, and oil spill cleanup.

Abstract: Embodiments discussed herein relate to systems and methods for separating two or more phases of an emulsion or other mixture. The methods include providing the mixture with a net and unipolar charge (e.g., such that adjacent droplets therein acquire net and unipolar charges), thereby enhancing coalescence of like-phase droplets therein and producing, or enhancing the production of, two or more consolidated phases; and collecting the two or more consolidated phases.

Abstract: Hierarchical porous membranes suitable for use in oil/water separation processes are provided. The membranes described herein are particularly well suited for separating trace amounts of water (e.g., no greater than 3 wt % water content, no greater than 1 wt % water content, or 50-1000 ppm water) from oil in droplets less than 1 um in size. The membranes have a wide range of applications, including deep seep oil exploration, oil purification, and oil spill cleanup.

Abstract: Embodiments discussed herein relate to systems and methods for separating two or more phases of an emulsion or other mixture. The methods include providing the mixture with a net and unipolar charge (e.g., such that adjacent droplets therein acquire net and unipolar charges), thereby enhancing coalescence of like-phase droplets therein and producing, or enhancing the production of, two or more consolidated phases; and collecting the two or more consolidated phases.